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研究生:黃東亮
研究生(外文):HUANG, TUNG-LIANG
論文名稱:具可見光波段之Type II二苯甲酮光起始劑衍生物合成、光學性質及光聚合探討
論文名稱(外文):Series of novel visible light benzophenone derivatives Type II photoinitiators for free radical polymerization
指導教授:陳永忠陳永忠引用關係
指導教授(外文):CHEN, YUNG-CHUNG
口試委員:鄭力誠林寶順莊宗原
口試委員(外文):Jheng, Li-ChengLIN, BAO-SHUNJUANG, TZONG-YUAN
口試日期:2020-06-24
學位類別:碩士
校院名稱:國立高雄科技大學
系所名稱:化學工程與材料工程系
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2020
畢業學年度:108
語文別:中文
論文頁數:175
中文關鍵詞:二苯甲酮衍生物光起始劑可見光自由基聚合光聚合速率
外文關鍵詞:Benzophenone derivativesPhotoinitiatorVisible lightFree radical polymerizationPhotoreactivity
相關次數:
  • 被引用被引用:0
  • 點閱點閱:246
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摘要 I
Abstract II
目錄 V
表目錄 IX
圖目錄 XI
第一章 緒論 1
1-1 前言 1
第二章 文獻回顧與研究動機 3
2-1 光固化介紹 3
2-1-1 光固化的起源與應用[4-7] 3
2-1-2 光固化樹酯特性比較[5] 4
2-1-3 光固化技術SWOT 6
2-2 光源介紹(定義與應用) 8
2-2-1 UV光源分類 9
2-2-2 發光二極體(Light-emitting diode, LED) 9
2-3 光固化系統 11
2-3-1 光固化樹酯(寡聚物與不飽和單體)之簡介 11
2-3-2 光起始劑(Photoinitiator, PI) 13
2-4 BP固化系統 19
2-4-1 BP雙分子系統 20
2-4-2 BP單分子系統 25
2-5 研究動機 30
第三章 實驗架構 32
3-1 實驗架構 32
3-2 儀器設備 33
3-3 實驗藥品 36
3-4 溶劑 43
3-5 二苯甲酮衍生物之合成 45
3-5-1 二苯甲酮衍生物之合成(Part-1) 45
3-5-2 二苯甲酮衍生物之合成(Part-2) 51
3-5-3 二苯甲酮衍生物之合成(Part-3) 54
3-6 實驗方法 61
3-6-1溶解度測試 61
3-6-2熱性質分析 61
3-6-3紫外/可見光光譜儀測量 62
3-6-4螢光光譜儀測量 62
3-6-5循環伏安法測量 62
3-6-6 Photo-DSC測量 63
3-6-7 UV-Quenching測試 63
3-6-8 電子順磁共振儀(ESR) 64
第四章 結果與討論 65
4-1 Benzophenone衍生物合成 65
4-1-1 Benzophenone衍伸物合成之鑑定(Part-1) 65
4-1-2 Benzophenone衍生物合成之鑑定(Part 2) 78
4-1-3 Benzophenone衍生物合成之鑑定(Part 3) 87
4-2物理性質測試 101
4-2-1溶解度測試 101
4-2-2熱性質分析 104
4-3 光電化學性質分析 110
4-3-1 UV/Vis 分析 110
4-3-2 螢光光譜(PL spectra)分析 116
4-3-3 循環伏安法測量[76] 119
4-4 光化學及光聚合分析 125
4-4-1 UV Quench 125
4-4-2 電子順磁共振光譜儀(ESR)分析 132
4-4-3 光聚合測試 135
第五章 結論 146
第六章參考文獻 147


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