中文摘要i
英文摘要iii
誌謝v
目錄vi
表目錄x
圖目錄xi
符號及縮寫xiv
一、緒論 1
1-1 燃料電池 1
1-1-1 燃料電池的發展 2
1-1-2 燃料電池之分類與應用 2
1-1-3 直接甲醇燃料電池之簡介 4
1-1-4 直接甲醇燃料電池之構造 5
1-1-5 鉑觸媒之毒化 6
1-1-6 雙金屬觸媒 8
1-1-7 甲醇穿透之問題 9
1-2 導電性高分子 10
1-2-1 導電性高分子的合成方法 10
1-2-2 6-氰基吲哚之簡介 13
1-2-3 聚(6-氰基吲哚)/聚苯乙烯磺酸應用於修飾電極 13
1-3 研究動機 14
二、鉑粒子嵌入含不同摻雜程度聚苯乙烯磺酸於聚(6-氰基吲哚)複合材料應用於甲醇氧化 16
2-1 實驗部分 16
2-1-1 藥品與裝置 16
2-1-2 工作電極基材之前處理 16
2-1-3 複合修飾電極之製備 17
2-1-4 陽極循環伏安曲線 18
2-1-5 傅立葉紅外光光譜 18
2-1-6 化學分析電子光譜 19
2-1-7 歐傑電子光譜 19
2-1-8 X光繞射分析 19
2-1-9 表面型態 19
2-1-10 穿透式電子顯微鏡分析 20
2-1-11 電化學分析 20
2-1-12 甲醇氧化測試 20
2-2 結果與討論 21
2-2-1 陽極循環伏安曲線 21
2-2-2 傅立葉紅外光光譜圖 23
2-2-3 化學分析電子光譜 25
2-2-4 深度分析 26
2-2-5 X光繞射分析 27
2-2-6 聚(6-氰基吲哚)/聚苯乙烯磺酸/鉑之材料分析 29
2-2-7 甲醇氧化能力之探討 33
2-2-8 電極於不同甲醇濃度中催化之影響 38
2-2-9 穩定度的測試 39
2-3 結論 41
三、總結 42
參考文獻 44
著作 50
自傳 51

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