目錄
摘要 i
Abstract ii
致謝 iii
目錄 iv
圖目錄 vii
表目錄 xiii
第一章 緒論 1
1-1 研究背景 1
1-2 太陽能電池介紹 2
1-3 鈣鈦礦太陽能電池簡介 4
1-3-1鈣鈦礦材料簡介 4
1-3-2 鈣鈦礦太陽能電池結構 5
1-4 研究動機 6
第二章 文獻回顧 7
2-1 鈣鈦礦太陽能電池發展 7
2-2 鈣鈦礦主動層製程方法 14
2-2-1 一步溶液法 14
2-2-2 兩步溶液法 15
2-2-2 電噴塗法 16
2-2-2 氣相沉積法 17
2-3不同晶體形貌對鈣鈦礦效能影響 19
2-3-1 電子傳輸層不同晶體形貌的影響 19
2-3-2 鈣鈦礦主動層不同結晶形貌的影響 32
2-3-3 鈣鈦礦奈米片轉換鈣鈦礦奈米線 41
第三章 實驗方法與分析 43
3-1 實驗流程 43
3-2 CH3NH3PbI3合成步驟 44
3-2-1 前驅物甲胺油酸鹽（Methylammonium oleate，MAOA）合成 44
3-2-2 前驅物PbI3-合成 44
3-3-3 以化學浴沉積法製備CH3NH3PbI3鈣鈦礦主動層 45
3-3 實驗藥品 46
3-4 實驗儀器與耗材 47
3-5 元件製作 48
3-5-1 ITO導電玻璃基板 48
3-5-2 黃光顯影蝕刻ITO導電玻璃基板 48
3-5-3 ITO玻璃基板清洗 50
3-5-4 PEDOT:PSS電洞傳輸層 50
3-5-5 太陽能元件製作 51
3-6薄膜分析 52
3-6-1 掃描式電子顯微鏡（Scanning electron microscope） 52
3-6-2 X光繞射儀（X-ray Diffraction） 53
3-6-3 紫外/可見光光譜儀(Ultraviolet-Visible spectrophotometer, UV-Vis) 54
3-6-4 光致發光光譜儀(Photoluminescence spectrometer,PL) 55
3-6-5 光伏特性測量系統 56
第四章 結果與討論 57
4-1不同劑量的乙酸乙酯(EA)對鈣鈦礦表面形貌效應探討 57
4-1-1鈣鈦礦奈米立方晶體(nanocubics，NC) 58
4-1-2鈣鈦礦奈米片(nanosheets，NS) 59
4-1-3鈣鈦礦奈米線(nanowires，NW) 61
4-1-4不同劑量的EA對鈣鈦礦沉積速率的影響 63
4-2不同劑量的EA對鈣鈦礦結晶性探討 66
4-3不同劑量的EA對鈣鈦礦薄膜吸收度探討 68
4-4不同劑量的EA對鈣鈦礦薄膜光致發光探討 69
4-5不同劑量的EA對元件測試及電性探討 70
第五章 結論 72
5-1 結論 72
5-2 未來展望 72
參考文獻 73

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