臺灣博碩士論文加值系統

磁流體為一種可以利用磁場進行控制的智能奈米流體，因為磁流體的光學、熱學、流變性質可以達到精準地控制因此被歸類為智能流體，其應用在工業上包含了無洩漏密封[1][2]、軸承潤滑液[3]，其軸承間具有磁力使得磁流體能夠完美的包覆在軸承之間達成無洩漏的密封狀態並且可以降低軸承之間的摩擦力並且此應用也在噴墨列印機上展現出優良的打印能力[4]，並且在光學上也根據其調節優越的特性成功製成了良好的光柵[5]並且對於施加不同強度的磁場還能夠產生對不同波長下使用的光學濾波片[6]，在生物醫療上因為其操控能力優越以外，磁流體的表面活性劑還能夠與生物分子的鍵結產生配對，諸如:生物感測器[7]、醫療診斷[8]、標靶治療[9]等等[10]。隨著網路技術的發達，我將研究在兆赫波段中鮮少被使用的磁光效應調制器來應對新網路時代的來臨，由於能夠在兆赫波段下產生磁光效應的材料需要斟酌，我將利用四氧化三鐵的磁流體在不同的平行磁場強度下的磁光特性對兆赫波段進行調制，藉由磁光效應所帶來的折射率變化對兆赫波產生有效的調制成果。
本論文將使用以ZnTe晶體作為兆赫波發射源的兆赫波時域光譜系統，利用高尖峰功率的飛秒雷射激發晶體產生出兆赫波並且也利用ZnTe作為兆赫波偵測器，通過離軸拋物面鏡將兆赫波導入樣品中心，最後藉由四分之一波片與Wollaston prism整理兆赫波訊號接收至光偵測器，藉由兆赫波通過前樣品與通過後的變化得出此樣品在兆赫波段的穿透率為何再以兆赫波的色散與振幅變化推算出樣品的折射率與消光係數。本研究使用親水性磁流體與親油性磁流體做出比對，以得證親油性磁流體對於兆赫頻段具有顯卓的表現。

Ferrofluid is a smart nanofluid that can be controlled using a magnetic field. Because the optical, thermal, and rheological properties of magnetic fluids can be precisely controlled, it is classified as a smart fluid. Its application in the industry includes leak-free sealing [1 ] [2], bearing lubricating fluid [3], there is magnetic force between the bearings so that the magnetic fluid can be perfectly covered between the bearings to achieve a leak-free sealed state and can reduce the friction between the bearings and this application is also spraying Ink printers have demonstrated excellent printing capabilities [4], and optically have successfully made good gratings [5] according to their excellent adjustment characteristics, and can also produce different wavelengths at different wavelengths for applying magnetic fields of different strengths. The optical filter used [6], in addition to its superior handling ability in biomedicine, Ferrofluid surfactants can also be paired with biomolecule bonds, such as: biosensors [7], medical diagnosis [8] ], Target therapy [9], etc. [10]. With the development of network technology, I will study magneto-optic effect modulators that are rarely used in Terahertz to cope with the advent of the new Internet era. Since materials capable of generating magneto-optical effects under Terahertz need to be considered, I will use Fe3o4 The magneto-optical properties of the Ferrofluid produced under different parallel magnetic field intensities modulate Terahertz, and the refractive index changes caused by the magneto-optical effect produce effective modulation results for Terahertz waves.
In this paper, a Terahertz time-domain spectroscopy system using a ZnTe crystal as a Terahertz emitter will be generated using a femtosecond laser with a high peak power to generate a Terahertz wave. The Terahertz wave will also be used as a Terahertz detector by ZnTe. Introduced into the sample center, and finally the Terahertz signal was received by the quarter wave plate and Wollaston prism to receive the light detector. The Terahertz wave passed the sample before and after the change to determine the transmittance of this sample in Terahertz. The refractive index and extinction coefficient of the sample were calculated based on the dispersion and amplitude changes of the Terahertz wave. In this study, a comparison was made between the hydrophilic Ferrofluid and the lipophilic Ferrofluid.

中文摘要 I
ABSTRACT III
致謝 V
目錄 VII
圖目錄 X
表目錄 XII

第一章 序論 1
1.1 兆赫波 1
1.2 磁流體之介紹 2
1.2.1 超順磁性 4
1.2.2 磁光效應 4
1.3 磁流體之兆赫波段研究 5
1.4 本論文的組織 8

第二章 實驗設置 9
2.1 磁流體製備 9
2.2 雷射系統(Legend Elite HE+ USP-5K-III) 9
2.3 基於ZnTe設置的兆赫波時域光譜(THz-TDS)架設 12

第三章 理論模型和分析方法 15
3.1 THz-TDS 15
3.1.1 基於ZnTe產生的兆赫波訊號 15
3.1.2 ZnTe偵測兆赫波訊號 17
3.2 THz-TDS取得材料的光學常數 26
3.2.1 厚樣品 26
3.2.2 薄樣品 30
3.2.3 取得折射率 32
3.3 光導率 34
3.3.1 馬克斯威爾方程式(Maxwell equation) 34
3.3.2 複介電功能 34
3.3.3 德魯德自由電子模型(Drude free-electron model) 35
3.3.4 德魯德史密斯模型(Drude-smith model) 39

第四章 結果與討論 41
4.1 磁流體材料特性分析 41

第五章 結論 51
5.1 結論 51
5.2 未來工作 52

參考文獻 53

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