臺灣博碩士論文加值系統

絹雲母礦係層狀矽酸鹽礦物的一種，為片狀結構，平均粒徑為10 μm，可作為造紙、建材中的填料，但受限於大尺寸使其實際資源利用效益並不大。本研究以臥式研磨機溼式研磨大規模製備次微米等級水相絹雲母，研磨轉速為1500 rpm，選擇大小為1.2 mm及0.6 mm的氧化鋯球作為研磨介質。在研磨漿料中添加羧甲基纖維素 (CMC) 作為增稠劑與分散劑。實驗過程中分別探討了 (1) 絹雲母的初始濃度、(2) CMC的添加量、(3) 氧化鋯球與絹雲母的重量比，以及 (4) 儲料桶上方加裝攪拌器對於絹雲母平均粒徑變化的影響。從實驗結果中得知，在儲料桶上方加裝攪拌器能讓儲料桶內的絹雲母漿料在研磨過程中混合均勻。當絹雲母漿料初始濃度為35 %，CMC添加量為0.5 %，氧化鋯球與絹雲母的重量比值為 2.38，並將漿液之黏度控制在1500~3500 mPa‧s時，可有效使其絹雲母之平均粒徑降低，研磨絹雲母的平均粒徑從10 μm降低至0.45 μm，厚度從1 μm降低至45 nm。從XRD結果中可發現，經研磨過的絹雲母並未產生新的晶相。將微量的研磨絹雲母 ( 0.16 g /cm2 ) 塗於石英玻璃上，可見光 ( 波長為550 nm ) 仍有77.4%的光穿透率，同時能有效地遮蔽UV光 ( 200 nm ~ 400 nm的平均光穿透率為40.5 % )；進一步更以亞甲基藍降解實驗證明研磨絹雲母確實具有阻隔紫外光之功能。

致謝 i
中文摘要 ii
Abstract iii
目錄 v
圖目錄 vii
表目錄 ix
第一章 文獻回顧 1
1.1 研磨機種類 1
1.1.1 臥式球磨機 1
1.1.2 直立式球磨機 3
1.1.3 行星式球磨機 5
1.2 乾式研磨與溼式研磨 7
1.2.1 乾式研磨 7
1.2.2 溼式研磨 10
第二章 前言 11
2.1 研究動機 11
2.2 研究方法與目的 12
2.3 研究內容 13
第三章 研究方法 14
3.1 實驗材料 14
3.1.1 天然絹雲母粉末 14
3.1.2 添加劑 16
3.1.3 研磨介質 16
3.2 實驗儀器 17
3.2.1 臥式研磨機 17
3.2.1 高扭力攪拌器 20
3.2.2 桌上型行星式球磨機 20
3.2.3 高速攪拌機 20
3.2.4 黏度計 20
3.2.5 烘箱 20
3.3 檢測儀器 21
3.3.1 沉降離心式粒徑分布儀 21
3.3.2 掃描式電子顯微鏡 ( Scanning Electron Microscopy ) 22
3.3.3 X射線繞射儀 (X-ray diffractometer ) 22
3.3.4 傅立葉轉換紅外線光譜儀 (Fourier-transform infrared spectroscopy ) 22
3.3.5 原子力顯微鏡 (Atomic Force Microscope ) 22
3.3.6 反射式紫外光-可見光光譜儀 23
3.3.7 紫外－可見光光譜儀 23
3.4 實驗方法 24
3.4.1 利用臥式研磨機研磨天然絹雲母 ( NS ) 24
3.4.2 研磨絹雲母漿料 ( BNS ) 穩定性 26
3.4.3 利用桌上型行星式球磨機研磨天然絹雲母 ( NS ) 26
3.4.4 研磨絹雲母 ( BNS ) 光學性質 26
3.4.5 研磨絹雲母 ( BNS ) 作為UV阻擋材料 27
第四章 結果與討論 28
4.1 利用臥式研磨機研磨天然絹雲母 ( NS ) 28
4.1.1 實驗組別1 29
4.1.2 實驗組別2 32
4.1.3 實驗組別3 35
4.1.4 實驗組別4 39
4.2 利用桌上型行星式球磨機研磨天然絹雲母 ( NS ) 50
4.3 研磨絹雲母 ( BNS ) 光學性質 54
4.4 研磨絹雲母 ( BNS ) 作為UV阻擋材料 58
第五章 結論與建議 61
5.1 結論 61
5.2 建議 61
第六章 參考文獻 62

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