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研究生:張書儒
研究生(外文):Shu-Ju Chang
論文名稱:由陰離子調控氧化銅奈米結構的形態及探討其對太陽能水分解的催化活性
論文名稱(外文):Tuning the morphological structures of CuO by anion regulation for solar water splitting
指導教授:江佳穎
指導教授(外文):Chia-Ying Chiang
口試委員:蔡大翔張家耀
口試委員(外文):Dah-Shyang TsaiJia-Yaw Chang
口試日期:2019-12-25
學位類別:碩士
校院名稱:國立臺灣科技大學
系所名稱:化學工程系
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2020
畢業學年度:108
語文別:中文
論文頁數:98
中文關鍵詞:釩酸鉍氧化銅產氧助催化劑水氧化反應水分解反應
外文關鍵詞:BiVO4CuOco-catalystoxygen evolutionwater splitting
相關次數:
  • 被引用被引用:0
  • 點閱點閱:127
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  • 下載下載:0
  • 收藏至我的研究室書目清單書目收藏:0
摘要
ABSTRACT
總目錄
圖目錄
表目錄
第一章
緒論 1
1.1 研究動機 1
1.2 研究方向 2
第二章
文獻回顧 3
2.1 CuO產氧助催化劑之探討 3
2.2 層狀羥基鹽 (layered hydroxy salt , LHS)之探討 6
2.3 BiVO4光電極材料性質探討 9
2.4 製備 BiVO4光電極之方法及原理 11
2.4.1 金屬有機沉積法 (Metal Organic Decomposition ,MOD) 11
2.4.2 水熱法 (Hydrothermal) 11
2.4.3 電沉積法 (Electrodeposition) 11
2.5 BiVO4改質策略及原理 13
2.5.1 半導體耦合 (Heterojunction) 13
2.5.2 金屬離子摻雜 (Doping) 14
2.5.3 添加產氧助催化劑(co-catalyst) 15
第三章 實驗設備及方法實驗設備及方法 17
3.1 實驗架構實驗架構 17
3.2 實驗藥品、設備及分析儀器 18
3.2.1 實驗藥品 18
3.2.2 實驗設備 19
3.2.3 分析儀器 20
3.2.4 BiVO4/CuO製備流程 21
3.3 儀器分析原理 23
3.3.1 光電化學分析 23
3.3.2 X光繞射儀 (X-ray Diffractometer, XRD) 25
3.3.3 場發射掃描式電子顯微鏡 (field-emission scanning electron microscope,,FESEM) 26
3.3.4 穿透式電子顯微鏡 (Transmission electron microscopy ,TEM) 27
3.3.5 拉曼光譜儀 (Raman spectroscopy) 27
3.3.6 紫外光/可見光光譜 (UV/Vis Spectrometer) 27
3.3.7 入射光光電子轉換效率 (Incident Photon-to-electron Conversion Efficiency, IPCE) 28
3.3.8 X光光電子能譜儀 (X-ray Photoelectron Spectroscope, XPS) 29
3.3.9 氣相層析儀(gas chromatograph,,GC) 29
3.3.10 感應耦合電漿原子發射光譜儀 (Inductively coupled plasma atomic emission spectroscopy , ICP - AES) 30
第四章 實驗結果與討論 31
4.1 BiVO4光電極薄膜之材料分析 31
4.2 Cu-LHS電沉積條件之選擇 36
4.3 不同陰離子所沉積之不同陰離子所沉積之BiVO4/CuO電極之材料分析 40
4.3.1 X光繞射 (X-ray Diffractometer , XRD)分析 40
4.3.2 掃描式電子顯微鏡(Scanning Electron Microscope, SEM)分析 42
4.3.3 穿透式電子顯微鏡 (Transmission electron microscopy ,TEM)分析 44
4.3.4 拉曼光譜拉曼光譜 (Raman spectra)分析 46
4.3.5 BiVO4/CuO電極之光電化學表現 47
4.4 不同陰離子所沉積之不同陰離子所沉積之BiVO4/CuO電極之生長機制探討 49
4.5 CuO沉積於沉積於BiVO4光陽極應用於水氧化反應之功能探討 53
4.5.1 紫外-可見分光光度法(Ultraviolet–visible spectroscopy,UV-Vis)分析 53
4.5.2 CuO沉積於沉積於BiVO4於水氧化反應之動力學探討 56
4.6 BiVO4/CuO異質結構光電極之電化學分析 59
4.7 BiVO4/CuO異質結構光電極之水分解效率分析及穩定性分析 63
4.7.1 計時安培法 (chronoamperometry)之穩定性分析 63
4.7.2 氣體產物分析 64
4.7.3 X-ray光電子能譜儀 (X-ray Photoelectron Spectroscope, XPS)分析 67
第五章 結論 72
第六章 參考文獻 74
第七章 附錄 85
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