臺灣博碩士論文加值系統

摘要 I
ABSTRACT II
致謝 IV
目錄 V
圖目錄 VIII
表目錄 X
第一章、緒論 1
1.1前言 1
1.1.1塗料的功能 1
1.1.2塗料發展 2
1.1.3塗料組成 3
1.2研究目的與動機 4
第二章、理論基礎與回顧 5
2.1腐蝕簡介 5
2.1.1腐蝕分類 5
2.2石墨烯與氧化石墨烯及奈米碳管簡介 8
2.2.1石墨烯簡介 8
2.2.2氧化石墨烯簡介 10
2.2.3奈米碳管簡介 11
2.3紫外線吸收劑 12
2.3.1紫外線吸收劑簡介 12
2.3.2紫外線吸收劑種類 13
2.3.3紫外線吸收劑作用原理 14
2.3.4紫外線吸收劑危害 15
2.4重防蝕塗料 16
2.4.1重防蝕塗料簡介 16
2.4.2環氧富鋅塗料簡介 16
2.4.3石墨烯及奈米碳管於環氧富鋅塗料之應用 17
第三章、實驗材料與方法 18
3.1實驗規劃 18
3.2實驗藥品 19
3.3實驗儀器 21
3.3.1儀器設備 21
3.3.2分析儀器 22
3.4實驗步驟 27
3.4.1碳鋼基板與不鏽鋼基板清洗 27
3.4.2富鋅環氧底漆試片製備 27
3.4.3有機矽環氧面漆試片製備 27
3.4.4水性無機鋅粉防蝕塗料試片製備 28
第四章、結果與討論 29
4.1石墨烯物性分析 29
4.1.1導電度分析 29
4.1.2形貌分析 29
4.1.3拉曼光譜儀分析結果 31
4.1.4 元素分析儀分析結果 32
4.1.5 石墨烯紫外線吸收效果分析 32
4.2石墨烯分散測試 35
4.3防蝕塗料初始配方及市售防蝕塗料分析 38
4.3.1鹽霧腐蝕測試 38
4.3.2耐候測試 42
4.3.3附著力測試 44
4.3.4撞擊測試 46
4.4第一階段配方優化及分析 46
4.4.1鹽霧腐蝕測試 51
4.4.2附著力測試 53
4.5第二階段配方優化及分析 54
4.5.1 循環老化測試 58
4.5.2 腐蝕電化學分析 69
4.6不同溶劑對之黏度測定 69
第五章、結論與未來展望 70
5.1結論 70
5.1.1石墨烯選用 70
5.1.2分散劑選用及配方評估 70
5.1.3配方優化及實場試驗 70
5.2未來展望 71
參考文獻 72
附錄 76

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