臺灣博碩士論文加值系統

摘要 I
Abstract III
致謝 V
目錄 VII
圖目錄 XI
表目錄 XIV
第一章 緒論 1
1.1 前言 1
1.2 薄膜分離技術 2
1.3 智能響應薄膜 4
1.3.1 概述與未來發展 4
1.3.2 響應種類 6
1.3.3 平板薄膜設計: 7
1.4 奈米複合材料 12
1.5 二維材料 14
1.5.1 介紹 14
1.5.2 石墨烯衍生物 14
1.6 熱響應高分子 16
1.7 滲透蒸發程序 18
1.7.1 滲透蒸發發展史 18
1.7.2 滲透蒸發的分離機制 19
1.8 文獻回顧 20
1.9 研究動機與目的 25
第二章 實驗材料與方法 27
2.1 實驗藥品 27
2.2 實驗器材與儀器 29
2.3 實驗步驟 31
2.3.1 合成熱響應高分子 31
2.3.2 製備氧化石墨烯 32
2.3.3 溶液配置 32
2.3.4 製備薄膜 35
2.4 材料鑑定與性質檢測 36
2.4.1 核磁共振氫譜 37
2.4.2 雷射奈米粒徑電位分析儀 37
2.4.3 紫外光-可見光/近紅外光分析儀 38
2.4.4 高倍率數位顯微鏡 39
2.4.5 掃描式電子顯微鏡 40
2.4.6 微米水接觸角 40
2.4.7 顯微拉曼光譜儀 41
2.4.8 衰減全反射傅里葉轉換紅外光譜儀 41
2.4.9 X射線光電子能譜儀 42
2.4.10 X光繞射儀 43
2.4.11滲透蒸發裝置 44
2.4.12 正電子湮滅譜儀 45
第三章 結果與討論 47
3.1 mPNIPAm之鑑定: 47
3.2 GO與GO-mPNIPAm熱響應材料於溶液狀態下之鑑定與分析 49
3.2.1溶液巨觀分析 49
3.2.2溶液粒徑變化分析 52
3.2.3溶液響應溫度變化 53
3.3 GO與GO-mPNIPAm熱響應複合薄膜分析與鑑定 55
3.3.1 薄膜表面型態分析 55
3.3.2 薄膜表面粗糙度分析 57
3.3.3 薄膜表面親疏水性分析 59
3.3.4 薄膜物理結構分析 60
3.3.5 薄膜化學組成分析 61
3.3.6 薄膜乾濕態層間距變化 66
3.4 GO與GO-mPNIPAm熱響應複合薄膜效能檢測 69
3.4.1 純水通量檢測 69
3.4.2 針對不同溫度下進行滲透蒸發之效能檢測 70
3.4.3 長時間響應開關的效能測試 73
3.5 一維與二維熱響應複合薄膜之機制分析 75
3.5.1 自由體積分析 75
3.5.2 機制分析 78
第四章 結論 79
參考文獻 80

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