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研究生:蔡永欣
研究生(外文):Tsai,Yung-Hsin
論文名稱:堇青石透明玻璃陶瓷的成核劑添加研究
論文名稱(外文):Research on Adding Nucleating Agent of Cordierite Transparent Glass Ceramics
指導教授:楊希文楊希文引用關係
指導教授(外文):Yang,Hsi-wen
口試委員:楊希文賴宜生洪集輝呂昊穎
口試委員(外文):Yang,Hsi-wenLai,I-ShengHung,Chi-HuiLu,Hao-Ying
口試日期:2020-07-23
學位類別:碩士
校院名稱:國立聯合大學
系所名稱:材料科學工程學系碩士班
學門:工程學門
學類:材料工程學類
論文種類:學術論文
論文出版年:2020
畢業學年度:108
語文別:中文
論文頁數:103
中文關鍵詞:高硬度透明釉料短時間微晶強化玻璃陶瓷奈米堇青石結構添加劑用於晶核成長控制
外文關鍵詞:high hardness transparent glazeshort-time microcrystalline strengthened glass ceramicsnano-cordierite structureadditives for crystal nuclei growth control
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中文摘要
中文摘要 I
Abstract IV
目錄 VI
圖目錄 IX
表目錄 XIII
第一章 緒論 1
1.1 前言 1
1.2 釉面磚基本性質及研究目的 1
1.3 釉面磚製程及市場介紹 2
1.4 瓷磚發展趨勢 6
第二章 文獻回顧 7
2.1 基礎玻璃 7
2.1.1 玻璃的定義 7
2.1.2 玻璃結構理論 10
2.2 結晶玻璃陶瓷 17
2.2.1 奈米結晶透明玻璃 17
2.2.2 菫青石結晶玻璃之基本特性 19
2.2.3 過往堇青石之成核劑添加研究 20
第三章 實驗步驟 25
3.1 玻璃製程 25
3.1.1 實驗藥品 25
3.1.2 玻璃製程 27
3.1.3 試片分析流程 31
3.2 玻璃性質量測 33
3.2.1 熱差式掃描分析儀(DSC) 33
3.2.2 熱機械分析(TMA) 34
3.2.3 紫外-可見光譜穿透分析 36
3.2.4 維氏硬度量測 36
3.2.5 X光繞射分析(XRD) 37
3.2.6 Raman 光譜分析 39
第四章 結果與討論 40
4.1 前導性研究 40
4.1.1 結晶動力學探討(DSC) 40
4.1.2 玻璃結晶情形探討 47
4.1.3 晶形與結晶強度(XRD) 50
4.1.4 透光度 52
4.1.5 硬度 52
4.2 成核劑添加製程改善 56
4.3 成核劑添加與長晶控制結果 61
4.3.1 熱差式掃描分析儀(DSC) 61
4.3.2 熱機械分析(TMA) 63
4.3.3 X光繞射分析(XRD) 65
4.3.4 玻璃外觀與透光度 71
4.3.5 維氏硬度檢測 75
4.3.6 硬度、結晶強度、透光度統合趨勢圖 77
4.3.7 Raman 光譜分析 80
4.4 電爐(實驗室)實際施釉製程 85
4.4.1 電爐(實驗室)實際施釉之硬度 87
4.5 瓦斯爐(工廠)實際施釉製程 88
4.5.1 釉面磚TMA與硬度分析 92
第五章 結論 94
參考文獻 96
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