臺灣博碩士論文加值系統

摘要 I
Abstract II
目錄 III
圖目錄 V
表目錄 VII
一、緒論 1
1.1前言 1
1.2電化學沉積(Electrochemical Deposition) 4
1.2.1脈衝式電化學沉積(Pulsed Electrochemical Deposition) 5
1.2.2三維樹狀銀電極(Silver Dendrites) 6
1.3 拉曼散射(Raman scattering) 8
1.4 表面增顯拉曼散射(Surface-Enhanced Raman Scattering) 9
1.4.1電磁場增顯(Electromagnetic Field Enhancement) 11
1.4.2化學增顯(Chemical enhancement) 13
1.5表面電漿共振(Surface Plasmon Resonance) 15
1.6熱點(Hot Spot) 17
1.7半胱胺酸(Cysteine)之反應性 18
1.8研究動機與目的 21
二、實驗方法與儀器 23
2.1 實驗藥品 23
2.2 實驗流程 24
2.3 實驗製備方法 26
2.3.1 樹狀銀電極之製備 26
2.3.2 樹狀銀電極應用前處理 28
2.3.3 拉曼樣品之製備 28
2.3.3.1 L-cysteine為偵測分子之樣品 28
2.3.3.2欲形成cystine之樣品 29
三、結果與討論 30
3.1 樹狀銀電極性質鑑定 30
3.1.1 樹狀銀電極之SEM分析 30
3.1.2 樹狀銀電極之XRD分析 32
3.1.3 樹狀銀電極之XPS分析 33
3.1.4 樹狀銀電極之UV分析 34
3.2 L-cysteine吸附於樹狀銀電極上之表面增顯拉曼光譜 35
3.2.1 pH值變化 35
3.2.2光強變化 40
3.3 L-cysteine於樹狀銀電極上偶和反應之表面增顯拉曼光譜 43
3.4 L-cysteine於已修飾的樹狀銀電極上偶合反應之拉曼顯微成像 47
四、結論 49
五、參考文獻 51

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