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研究生:曾思敏
研究生(外文):ZENG, SI-MIN
論文名稱:製備鋰離子電池三元正極材料 LiNi0.5Co0.2Al0.3O2與電化學性質之研究
論文名稱(外文):Preparation and Electrochemical Performance of LiNi0.5Co0.2Al0.3O2 Cathode Materials for Lithium Ion Batteries
指導教授:蔡德華
指導教授(外文):TSAI, TEH-HUA
口試委員:張裕祺洪桂彬蘇至善
口試委員(外文):CHANG, YU-CHIHONG, GUI-BINGSU, CHIE-SHAAN
口試日期:2020-07-15
學位類別:碩士
校院名稱:國立臺北科技大學
系所名稱:化學工程與生物科技系化學工程碩士班
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2020
畢業學年度:108
語文別:中文
論文頁數:89
中文關鍵詞:共沉澱法正極材料三元鋰離子電池LiNi0.5Co0.2Al0.3O2
外文關鍵詞:Cathode MaterialsTernary lithium-ion batteryCo-precipitationNCA
相關次數:
  • 被引用被引用:0
  • 點閱點閱:146
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  • 下載下載:0
  • 收藏至我的研究室書目清單書目收藏:0
摘要 i
Abstract ii
誌謝 iv
目錄 v
表目錄 vi
圖目錄 vii
第一章 緒論 1
1.1 前言 1
1.2 研究動機與目的 2
1.3 研究架構 3
第二章 文獻回顧 4
2.1 鋰離子電池簡介 4
2.1.1 鋰離子電池工作原理 4
2.2 正極材料介紹 6
2.3 共沉澱法 7
2.4 鎳鈷鋁三元正極材料 10
第三章 實驗藥品材料 15
3.1 實驗藥品材料 15
3.1.1 合成正極材料LiNi0.5Co0.2Al0.3O2使用藥品 15
3.1.2 組裝鈕扣電池所需藥品 19
3.2 實驗設備與分析儀器 21
3.3 實驗儀器介紹 25
3.3.1 感應耦合電漿發射光譜分析儀(Inductively coupled plasma-optical emission spectrometry, ICP-OES) 25
3.3.2 X-光繞射分析儀(X-ray diffraction, XRD) 26
3.3.3 掃描式電子顯微鏡(Scanning electron microscope, SEM) 27
3.3.4 雷射光散射式粒徑分佈分析儀 (Particle size analyzer, PSA) 28
3.4 實驗流程 29
3.4.1 合成裝置圖 29
3.4.2 改變前驅體製備條件 30
3.4.3 LiNi0.5Co0.2Al0.3O2正極材料製備 30
3.4.4 製備正極極片 32
3.4.5 手套箱操作流程 34
3.4.6 鈕扣型電池組裝 35
第四章 結果與討論 37
4.1 ICP-OES元素分析 37
4.1.1不同合成溫度之ICP-OES分析 37
4.1.2不同合成氨水濃度之ICP-OES分析 38
4.1.3不同合成pH值之ICP-OES分析 39
4.1.4不同煅燒溫度之ICP-OES分析 40
4.2 XRD分析 42
4.2.1不同合成溫度之XRD分析 42
4.2.2 不同合成氨水濃度之XRD分析 44
4.2.3 不同合成pH之XRD分析 46
4.2.4 不同煅燒溫度之XRD分析 48
4.3粒徑分析 52
4.3.1不同合成溫度之粒徑分析 52
4.3.2不同合成氨水濃度之粒徑分析 53
4.3.3不同合成pH值之粒徑分析 55
4.3.4不同煅燒溫度之粒徑分析 56
4.4 SEM分析 58
4.4.1 不同合成溫度之SEM分析 59
4.4.2 不同合成氨水濃度之SEM分析 60
4.4.3 不同合成pH值之SEM分析 61
4.4.4 不同煅燒溫度之SEM分析 63
4.5 電化學分析 65
4.5.1 循環伏安測試 65
4.5.2 變速率充放電測試 66
4.5.3 交流阻抗測試 73
第五章 結論 80
符號說明 82
參考文獻 83
附錄 87

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