臺灣博碩士論文加值系統

本研究使用macleod軟體模擬、設計隔熱膜，材料選用各式金屬和高分子來製作。金屬膜選用金、銀、銅、鋁，陶瓷則選用TiO2、SnO2、ZnO、Si3N4，模擬後得到最佳設計為TiO2/Si/Ag/TiO2/Si/Ag/TiO2 ，其可見光平均透射率86.17%，紅外光平均透射率4.09%。然而金屬、陶瓷膜需要真空蒸鍍、磁控濺鍍大面積製作，耗時費工。相對而言高分子膜可以大片塗佈，有利於縮短工時。
高分子膜使用實驗上最高及最低折射率的材料polyvinylsulfide (聚硫醚，PVS)和polydimethylsiloxane(聚二甲基矽氧烷，PDMS)，基板選用polyethylene terephthalate(聚對苯二甲酸乙二酯，PET)，兩材料藉由macleod軟體模擬得知在特定光學厚度下交錯排列可降低特定波段的穿透率，在80層排列下其可見光穿透率可到92.284%，紅外光反射率20.64%，相對於3M光學膜200層製程更加簡單方便。
接著再設計以高分子、金屬與陶瓷交錯排列設計，既可具備金屬膜層數較少的特性，又兼具高分子膜層塗佈簡單的優點，其最佳設計結果為PVS/Si/Ag/PVS /Si/Ag/PVS，其可見光透射率85.13%，紅外光透射率4.457%。
最後本研究在玻璃兩面用不同鍍膜的方式進行模擬，其設計上有金屬膜的部分可以反射大部分的紅外光，而高分子膜的部分讓可見光穿透其兩層鍍膜可見光，其穿透率85.19%，紅外光700~2500 nm穿透率3.34%。

This research uses macleod software to simulate and design the heat insulation film, The materials are made of various metals and polymers. After macleod simulation, TiO2/Ag/TiO2 has the best performance under a specific optical thickness. Using this as the basis to add the number of material layers to get the best design TiO2/Si/Ag/TiO2/Si/Ag/TiO2, the average transmittance of visible light is 86.17%, and the average transmittance of infrared light is 4.09%.
The polymer film is made of polyvinylsulfide and polydimethylsiloxane with the highest and lowest refractive index materials. With an arrangement of ninety layers, the staggered arrangement of the two materials at a specific optical thickness can reduce the transmittance of IR waves, and transmittance of the visible light is 92.284%.
The third design is the arrangement of polymer, metal and oxide. It has the characteristics of fewer metal film layers and the advantage of simple polymer film coating. Its design combines the advantages of polymer and metal film as heat insulation Membrane has its development characteristics.

論文審定書 i
摘要 ii
Abstract iii
目錄 iv
圖目錄 v
表目錄 vii
1. 第一章 緒論 1
1.1前言 1
1.2研究動機 4
2. 第二章 基礎理論與材料特性 5
2.1薄膜光學 5
2.1.1 導納軌跡法 6
2.2 Essential macleod 11
2.3 各式材料介紹 11
2.3.1 銀 13
2.3.2 鋁 13
2.3.3 金 13
2.3.4 銅 13
2.3.5 高分子 13
2.3.6 二氧化鈦 14
2.3.7 二氧化錫 14
2.3.8 氮 14
2.3.9 氧化鋅 14
2.4 模擬構想 15
第三章 各式隔熱紙之模擬設計 17
3.1 以金屬為主之隔熱膜 17
3.1.1 利用macleod設計包含銀膜、陶瓷之3層隔熱膜 22
3.1.2 利用macleod設計包含鋁膜、陶瓷之3層隔熱膜 29
3.1.3 多層薄膜架構 37
3.2 以高分子材料為主之隔熱膜 41
3.2.1 週期性排列 42
3.2.2 以高分子取代氧化膜之多層設計 46
3.2.3 兩層鍍膜 49
3.2.4 太陽光進光量 50
3.2.5 鍍膜誤差分析 52
3.2.6 薄膜顏色 53
3.3 各式隔熱膜比較 54
第四章 結果與討論 57
第五章 未來工作 58
參考文獻 59

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