臺灣博碩士論文加值系統

為提昇玻璃基鑽石工具之性能，本研究在 鑽石工具 之 玻璃基 地相 中，加入不同 比例
之 奈米氧化鎂MgO、奈米氧化鈦TiO2以及奈米氧化鋯ZrO2等添加物 ，探討奈米添加物對於玻璃基鑽石工具之晶體結構、熱性質與機械性質之影響。添加的奈米粉末分別以混練及重熔方式加入基地相中，各種粉末試片先進行熱分析，試片燒結完成後再以X光繞射儀分析是否有新的結晶相出現，並進行各種機械性能試驗。此外也使用掃描式電子顯微鏡觀察鑽石粉末與玻璃之結合情形，並進行磨耗比測試，以了解不同比例奈米添加物對玻璃基鑽石工具試片性能之影響。

For improve the performance of the vitirfied bond diamond tools, various proportions of the nano MgO, nano TiO2, and nano ZrO2 were added to the glass matrix of the diamond tools. The influence of nano additives on the crystal structure, and mechanical properties of the vitrified bond diamond tools were discussed. The nano powders were added to the glass matrix by mixing or remelting. The various powders are first subjected to a thermal analysis. The sintered specimens were then preceding X-ray diffraction analyzes to confirm whether there are new crystalline phases formation, and various Mechanical properties test were also executed. In addition, a scanning electron microscope was used to observe the bonding between the diamond grits and vitirfied matrix, and a wear ratio test was performed to comprehend the effect of various nano additives on the performance of vitrified bond diamond tools.

摘 要.....................................................................I
ABSTRACT..................................................................II
誌 謝...................................................................III
目 錄....................................................................IV
表目錄...................................................................VII
圖目錄..................................................................VIII

第一章 緒論.................................................................1
1.1前言....................................................................1
1.2研究動機與目的...........................................................2
第二章 玻璃基鑽石材料介紹....................................................3
2.1 鑽石與工業用途..........................................................3
2.1.1鑽石簡介...............................................................3
2.1.2鑽石晶體結構與物理性質..................................................4
2.2鑽石工具應用.............................................................6
2.2.1鑽石工具簡介...........................................................6
2.2.2鑽石工具研磨特性.......................................................7
2.2.3鑽石砂輪構造與結合種類..................................................7
2.2.4鑽石砂輪結合基材.......................................................9
2.3玻璃簡介................................................................11
2.3.1玻璃概述..............................................................11
2.3.2玻璃基地相成分........................................................11
2.3.3玻璃的表面張力........................................................14
2.3.4玻璃的強度............................................................14
2.3.5玻璃的缺陷............................................................15
2.3.6玻璃的脆性和硬度......................................................16
2.4奈米粉末的基本概述.......................................................17
2.4.1氧化鎂的簡介..........................................................17
2.4.2氧化鋯的簡介..........................................................17
2.4.3氧化鈦的簡介..........................................................17
2.5燒結概述................................................................18
2.5.1燒結原理..............................................................18
2.5.2影響燒結的因素........................................................20
2.5.3燒結鑽石特性..........................................................21
第三章 實驗過程............................................................22
3.1實驗流程................................................................22
3.2試片製作................................................................27
3.3重熔試片製作流程........................................................31
3.4燒结流程................................................................31
3.5分析項目................................................................33
【1】DSC熱分析.............................................................33
【2】徑向收縮率分析.........................................................34
【3】硬度值分析............................................................34
【4】XRD(X-ray diffraction)分析............................................35
【5】微結構SEM(Scanning Electron Microscope)分析...........................36
【6】磨耗性能分析..........................................................37
【6】碳化鎢磨耗表面粗糙度量測...............................................38
第四章 實驗結果與討論......................................................39
4.1熱分析.................................................................39
4.2徑向收縮率量測..........................................................43
4.3硬度量測................................................................45
4.4 XRD分析結果............................................................46
4.5SEM表面微結構分析.......................................................50
4.6磨耗量測................................................................54
4.7碳化鎢磨耗表面粗糙度量測.................................................54
第五章 結論................................................................56
參考文獻...................................................................57
附 錄..................................................................62

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