跳到主要內容

臺灣博碩士論文加值系統

(100.28.2.72) 您好!臺灣時間:2024/06/16 09:03
字體大小: 字級放大   字級縮小   預設字形  
回查詢結果 :::

詳目顯示

我願授權國圖
: 
twitterline
研究生:江佳恩
研究生(外文):CHIANG, JIA-EN
論文名稱:含氮雜環與雙咔唑衍生物材料之電致變色轉換和紫外光-可見光-近紅外光光譜性質研究
論文名稱(外文):Electrochromic Switching and UV-Visible-NIR Spectral Properties of Nitrogen-Containing Heterocycles and Dicarbazole Derivatives
指導教授:吳知易
指導教授(外文):WU, TZI-YI
口試委員:粘譽薰郭仲文李立鼎
口試委員(外文):Nien, YU-HSUNKuo, CHUNG-WENLEE, LI-TING
口試日期:2021-07-15
學位類別:碩士
校院名稱:國立雲林科技大學
系所名稱:化學工程與材料工程系
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2021
畢業學年度:109
語文別:中文
論文頁數:250
中文關鍵詞:共軛導電高分子電致變色元件電致變色咔唑異噁唑
外文關鍵詞:Conjugated conductive polymerelectrochromic deviceelectrochromismcarbazoleisoxazole
相關次數:
  • 被引用被引用:0
  • 點閱點閱:136
  • 評分評分:
  • 下載下載:0
  • 收藏至我的研究室書目清單書目收藏:0
摘要 i
Abstract ii
誌謝 iii
目錄 iv
表目錄 vii
圖目錄 xv
第一章、緒論 1
1-1 前言: 1
1-2 變色效應: 2
1-2-1 光致變色(Photochromism): 2
1-2-2 熱致變色(Thermochromism): 2
1-2-3 電致變色 (Electrochromism): 3
1-3 電致變色介紹: 4
1-3-1電致變色簡介: 4
1-3-2電致變色機制: 5
1-3-3 電致變色元件結構: 6
1-3-4 電致變色之基本參數: 7
第二章、文獻回顧與研究動機 10
2-1文獻回顧: 10
2-2 研究動機: 24
第三章、實驗方法與步驟 26
3-1 實驗系統流程圖: 26
3-2 實驗藥品: 27
3-3 實驗方法: 28
3-3-1 薄層層析法: 28
3-3-2 管柱層析法: 28
3-4 實驗設備: 29
3-5 實驗合成: 30
3-5-1 S-N-S陽極材料導電高分子之單體合成 30
3-5-2 CzBN陽極材料導電高分子之單體合成 45
3-5-3 ProDOT陰極材料導電高分子之單體合成: 54
3-5-4 離子液體合成 58
3-5-5 高分子導電薄膜合成 60
3-6實驗裝置 61
3-6-1 ITO導電基板之前處理 61
3-6-2 電化學聚合 61
3-6-3 五種導電高分子薄膜單電極之光學性質測試 62
3-6-4 五種導電高分子元件之光學性質測試 63
第四章、結果與討論 65
4-1 五種導電高分子化學特性探討及研究: 65
4-1-1 五種導電高分子電解液之選擇: 65
4-1-2 五種導電高分子起始氧化電位: 66
4-2 定電位法電化學聚合: 70
4-2-1 五種陽極導電高分子之電化學聚合: 70
4-2-2 PProDOT結構之陰極導電高分子電化學聚合: 73
4-3 五種導電高分子薄膜之氧化還原能力分析 74
4-4 五種導電高分子薄膜之單電極光學性質分析: 81
4-4-1 五種導電高分子之單電極吸收光譜: 81
4-4-2 五種導電高分子之單電極HOMO與LUMO能階: 102
4-4-3 五種導電高分子之單電極穿透度變化值 103
4-4-4 五種導電高分子單電極之轉換時間、穩定性及著色效率探討 114
4-5 兩種陰極導電高分子薄膜之單電極光學性質分析 120
4-6 五種導電高分子之元件光學性質分析: 127
4-6-1五種導電高分子元件之吸收光譜: 127
4-6-2 五種導電高分子之元件穿透度變化值 167
4-6-3 五種導電高分子元件之轉換時間、穩定性及著色效率探討 178
4-6-4 五種導電高分子元件之循環電化學穩定性 189
4-6-5 五種導電高分子元件之光學記憶效應探討 197
4-7 五種導電高分子單電極與元件之相關文獻比較 205
第五章、結論 214
參考文獻 216

[ ] 段景春,「京都協議書與溫室效應」,濮陽職業技術學院學報,vol 18,16-17,2005。
[ ] 環境資訊中心:全球暖化禍首
https://e-info.org.tw/node/118006
[ ] 沈慶月,「光致變色材料的研究與應用」,材料報導,vol 10,31-35,2005。
[ ] 維基百科:熱致變色https://zh.wikipedia.org/wiki/%E7%83%AD%E8%87%B4%E5%8F%98%E8%89%B2
[ ] J. R. Platt, "Electrochromism, a possible change of color producible in dyes by and electric field", The Journal of Chemical Physics, vol 34, 862-863, 1961.
[ ] 智能窗https://kknews.cc/zh-hk/tech/n6xj2xq.html
[ ] 黃文昌,「一般報導:電致變色」,科學發展,vol 549,68-72,2018。
[ ] 普魯士藍:顏料歷史的關鍵https://zhuanlan.zhihu.com/p/30632629
[ ] 群青:曾經最昂貴的顏料https://mp.weixin.qq.com/s?__biz=MzI3NDYwNDQ4OA==&mid=2247484141&idx=1&sn=628f5697f0ab1a95b6561a963d9d640a&chksm=eb10ca4adc67435cc9627604c9bd0d05dcefc3ded101be9d0799f30e0ed6f6b04fd2fd996520&scene=21#wechat_redirecthttps://mp.weixin.qq.com/s?__biz=MzI3NDYwNDQ4OA==&mid=2247484141&idx=1&sn=628f5697f0ab1a95b6561a963d9d640a&chksm=eb10ca4adc67435cc9627604c9bd0d05dcefc3ded101be9d0799f30e0ed6f6b04fd2fd996520&scene=21#wechat_redirect
[ ] S. K. Deb, "A novel electrophotographic system", Optical Society of America, vol 8, 192-195, 1969.
[ ] S. Varis, M. Ak, C. TanyeliIdris, M. Akhmedov and L. Toppare, "Synthesis and characterization of a new soluble conducting polymer and its electrochromic device",Solid State Sciences, vol 8, 1477-1483, 2006.
[ ] P. Monk, R. Mortimer and D. Rosseinsky, "Electrochromism and electrochromic devices", Cambridge University Press, vol 6, 777-780, 2007.
[ ] 魏志福,「薄層色譜-光密度法分離分析原油族組成」,地球化學,vol 39,381-385,2010。
[ ] W. A. Gazotti Jr, G. Casalbore‐Miceli, A .Geri and M. A. A. de Paoli, " Solid‐state electrochromic device based on two optically complementary conducting polymers", Advanced Materials, vol 10, 60-64, 1998.
[ ] 國際照明委員會CIE體系:
http://www.charts.kh.edu.tw/teaching-web/98color/color2-3.htm
[ ] B. Hu, C. Li, Z. Liu, X. Zhang, W. Luo and L. Jin, "Synthesis and multi-electrochromic properties of asymmetric structure polymers based on carbazole-EDOT and 2,5–dithienylpyrrole derivatives", Electrochimica Acta, vol 305, 1-10, 2019.
[ ] E. Tutuncu, M. I. Ozkut, B. Balci, H. Berk and A. Cihaner, "Electrochemical and optical characterization of a multielectrochromic copolymer based on 3,4-ethylenedioxythiophene and functionalized dithienylpyrrole derivative", European Polymer Journal, vol 110, 233-239, 2019.
[ ] D. Zhang, M. Cai, Z. Bin, Y. Zhang, D. Zhang and L. Duan, "Highly efficient blue thermally activated delayed fluorescent OLEDs with record-low driving voltages utilizing high triplet energy hosts with small singlet–triplet splittings", Chemical Science, vol 7, 3355-3363, 2016.
[ ] G. Tahtali, Z. Has, C. Doyranli, C. Varlikli and S. Koyuncu, "Solution processable neutral state colourless electrochromic devices: effect of the layer thickness on the electrochromic performance", Journal of Materials Chemistry, vol 4, 10090-10094, 2016.
[ ] A. A. Argun, P. H. Aubert, B. C. Thompson, I. Schwendeman, C. L. Gaupp, J. Hwang, N. J. Pinto, D. B. Tanner, A. G. MacDiarmid and J. R. Reynolds, "Multicolored electrochromism in polymers: structures and devices", Chemistry of Materials, vol 16, 4401-4412, 2004.
[ ] S. Janietz and B. Schulz, "Electrochemical investigations on poly(arylene-1,3,4- oxadiazole)s", European Polymer Journal, vol 32, 465-474, 1996.
[ ] P. A. Chicheva, K. A. Chudov, K. S. Levchenko, N. O. Poroshin, P. S. Shmelin and E. P. Grebennikov, "The study of the electrochemical properties of new electrochromic compounds based on 3-aryl-4,5-bis(pyridin-4-yl)isoxazoles derivatives", Journal of Physics: Conference Series, vol 1347, 1565-1569, 2019.
[ ] K. Akira, F. Hiroki and Y. Takakazu, "Chemical and electrochemical oxidation of thiophene-pyridine and thiophene-pyrimidine co-oligomers in solutions", The Journal of Physical Chemistry B, vol 111, 8020-8026, 2007.
[ ] X. Lin, N. Li, W. Zhang, Z. Huang, Q. Tang, C. Gong and X. Fu, "Synthesis and electrochromic properties of benzonitriles with various chemical structures", Dyes and Pigments, vol 171, 107783-107790, 2019.
[ ] M. İ. Özkut, J. Mersini, A. M. Önal and A. Cihaner, " Substituent and heteroatom effects on the electrochromic properties of similar systems", Journal of Polymer Science Part A: Polymer Chemistry, vol 50, 615-621, 2012.
[ ] J. H. Huang, C. Y. Hsu, C. W. Hu, C. W. Chu and C. K. Ho,"The influence of charge trapping on the electrochromic performance of poly(3,4-alkylenedioxythiophene) derivatives", ACS Applied Materials & Interfaces, vol 2, 351-359, 2010.
[ ] K. Tanaka, T. Shichiri and T. Yamabe, "Electronic properties of mislinked polypyrrole and polythiophene", Synthetic Metals, vol 14, 271-277, 1986.
[ ] Y. W. Chen-Yang, J. L. Li, T. L. Wu, W. S. Wang, and T. F. Hon, "Electropolymerization and electrochemical properties of (N-hydroxyalkyl) pyrrole/pyrrole copolymers", Electrochimica Acta, vol 49, 2031-2040, 2004.
[ ] B. Krische and M. Zagorska, "The polythiophene paradox", Synthetic Metals, vol 28, 263-268, 1989.
[ ] J. P. Ferraris and G. D. Skiles, "Substitutional alloys of organic polymeric conductors", Polymer, vol 28, 179-182, 1987.
[ ] J. F. Ambrose and F. A. Nelson, "Anodic oxidation pathways of carbazoles I. Carbazole and N-substituted derivatives", Electrochem, vol 115, 1159-1164, 1968.
[ ] P. Baronas, K. Kazlauskas, A. Gruodis, V. Jankauskas, A. Tomkeviciene, J. Simokaitiene and S. Jursenas, "High-triplet-energy carbazole and fluorene tetrads", Journal of Luminescence, vol 169, 256-265, 2015.
[ ] MONASH University:CH Instruments electrochemical workstation
http://www.xwzhang-group.com/instruments.html
[ ] Organic Chemistry Portal:Paal-Knorr Pyrrole Synthesis
https://www.organic-chemistry.org/namedreactions/paal-knorr-pyrrole-synthesis.shtm
[ ] Organic Chemistry Portal:Huisgen Cycloaddition 1,3-Dipolar
https://www.organic-chemistry.org/namedreactions/huisgen-1,3-dipolar-cycloaddition.shtm
[ ] Y. Dai, W. Li, X. Qu, J. Liu, S. Yan, M. Ouyang, X. Lv and C. Zhang, "Electrochemistry, electrochromic and color memory properties of polymer/copolymer based on novel dithienylpyrrole structure", Electrochimica Acta, vol 229, 271-280, 2017.
[ ] E. Oguzhan, H. Bilgili, F. B. Koyuncu, E. Ozdemir and S. Koyuncu, "A new processable donoreacceptor polymer displaying neutral state yellow electrochromism", Polymer, vol 54, 6283-6292, 2013.
[ ] N. Guven and P. Camurlu, "Electrosyntheses of anthracene clicked poly(thienylpyrrole)s and investigation of their electrochromic properties", Polymer, vol 73, 122-130, 2015.
[ ] P. Camurlu, Z. Bicil, C. Gültekin and N. Karagoren, "Novel ferrocene derivatized poly(2,5-dithienylpyrrole)s: Optoelectronic properties, electrochemical copolymerization", Electrochimica Acta, vol 63, 245-250, 2012.
[ ] T. Soganci, H. C. Soyleyici and M. Ak, "Fabrication of multifunctional 2,5-di(2-thienyl) pyrrole based conducting copolymer for further sensor and optoelectronic applications", Journal of The Electrochemical Society, vol 165, 941-953, 2018.
[ ] W. H. Wang, J. C. Chang and T. Y. Wu, "4-(Furan-2-yl)phenyl-containing polydithienylpyrroles as promising electrodes for high contrast and coloration efficiency electrochromic devices", Organic Electronics, vol 74, 23-32, 2019.
[ ] S. Cai, H. Wen, S. Wang, H. Niu, C. Wang, X. Jiang, X. Bai and W. Wang, "Electrochromic polymers electrochemically polymerized from 2,5–dithienylpyrrole (DTP) with different triarylamine units: Synthesis, characterization and optoelectrochemical properties", Electrochimica Acta, vol 228, 332-342, 2017.
[ ] J. C. Lai, X. R. Lu, B. T. Qu, F. Liu, C. H. Li and X. Z. You," A new multicolored and near-infrared electrochromic material based on triphenylamine-containing poly(3,4-dithienylpyrrole) ", Organic Electronics, vol 15, 3735-3745, 2014.
[ ] T. Soganci, H. C. Soyleyici, E. Giziroglu and M. Ak, "Processable amide substituted 2,5-bis(2-thienyl)pyrrole based conducting polymer and its fluorescent and electrochemical properties", Journal of the Electrochemical Society, vol 163, 1096-1103, 2016.
[ ] T. Y. Wu and J. L. Li, "Electrochemical synthesis, optical, electrochemical and electrochromic characterizations of indene and 1,2,5-thiadiazolebased poly(2,5-dithienylpyrrole) derivatives", RSC Advances. vol 6, 15988-15998, 2016.
[ ] T. Soganci, O. Gumusay, H. C. Soyleyici and M. Ak, "Synthesis of highly branched conducting polymer architecture for electrochromic applications", Polymer, vol 134, 187-195, 2018.
[ ] G. Wang, X. Fu, J. Huang, L. W. and J. Deng. "Synthesis, electrochemical and fluorescence properties of three new dithienylpyrroles bearing aromatic amine units", Journal of Electroanalytical Chemistry, vol 661, 351-358, 2011.
[ ] 謝瑋哲,「以多元咔唑與雙噻吩衍生物合成共聚物及其在電致變色元件之應用」,化學工程與材料工程系,國立高雄科技大學,98,2020。
[ ] P. Camurlu, Z. Bicil, C. Gültekin and N. Karagoren, "Novel ferrocene derivatized poly(2,5-dithienylpyrrole)s:optoelectronic properties, electrochemical copolymerization", Electrochimica Acta, vol 63, 245-250, 2012.
[ ] I. Yagmur, M. Ak and A. Bayrakceken, "Fabricating multicolored electrochromic devices using conducting copolymers", Smart Materials and Structures, vol 22, 115-122, 2013.
[ ] E. Yildiz, P. Camurlu, C. Tanyeli, I. Akhmedov and L. Toppare, "A soluble conducting polymer of 4-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)benzenamine and its multichromic copolymer with EDOT", Journal of Electroanalytical Chemistry, vol. 612, 247-256, 2008.
[ ] B. Hu, C. Y. Li, J. W. Chu, Z. C. Liu, X. L. Zhang and L. Jin, "Electrochemical and electrochromic properties of polymers based on 2,5-di(2-thienyl)-1H-pyrrole and different phenothiazine units", Journal of the Electrochemical Society, vol 166, 1-11, 2019.
[ ] S. Koyuncu and F. B. Koyuncu, "A new ITO-compatible side chain-functionalized multielectrochromic polymer for use in adaptive camouflage-like electrochromic devices", Reactive and Functional Polymers, vol 131, 174-180, 2018.
[ ] C. W. Kuo, T. Y. Wu and M. W. Huang, "Electrochromic characterizations of copolymers based on 4,4-bis(N-carbazolyl)-1,1-biphenyl and indole-6-carboxylic acid and their applications in electrochromic devices", Journal of the Taiwan Institute of Chemical Engineers, vol 68, 481-488, 2016.
[ ] Y. S. Su and T. Y. Wu, "Three carbazole-based polymers as potential anodically coloring materials for high-contrast electrochromic devices", Polymers, vol 9, 125-135, 2017.
[ ] B. Wang, J. Zhao, R. Liu, J. Liu and Q. He, "Electrosyntheses, characterizations and electrochromic properties of a copolymer based on 4,4'-di(N-carbazoyl)biphenyl and 2,2'-bithiophene", Solar Energy Materials and Solar Cells, vol 95, 1867-1874, 2011.
[ ] O. Usluer, S. Koyuncu, S. Demic and R. A. J. Janssen, "A novel high-contrast ratio electrochromic material from spiro[cyclododecane-1,9'- fluorene]bicarbazole", Journal of Polymer Science Part B: Polymer Physics, vol 49, 333-341, 2011.
[ ] G. Tahtali, Z. Has, C. Doyranli, C. Varlikli and S. Koyuncu, "Solution processable neutral state colourless electrochromic devices: effect of the layer thickness on the electrochromic performance", Journal of Materials Chemistry C, vol 4, 10090-10094, 2016.
[ ] S. Koyuncu, B. Gultekin, C. Zafer, H. Bilgili, M. Can, S. Demic, İ. Kaya and S. Icli, "Electrochemical and optical properties of biphenyl bridged-dicarbazole oligomer films: Electropolymerization and electrochromism", Electrochimica Acta, vol 54, 5694-5702, 2009.

電子全文 電子全文(網際網路公開日期:20260824)
QRCODE
 
 
 
 
 
                                                                                                                                                                                                                                                                                                                                                                                                               
第一頁 上一頁 下一頁 最後一頁 top
1. 含亞胺之聚二噻吩一吡咯電致變色材料合成、光學及電化學性質探討
2. 含亞胺的聚二噻吩基吡咯電致變色材料之合成及光電化學性質探討
3. 含有二苯基芘基胺結構的電致變色聚合物薄膜之電化學合成及其光電性質
4. 含雙咔唑取代基團之三苯胺及N-苯基咔唑衍生物的電聚合高分子薄膜之製備及其光電特性
5. 含有吩噻嗪-三苯胺或氰苯基咔唑結構的聚醯胺之合成及其光電性質
6. 高對比近紅外光電致變色共軛高分子的電化學合成與光電性質研究
7. 吡咯-三苯胺衍生物及其電聚合物之合成及光電性質
8. 含氮雜環材料之合成與光電鑑定
9. 取代基和連接基對於三苯胺衍生物的電化學及光學性質之影響
10. 以多元咔唑與雙噻吩衍生物合成共聚物及其在電致變色元件之應用
11. 以吲哚、咔唑及二噻吩基乙烯分別與噻吩衍生物合成共聚物並進行光學及電化學性質探討
12. 含10,11-二氫化-5H-二苯[b,f]氮呯結構之聚(芳香胺-醯亞胺)與聚(芳香胺-醯胺)的電化學合成與電致變色性質之研究
13. 具多個三苯胺或N-苯基咔唑封端基的雙(三苯胺)所衍生的高度交聯聚芳香胺之電化學合成及其電致變色性質
14. 含N-甲基咪唑、三氟甲基苯及N-苯基咔唑之聚二噻吩一吡咯電致變色材料合成、光學及電化學性質探討
15. 三芳香胺聚合物及二腈衍生物之合成及光電性質
 
無相關期刊