跳到主要內容

臺灣博碩士論文加值系統

(44.201.92.114) 您好!臺灣時間:2023/03/31 08:45
字體大小: 字級放大   字級縮小   預設字形  
回查詢結果 :::

詳目顯示

我願授權國圖
: 
twitterline
研究生:江韋成
研究生(外文):Wei-Cheng Jiang
論文名稱:奈米銀線之量產合成及其應用
論文名稱(外文):Mass production synthesis and application of silver nanowires
指導教授:陳建忠陳建忠引用關係
指導教授(外文):Chien-Chong Chen
口試委員:李茂田李元堯張仁瑞陳建忠
口試委員(外文):Maw-Tien LeeYuan-Yao LiJen-Ray ChangChien-Chong Chen
口試日期:2022-07-15
學位類別:碩士
校院名稱:國立中正大學
系所名稱:化學工程研究所
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2022
畢業學年度:110
語文別:中文
論文頁數:156
中文關鍵詞:奈米銀線量產合成無PVP多元醇合成透明導電薄膜薄膜加熱器使用高透光拉伸感測器感測器人體運動監測
外文關鍵詞:silver nanowiresmass production synthesisPVP-free polyol synthesistransparent conductive filmsuse of film heaterhigh transmission stretch sensorssensor human motion monitoring
相關次數:
  • 被引用被引用:0
  • 點閱點閱:64
  • 評分評分:
  • 下載下載:0
  • 收藏至我的研究室書目清單書目收藏:0
目錄
誌謝 I
摘要 II
目錄 VII
圖目錄 XI
第一章 介紹 1
1-1 奈米銀線之合成回顧 1
1-2 奈米銀線反應機制與反應式 2
1-3 奈米銀線薄膜之回顧 4
1-4 奈米銀線感測器之回顧 5
1-5 研究動機及目的 6
第二章 實驗材料及實驗方法 7
2-1實驗藥品與儀器設備 7
2-1.1實驗藥品 7
2-1.2實驗儀器設備 7
2-2 實驗步驟 7
2-2-1製備Fe(NO3)3溶液及NaCl溶液前驅物溶液 7
2-2-2單杯放大五/二十五倍單次使用烘箱合成一/五/十杯並嘗試三種反應時間(14/30/100min) 8
2-2-3使用培養皿加大受熱面積合成二十五倍並嘗試兩種反應時間(25/50min) 8
2-2-4使用鐵盤加大受熱面積合成二十五倍並嘗試兩種反應時間(25/50min) 8
2-2-5合成完成的奈米銀線處理及檢測 9
2-2-6配置奈米銀線分散液 9
2-2-7使用抽氣過濾空氣乾燥的奈米銀線進行噴塗 9
2-2-8使用抽氣過濾氬氣乾燥的奈米銀線進行噴塗 9
2-2-9使用抽氣過濾未乾燥的奈米銀線進行噴塗及縮小玻璃片噴塗面積 10
2-2-10離心處理過程 10
2-2-11使用離心處理的奈米銀線進行噴塗 10
2-2-12 SR薄膜製備 11
2-2-13奈米銀線薄膜製備(SR基底) 11
2-2-14奈米銀線薄膜製備(SR基底) (大面積) 11
2-2-15 升溫測試實驗步驟 11
2-2-16人體手部加溫實驗步驟 11
2-2-17感測器製備 12
2-2-18 不同拉伸量的實驗步驟: 12
2-2-19 手指彎曲測試實驗步驟: 12
2-2-20眨眼測試實驗步驟: 12
2-2-21感測器熱退火處理實驗步驟 13
2-2-22脈搏測試實驗步驟 13
2-2-23感測器多點量測(吃東西情境)實驗步驟 13
2-2-24感測器量測腹式呼吸實驗步驟 13
2-2-25感測器多點量測(驚嚇情境)實驗步驟 13
2-2-26感測器判別食物軟硬度及辨別不同水溫實驗步驟 14
2-2-27具透明度的奈米銀線感測器應用測試步驟 14
第三章 結果與討論 15
3-1 奈米銀線合成 15
3-1-1 UV/Vis 奈米銀線長徑比預測表及XRD奈米銀線長徑比預測表的建立 15
3-1-2單杯放大五倍單次使用烘箱合成五杯並嘗試兩種反應時間(14/30min) 15
3-1-3單杯放大二十五倍單次使用烘箱合成一杯並嘗試一種反應時間(100min) 17
3-1-4單杯放大二十五倍單次使用烘箱合成十杯並嘗試一種反應時間(100min) 18
3-1-5使用培養皿加大受熱面積合成二十五倍並嘗試兩種反應時間(25/50min) 19
3-1-6使用鐵盤加大受熱面積合成二十五倍並嘗試兩種反應時間(15/30min) 20
3-1-7 奈米銀線合成成本計算及與市價做比較 21
3-2奈米銀線薄膜製備 22
3-2-1 使用抽氣過濾空氣乾燥的奈米銀線進行噴塗 22
3-2-2 使用抽氣過濾氬氣乾燥的奈米銀線進行噴塗 22
3-2-3 使用抽氣過濾未乾燥的奈米銀線進行噴塗 22
3-2-4 使用抽氣過濾未乾燥的奈米銀線進行噴塗 (縮小噴塗範圍) 23
3-2-5使用離心處理的奈米銀線進行噴塗 23
3-3奈米銀線薄膜升溫及用於手部加溫 24
3-3-1 奈米銀線薄膜不同電壓下的升溫(玻璃基底) 24
3-3-2 奈米銀線薄膜3V電壓下的升溫及用於人體手部加溫(SR基底) 24
3-3-3 奈米銀線薄膜3V電壓下(連接電池座)的升溫及用於人體手部加溫(SR基底) 25
3-3-4 奈米銀線薄膜15V電壓下的升溫及用於人體手部加溫(大面積) 25
3-4高透光奈米銀線感測器測試 26
3-4-1 感測器不同初始電阻下測量其透光率及不同拉伸量的電阻變化率 26
3-4-2 手指彎曲測試 27
3-4-3 眨眼測試 27
3-4-4 脈搏測試 27
3-4-5 將感測器進行熱退火處理以用來作為溫度感測器使用 27
3-4-6 感測器多點量測(吃東西情境) 28
3-4-7 感測器量測腹式呼吸 29
3-4-8感測器多點量測(驚嚇情境) 29
3-4-9感測器區別出食物軟硬度的不同 30
3-4-10 感測器區別出判別溫度不同的水 30
3-4-11具透明度的奈米銀線感測器應用 31
第四章 研究自評 32
第五章 結論 33
第六章 未來展望 34
參考文獻 35
圖片說明 41
圖片 50


[1]S. Coskun, B. Aksoy, and H. Unalan, ’’ Polyol Synthesis of Silver Nanowires: An Extensive Parametric Study’’, 2011, Crystal Growth and Design, 11, P4963-4969.
[2]H. Ding, Y. Zhang, G. Yang, S. Zhang, L. Yua and P. Zhanga, ’’Large scale preparation of silver nanowires with different diameters by a one-pot method and their application in transparent conducting films’’, 2016, RSC Advanced, 10, P8096-8102.
[3]Z. Yi, X. Xu, X. Tand, L. Liu, W. Zhang, Y. Yi, J. Luo, W. Yao, Y. Yi, T. Duan, Y. Tang, ’’Microwave-assisted polyol method rapid synthesis of high quality and yield Ag nanowires’’, 2017, Surface and Coatings Technology, 327, P118-115.
[4]S. Fahad, H. Yu, L. Wang, Z. Abdin, M. Haroon, R. Ullah, A. Nazir, K. Naveed, T. Elshaarani and A. Khan, ’’Recent progress in the synthesis of silver nanowires and their role as conducting materials’’, 2019, Journal of Materials Science, 54, P997-1035.
[5]H. Wang, X. Qiao, J. Chen, X. Wang, S. Ding, ’’Mechanisms of PVP in the preparation of silver nanoparticles’’, 2005, Materials Chemistry and Physics, 9, P449-453.
[6]J. Jiu, T. Sugahara, M. Nogi and K. Suganuma, ’’Ag nanowires: large-scale synthesis via a trace-salt-assisted solvothermal process and application in transparent electrodes’’, 2013, Journal of Nanoparticle Research, 15, P1588-1592.
[7]K. Jyoti, M. Baunthiyal, A. Singh, ’’Characterization of silver nanoparticles synthesized using Urtica dioica Linn. leaves and their synergistic effects with antibiotics’’, 2016, Research and Applied Science, 9, P217-227.
[8]D. Li, T. Han, L. Zhang, H. Zhang and H. Chen, ’’Flexible transparent electrodes based on silver nanowires synthesized via a simple method’’, 2017, Royal Society Open Science, 4, P170-178.
[9]P. Phanjom, G. Ahmed, ’’Biosynthesis of Silver Nanoparticles by Aspergillus oryzae and Its Characterizations’’, 2015, Nanoscience and Nanotechnology, 5, P14-21.
[10]A. M. Awwad1, N. Salem and A. O. Abdeen, ’’Green synthesis of silver nanoparticles using carob leaf extract and its antibacterial activity’’, 2013, International Journal of Industrial Chemistry, 4, P29-34.
[11]K. Anandalakshmi, J. Venugobal and V. Ramasamy, ’’Characterization of silver nanoparticles by green synthesis method using Pedalium murex leaf extract and their antibacterial activity’’, 2015, Applied Nanoscience, 6, P399-408.
[12]K. Shameli, M. B. Ahmad, A. Zamanian, P. Sangpour, P. Shabanzadeh, ’’Green biosynthesis of silver nanoparticles using Curcuma longa tuber powder’’, 2012, International Journal of Nanomedicine, 7, P5603-5610.
[13]B. K. Mehta1, M. Chhajlani1 and B. D. Shrivastava, ’’Green synthesis of silver nanoparticles and their characterization by XRD’’, 2016, Journal of Physics, 836, P7-8.
[14]K. Paulkumar, G. Gnanajobitha, M. Vanaja, S. Rajeshkumar, C. Malarkodi, K. Pandian, and Gurusamy, ’’Piper nigrum Leaf and Stem Assisted Green Synthesis of Silver Nanoparticles and Evaluation of Its Antibacterial Activity Against Agricultural Plant Pathogens’’, 2014, The Scientific World Journal, 2014, P1-9.
[15]Q. N. Luu, J. M. Doorn, M. T. Berry, C. Jiang, C. Lin , P. S. May, ’’Preparation and optical properties of silver nanowires and silver-nanowire thin films’’, 2011, Colloid and Interface Science, 256, P151-158.
[16]R.-L. Zong, J. Zhou, Q. Li, B. Du, B. Li, M. Fu, X.-W. Qi, and L.-T. Li, ’’Synthesis and Optical Properties of Silver Nanowire Arrays Embedded in Anodic Alumina Membrane’’, 2004, Physical Chemistry B, 108, P16713-16716.
[17]C. Chen, L. Wang , G. Jiang, J. Zhou, X. Chen, H. Yu and Q. Yang, ’’Study on the synthesis of silver nanowires with adjustable diameters through the polyol process’’, 2006, Nanotechnology, 17, P3933-3938.
[18]D. Chen, X. Qiao, X. Qiu, J. Chen, R. Jiang, ’’Convenient synthesis of silver nanowires with adjustable diameters via a solvothermal method’’, 2010, Colloid and Interface Science, 344, P289-291.
[19]E.-J. Lee, M.-H. Chang, Y.-S. Kim, and J.-Y. Kim, ’’High-pressure polyol synthesis of ultrathin silver nanowires: Electrical and optical properties’’, 2013, APL Materials, 1, P412-418.
[20]Y. Sun, Y. Yin, B. T. Mayers, T. Herricks and Y. Xia, ’’Uniform Silver Nanowires Synthesis by Reducing AgNO3 with Ethylene Glycol in the Presence of Seeds and Poly(Vinyl Pyrrolidone)’’, 2002, Chemistry of Materials, 14, P4736-4745.
[21]M. Chen, C. Wang, X. Wei, and G. Diao, ’’Rapid Synthesis of Silver Nanowires and Network Structures under Cuprous Oxide Nanospheres and Application in Surface-Enhanced Raman Scattering’’, 2013, Physical Chemistry C, 117, P13593-13601.
[22]R. F. Aroca, P. J. G. Goulet, D. S. dos Santos, R. A. Alvarez-Puebla and O. N. Oliveira, ’’Silver Nanowire Layer-by-Layer Films as Substrates for Surface-Enhanced Raman Scattering’’, 2004, Analytical Chemistry, 117, P378-382.
[23]W. Chen, J. Jiang, W. Zhang, T. Wang, J. Zhou, C.-H. Huang and X. Xie, ’’Silver Nanowire-Modified Filter with Controllable Silver Ion Release for Point-of-Use Disinfection’’, 2019, Environmental Science and Technology, 53, P7504-7512.
[24]H. Sim, C. Kim, S. Bok, M. K. Kim, G.-H. Lim, S. M. Cho and Byungk, ’’Five-minute synthesis of silver nanowires and their roll-to-roll processing for large-area organic light emitting diodes film’’, 2018, Nanoscale, 25, P12087-12092.
[25]X. Zeng, Q. Zhang, R. Yu and C. Lu, ’’A New Transparent Conductor: Silver Nanowire Film Buried at the Surface of a Transparent Polymer’’, 2010, Advanced Materials, 22, P4484-4488.
[26]L. Hu, H. Kim, J. Lee, P. Peumans and Y. Cui, ’’Scalable Coating and Properties of Transparent, Flexible, Silver Nanowire Electrodes’’, 2010, ACS Nano, 4, P2955-2963.
[27]W. Jo, H. Kang, J. Choi, H. Lee and H. Kim, ’’Plasticized Polymer Interlayer for Low-Temperature Fabrication of a High-Quality Silver Nanowire-Based Flexible Transparent and Conductive Film’’, 2010, ACS Applied Materials and Interfaces, 9, P15114-15121.
[28]C.-H. Liu, X. Yu, ’’Silver nanowire-based transparent, flexible, and conductive thin film’’, 2011, Nanoscale Research Letters, 6, P75-82.
[29]V. Scardaci , R. Coull, P. Lyons, D. Rickard and J. Coleman, ’’Spray Deposition of Highly Transparent, Low-Resistance Networks of Silver Nanowires over Large Areas’’, 2011, Small, 18, P2621-2628.
[30]A. Kumar, C. Bae, L. Piao, S. Kim, ’’Silver nanowire based flexible electrodes with improved properties: High conductivity, transparency, adhesion and low haze’’, 2013, Materials Research Bulletin, 48, P2944-2949.
[31]M. Amjadi, A. Pichitpajongkit, S. Lee, S. Ryu and I. Park, ’’Highly Stretchable and Sensitive Strain Sensor Based on Silver NanowireElastomer Nanocomposite’’, 2014, ACS Nano, 5, P5154-5163.
[32]D. Jiang, Y. Wang, B. Li, C. Sun, Z. Wu, H. Yan, L. Xing, S. Qi, Y. Li, H. Liu, W. Xie, X. Wang, T. Ding and Z. Guo, ’’Flexible Sandwich Structural Strain Sensor Based on Silver Nanowires Decorated with Self-Healing Substrate’’, 2019, Macromolecular Materials and Engineering, 304, P1974-1978.
[33]S. Sheng, L. Lihua, J. Aoqun, D. Qianqian, J. Jianlong, Z. Qiang and Z. Wendong, ’’Highly sensitive wearable strain sensor based on silver nanowires and nanoparticles’’, 2018, Nanotechnology, 29, P255202-255209.
[34]M. Lagrange, D. P. Langley, G. Giusti, C. Jiménez, Y. Bréchete and D. Bellet, ’’ptimization of silver nanowire-based transparent electrodes: effects of density, size and thermal annealing, Royal Society of Chemistry’’, 2015, Nanoscale, 7, P17410-17415.
[35]Z. Cui, F. R. Poblete and Y. Zhu, ’’Tailoring the Temperature Coefficient of Resistance of Silver Nanowire Nanocomposites and their Application as Stretchable Temperature Sensors’’, 2019, Applied Materials Interfaces, 11, P17836-17842.
[36]J. Young, D. Lee, G. Hoon Jun, H. J. Ryu and S. Hong, ’’High conductivity and stretchability of 3D welded silver nanowire filled graphene aerogel hybrid nanocomposites’’, 2017, Journal of Materials Chemistry C, 5, P8211-8220.
[37]何彥廷 ,「具無線、即時與陣列感測系統 (WRSAS)的開發與其在以奈米碳管紙為主體的陣列感測器之應用」 , 國立中正大學化學工程研究所碩博士論文 , 民國一百一十年。
[38]P. Zhang, I. Wyman, J. Hu, S. Lin, Z. Zhong, Y. Tu, Z. Huang, Y. Wei, ’’ Silver nanowires: Synthesis technologies, growth mechanism and multifunctional applications’’, 2017, Materials Science and Engineering: B, 223, P1-23.
[39]H. Sim, S. Bok, B. Kim, M. Kim, G. Lim, S. Cho and B. Lim, ’’ Organic-Stabilizer-Free Polyol Synthesis of Silver Nanowires for Electrode Applications’’, 2016, Nanotechnology, 55, P1-6.
[40]L. Gou, M. Chipara and J. M. Zaleski, ’’ Convenient, Rapid Synthesis of Ag Nanowires’’, 2007, Chemistry of Materials, 19, P1755-1760.
[41]S. Fahad, H. Yu, L. Wang, Z.-U. Abdin, M. Haroon, R. S. Ullah, A. Nazir, K.-U.-R. Naveed, T. Elshaarani and A. Khan, ’’ Recent progress in the synthesis of silver nanowires and their role as conducting materials’’, 2018, Journal of Materials Science, 54, P997–1035.
[42]M. Waynie, Schuette and W. E. Buhro, ’’ Silver Chloride as a Heterogeneous
Nucleant for the Growth of Silver Nanowires’’, 2013, ACS Nano, 14, P3844-3853.
[43] K. Y. Tan, Z. X. Hoy, P. L. Show, N. M. Huang, H. N. Lim, C. Y. Foo, ’’ Single droplet 3D printing of electrically conductive resin using high aspect ratio silver nanowires’’, 2021, Additive Manufacturing, 48, P102473-102484
[44] M. A. Hussein, E. M. Herzig, M. Schindler, F. Lohrer, C. M. Palumbiny,
W. Wang, S. V. Roth, P. M. Buschbaum, ’’ Comparative Study of the Nanomorphology of Spray and Spin Coated PTB7 Polymer: Fullerene Films’’, 2016, Polymer Engineering and Science, 56, P889-894








電子全文 電子全文(網際網路公開日期:20240902)
QRCODE
 
 
 
 
 
                                                                                                                                                                                                                                                                                                                                                                                                               
第一頁 上一頁 下一頁 最後一頁 top
無相關期刊