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研究生:江韋成
研究生(外文):Wei-Cheng Jiang
論文名稱:奈米銀線之量產合成及其應用
論文名稱(外文):Mass production synthesis and application of silver nanowires
指導教授:陳建忠陳建忠引用關係
指導教授(外文):Chien-Chong Chen
口試委員:李茂田李元堯張仁瑞陳建忠
口試委員(外文):Maw-Tien LeeYuan-Yao LiJen-Ray ChangChien-Chong Chen
口試日期:2022-07-15
學位類別:碩士
校院名稱:國立中正大學
系所名稱:化學工程研究所
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2022
畢業學年度:110
語文別:中文
論文頁數:156
中文關鍵詞:奈米銀線量產合成無PVP多元醇合成透明導電薄膜薄膜加熱器使用高透光拉伸感測器感測器人體運動監測
外文關鍵詞:silver nanowiresmass production synthesisPVP-free polyol synthesistransparent conductive filmsuse of film heaterhigh transmission stretch sensorssensor human motion monitoring
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目錄
誌謝 I
摘要 II
目錄 VII
圖目錄 XI
第一章 介紹 1
1-1 奈米銀線之合成回顧 1
1-2 奈米銀線反應機制與反應式 2
1-3 奈米銀線薄膜之回顧 4
1-4 奈米銀線感測器之回顧 5
1-5 研究動機及目的 6
第二章 實驗材料及實驗方法 7
2-1實驗藥品與儀器設備 7
2-1.1實驗藥品 7
2-1.2實驗儀器設備 7
2-2 實驗步驟 7
2-2-1製備Fe(NO3)3溶液及NaCl溶液前驅物溶液 7
2-2-2單杯放大五/二十五倍單次使用烘箱合成一/五/十杯並嘗試三種反應時間(14/30/100min) 8
2-2-3使用培養皿加大受熱面積合成二十五倍並嘗試兩種反應時間(25/50min) 8
2-2-4使用鐵盤加大受熱面積合成二十五倍並嘗試兩種反應時間(25/50min) 8
2-2-5合成完成的奈米銀線處理及檢測 9
2-2-6配置奈米銀線分散液 9
2-2-7使用抽氣過濾空氣乾燥的奈米銀線進行噴塗 9
2-2-8使用抽氣過濾氬氣乾燥的奈米銀線進行噴塗 9
2-2-9使用抽氣過濾未乾燥的奈米銀線進行噴塗及縮小玻璃片噴塗面積 10
2-2-10離心處理過程 10
2-2-11使用離心處理的奈米銀線進行噴塗 10
2-2-12 SR薄膜製備 11
2-2-13奈米銀線薄膜製備(SR基底) 11
2-2-14奈米銀線薄膜製備(SR基底) (大面積) 11
2-2-15 升溫測試實驗步驟 11
2-2-16人體手部加溫實驗步驟 11
2-2-17感測器製備 12
2-2-18 不同拉伸量的實驗步驟: 12
2-2-19 手指彎曲測試實驗步驟: 12
2-2-20眨眼測試實驗步驟: 12
2-2-21感測器熱退火處理實驗步驟 13
2-2-22脈搏測試實驗步驟 13
2-2-23感測器多點量測(吃東西情境)實驗步驟 13
2-2-24感測器量測腹式呼吸實驗步驟 13
2-2-25感測器多點量測(驚嚇情境)實驗步驟 13
2-2-26感測器判別食物軟硬度及辨別不同水溫實驗步驟 14
2-2-27具透明度的奈米銀線感測器應用測試步驟 14
第三章 結果與討論 15
3-1 奈米銀線合成 15
3-1-1 UV/Vis 奈米銀線長徑比預測表及XRD奈米銀線長徑比預測表的建立 15
3-1-2單杯放大五倍單次使用烘箱合成五杯並嘗試兩種反應時間(14/30min) 15
3-1-3單杯放大二十五倍單次使用烘箱合成一杯並嘗試一種反應時間(100min) 17
3-1-4單杯放大二十五倍單次使用烘箱合成十杯並嘗試一種反應時間(100min) 18
3-1-5使用培養皿加大受熱面積合成二十五倍並嘗試兩種反應時間(25/50min) 19
3-1-6使用鐵盤加大受熱面積合成二十五倍並嘗試兩種反應時間(15/30min) 20
3-1-7 奈米銀線合成成本計算及與市價做比較 21
3-2奈米銀線薄膜製備 22
3-2-1 使用抽氣過濾空氣乾燥的奈米銀線進行噴塗 22
3-2-2 使用抽氣過濾氬氣乾燥的奈米銀線進行噴塗 22
3-2-3 使用抽氣過濾未乾燥的奈米銀線進行噴塗 22
3-2-4 使用抽氣過濾未乾燥的奈米銀線進行噴塗 (縮小噴塗範圍) 23
3-2-5使用離心處理的奈米銀線進行噴塗 23
3-3奈米銀線薄膜升溫及用於手部加溫 24
3-3-1 奈米銀線薄膜不同電壓下的升溫(玻璃基底) 24
3-3-2 奈米銀線薄膜3V電壓下的升溫及用於人體手部加溫(SR基底) 24
3-3-3 奈米銀線薄膜3V電壓下(連接電池座)的升溫及用於人體手部加溫(SR基底) 25
3-3-4 奈米銀線薄膜15V電壓下的升溫及用於人體手部加溫(大面積) 25
3-4高透光奈米銀線感測器測試 26
3-4-1 感測器不同初始電阻下測量其透光率及不同拉伸量的電阻變化率 26
3-4-2 手指彎曲測試 27
3-4-3 眨眼測試 27
3-4-4 脈搏測試 27
3-4-5 將感測器進行熱退火處理以用來作為溫度感測器使用 27
3-4-6 感測器多點量測(吃東西情境) 28
3-4-7 感測器量測腹式呼吸 29
3-4-8感測器多點量測(驚嚇情境) 29
3-4-9感測器區別出食物軟硬度的不同 30
3-4-10 感測器區別出判別溫度不同的水 30
3-4-11具透明度的奈米銀線感測器應用 31
第四章 研究自評 32
第五章 結論 33
第六章 未來展望 34
參考文獻 35
圖片說明 41
圖片 50


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