臺灣博碩士論文加值系統

　　本研究利用濕式化學法於鋁箔紙上成長氧化鋅奈米片，鋁箔相較其他材料便宜，並將其用於光催化降解有機汙染物之應用。研究中探討在不同氧化鋅反應前驅物濃度下，所製備氧化鋅奈米片的表面形貌、晶體結構及元素組成，並在紫外光的照射下，針對不同氧化鋅反應前驅物濃度下，所製備氧化鋅奈米片於光催化降解甲基藍。此結果證實在氧化鋅反應前驅物濃度為50 mM時，所製備氧化鋅奈米片為光催化降解的最佳參數。後續針對於此氧化鋅奈米片進行循環測試及捕捉劑測試，藉以了解材料的穩定性及反應機制。
　　後續再藉由濕式化學法與氧化鋅奈米片上沉積硫化鎘奈米結構進而形成氧化鋅/硫化鎘奈米異質結構，並將其應用於光催化降解對位乙醯氨基酚。在研究中也針對於氧化鋅/硫化鎘奈米異質結構的表面形貌、晶體結構及元素組成進行分析。此外在紫外光的照射下，測試不同硫化鎘反應前驅物濃度與反應時間於製備氧化鋅/硫化鎘奈米異質結構在光催化降解對位乙醯氨基酚之影響進行深入研究與探討。

Zinc Oxide (ZnO) nanosheets can be grown on the aluminum foil by wet chemical method and applied to photocatalytic degradation of organic pollutants. The study discussed the surface morphology, crystal structure, and elemental composition of the prepared ZnO nanosheets under different ZnO precursor concentrations. ZnO nanosheets with different concentrations of ZnO reaction precursors were used to evaluate the photocatalytic efficiency of degradation of methylene blue under ultraviolet light irradiation. This result confirms that the ZnO nanosheets are the best parameters for photocatalytic degradation at the ZnO reaction precursor concentration of 50 mM.
Subsequently, cadmium sulfide (CdS) nanostructures were deposited on the ZnO nanosheets by wet chemical method to form ZnO/CdS nano-heterostructures, which were applied to photocatalytic degradation of acetaminophen. The surface morphology, crystal structure, and elemental composition of the ZnO/CdS nano-heterostructures were also analyzed. In addition, ZnO/CdS nano-heterostructures with different concentrations of CdS precursors and reaction times were used to evaluate the photocatalytic efficiency of degradation of acetaminophen under ultraviolet light irradiation.

摘要 I
Abstract II
圖目錄 VII
表目錄 XI
第一章 序論 1
1.1研究背景 1
1.2研究動機與目的 2
第二章 文獻回顧 4
2.1 奈米材料技術 4
2.1.1 奈米材料的簡介 4
2.1.2 奈米材料的製備 8
2.1.3 奈米材料的應用 10
2.2 氧化鋅 11
2.2.1 氧化鋅介紹 11
2.2.2 氧化鋅的光學性質 14
2.2.3 一維氧化鋅奈米結構的合成方式 15
2.3 硫化鎘 25
2.3.1硫化鎘介紹 25
2.4 光催化降解簡介 27
2.4.1常見有機汙染物的處理法 29
第三章 研究方法 30
3.1實驗藥品與設備 30
3.1.1實驗藥品 30
3.1.2實驗設備 32
3.1.3分析儀器 33
3.2 以鋁箔作為基材成長氧化鋅奈米結構 43
3.2.1 在鋁箔上成長氧化鋅奈米結構 43
3.2.2 製備氧化鋅/硫化鎘奈米異質結構 46
3.3 光催化降解實驗 48
3.3.1不同濃度所製備氧化鋅奈米結構之光催化降解測試 48
3.3.2 光催化降解循環測試 49
3.3.3 光催化降解之捕捉劑測試 49
第四章 結果與討論 50
4.1 氧化鋅奈米結構分析 50
4.1.1 表面形貌的分析 50
4.1.2 微結構的分析 52
4.1.3 晶體結構的分析 54
4.1.4 表面元素組成及化學狀態的分析 56
4.1.5 光致放光特性的分析 58
4.1.6 氧化鋅奈米結構於光催化降解之應用 59
4.1.6.1光催化降解甲基藍 59
4.1.6.2 捕捉劑的分析 62
4.1.6.3 光催化降解普拿疼 64
4.2氧化鋅/硫化鎘奈米異質結構分析 66
4.2.1 表面形貌的分析 66
4.2.2 微結構的分析 68
4.2.3 晶體結構的分析 70
4.2.4 光致放光特性的分析 72
4.2.5 氧化鋅/硫化鎘奈米異質結構於光催化降解之應用 73
4.2.5.1光催化降解普拿疼 73
第五章 結論 77
5.1氧化鋅奈米結構於光催化降解之應用 77
5.2氧化鋅/硫化鎘奈米異質結構於光催化降解之應用 78
第六章 參考資料 79

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