臺灣博碩士論文加值系統

摘要 I
Abstract II
誌謝 VI
目錄 VII
表目錄 X
圖目錄 XI
第1章 緒論 1
1.1 前言 1
1.2 鋰硫電池發展 3
1.3 鋰硫電池工作原理 5
1.4 鋰硫電池固有問題 6
1.5 研究動機 7
第2章 文獻回顧 8
2.1 電極結構 8
2.1.1 膜結構 9
2.2 相轉換法 10
2.2.1 溼式相轉換法 10
2.2.2 溼式相轉換成膜理論 11
2.3 添加劑 12
2.3.1 碳材料應用 12
2.3.2 氧化物應用 13
第3章 實驗方法 15
3.1 電極與複合材料製備 15
3.1.1 傳統二維塗佈電極 15
3.1.2 相轉換基材 15
3.1.3 添加物/相轉換基材 16
3.2 電池組裝 17
3.2.1 鋰硫電池電解液 17
3.2.2 鋰硫電池陰極液 17
3.2.3 鋰硫電池組裝 17
3.3 電化學分析 18
3.3.1 電化學阻抗分析 18
3.3.2 電化學循環測試 19
3.3.3 循環伏安測試 19
3.4 材料特性分析 20
3.4.1 掃描式電子顯微鏡 20
3.4.2 微拉曼及微光激發光譜儀 20
3.4.3 傅立葉轉換紅外光光譜儀 21
3.4.4 氣體吸脫附分析儀 21
3.4.5 四點探針量測儀 22
3.4.6 紫外光/可見光/近紅外光分光光譜儀 22
3.4.7 化學分析電子光譜儀 22
第4章 結果與討論 23
4.1 傳統鋰硫電池 23
4.1.1 二維塗佈電極 23
4.2 相轉換碳骨架 25
4.2.1 相轉換法 25
4.2.2 巨觀形貌 30
4.2.3 顯微結構 32
4.2.4 拉曼光譜分析 34
4.2.5 傅立葉轉換紅外線光譜分析 35
4.2.6 比表面積與孔徑分析 36
4.3 相轉換電極鋰硫電池 37
4.3.1 顯微結構 37
4.3.2 吸附實驗 39
4.3.3 阻抗分析 41
4.3.4 循環伏安分析 43
4.3.5 循環測試 46
4.4 同質多孔碳材/相轉換電極電池 51
4.4.1 顯微結構 52
4.4.2 吸附實驗 53
4.4.3 成核實驗 54
4.4.4 循環測試 55
4.5 異質高熵氧化物/相轉換電極鋰硫電池 57
4.5.1 顯微結構 58
4.5.2 吸附實驗 59
4.5.3 成核實驗 60
4.5.4 循環測試 61
4.6 電化學性能比較 62
第5章 本研究之創新性、學術性與應用性 63
第6章 結論 64
第7章 參考文獻 65

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