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研究生:張俊棋
研究生(外文):CHANG, CHUN-CHI
論文名稱:利用電沉積法製備兼具自潤性及耐磨耗之鎳基複合鍍層
論文名稱(外文):Study of Contained Self-lubrication and Wear Resistance Property Nickel Based Composite Coating Prepared by Electrodeposition
指導教授:許宏華
指導教授(外文):SHEU, HUNG-HUA
口試委員:許宏華葛明德劉益銘李弘彬鍾武勳
口試委員(外文):SHEU, HUNG-HUAGER, MING-DERLIU, YIH-MINGLEE, HUNG-BINCHUNG, WU-HSUN
口試日期:2022-07-07
學位類別:碩士
校院名稱:國防大學
系所名稱:化學工程碩士班
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2022
畢業學年度:110
語文別:中文
論文頁數:176
中文關鍵詞:電沉積鎳-碳化硼鎳-鐵氟龍鎳-鐵氟龍-碳化硼耐磨耗性耐蝕性
外文關鍵詞:ElectrodepositionNi-B4CNi-PTFENi-PTFE-B4CWear ResistanceCorrosion Resistance
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  • 被引用被引用:0
  • 點閱點閱:89
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謝誌 i
摘要 ii
ABSTRACT iv
目次 vi
表目錄 ix
圖目錄 xi
1. 緒論 1
1.1研究背景 1
1.2研究目的與動機 2
2. 文獻回顧與理論基礎 4
2.1鎳基複合鍍層的發展與製備 4
2.1.1電鍍操作參數對複合鍍的影響 12
2.1.1.1電流密度對複合鍍層的影響 12
2.1.1.2轉速對複合鍍的影響 15
2.1.1.3微粒濃度對複合鍍的影響 20
2.1.1.4界面活性劑對複合鍍的影響 25
2.1.2硬質顆粒對鎳基複合鍍層耐磨耗的影響 31
2.1.3自潤性鎳基複合鍍層的性質 34
2.2電沉積理論與機制 38
2.3磨潤基礎理論 40
2.4腐蝕機構原理 45
3. 實驗設備、方法與步驟 48
3.1實驗設備 48
3.2實驗藥品 61
3.3複合鍍層製備流程 62
3.3.1電鍍前準備與前處理 62
3.3.2 鍍浴配置 63
4. 結果與討論 66
4.1界面活性劑對複合鍍層製備的影響 66
4.1.1界面活性劑種類對Ni-B4C複合鍍層中B4C顆粒分布的影響 66
4.1.2界面活性劑種類對Ni-PTFE複合鍍層中PTFE顆粒分布的影響 72
4.2影響複合鍍層中微粒分布因素之探討 76
4.2.1鍍液轉速對微粒分布之影響 76
4.2.2電流密度對微粒分布之影響 85
4.2.3添加微粒濃度對微粒分布之影響 91
4.3添加顆粒對鎳基複合鍍層機械性質之影響 105
4.4添加顆粒對鎳基複合鍍層的耐磨耗性質之影響 111
4.5添加顆粒對鎳基複合鍍層的耐蝕性之影響 129
5. 結論 138
6. 未來規劃 141
參考文獻 142

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