臺灣博碩士論文加值系統

誌謝 i
摘要 ii
Abstract iii
目錄 v
圖目錄 viii
表目錄 xii
第一章 前言 1
第二章 文獻回顧 2
2.1 黑磷 2
2.1.1 黑磷背景 2
2.1.2 高壓合成法 3
2.1.3 低壓合成法 3
2.2 黑磷之抗氧化改質 6
2.2.1 氧化機制 6
2.2.2 表面改質 6
2.2.3 摻雜改質 19
2.2.4 黑磷之氣體感測器 23
2.3 氣體感測器 25
2.3.1 氣體感測器背景 25
2.3.2 氣體感測器之特性 26
2.3.3 半導體氣體感測器之機制 27
2.4 影響氣體感測效能之因素 29
2.4.1 微結構 29
2.4.2 濕度 32
2.4.3 溫度 33
2.4.4 表面修飾 34
2.5 研究動機及目的 35
第三章 實驗方法與步驟 36
3.1 實驗設備 36
3.2 實驗藥品 37
3.3 實驗方法與步驟 37
3.3.1 BP、Te-BP 及 Sb-BP 摻雜之合成 38
3.3.2 BPNSs、Te-BPNSs 及 Sb-BPNSs 之合成 39
3.4 奈米結構之分析 39
3.4.1 X 光繞射分析儀(XRD) 39
3.4.2 場發掃描式電子顯微鏡(FESEM) 39
3.4.3 拉曼光譜儀(Raman spectrum) 40
3.4.4 X 光射線光電子能譜(XPS) 40
3.4.5 掃描式探針顯微鏡(AFM) 40
3.4.6 光學顯微鏡(OM) 40
3.4.7 穿透式電子顯微鏡(TEM) 41
3.5 氣體感測之分析 41
3.5.1 氣體感測試片之製備方式 41
3.5.2 氣體感測性質之量測 41
第四章 結果與討論 42
4.1塊狀 BP、Te-BP、Sb-BP 結構分析 42
4.1.1 不同反應溫度對 BP、Te-BP、Sb-BP 之影響 42
4.1.2 不同摻雜濃度對 BP、Te-BP、Sb-BP 之影響 44
4.2 BPNSs、Te-BPNSs、Sb-BPNSs 構造及形貌分析 50
4.3 Te-BPNSs 及 Sb-BPNSs 抗氧化效能分析 61
4.4 摻雜Te、Sb對於氣體感測之影響 69
4.4.1 BPNSs、Te-BPNSs、Sb-BPNSs 選擇性及其響應時間 69
4.4.2 BPNSs、Te-BPNSs、Sb-BPNSs 應用於氣體感測之環境穩定性分析 73
第五章 結論 76
參考文獻 77

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