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論文名稱:一步法合成T-ZnO@SiO2-氟矽烷偶合劑之 複合塗料應用於防蝕與耐性能之研究
論文名稱(外文):A study on the application of composite coatings using one-step synthesized T-ZnO@SiO2-fluorosilane coupling agent for corrosion protection and durability performance
外文關鍵詞:One-step processzinc oxidepolysiliconcomposite coatingself-cleaning coatingcorrosion-resistant coatingsuperhydrophobic coating
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摘要 i
Abstract ii
摘要 i
Abstract ii
致謝 iii
目錄 iv
表目錄 ix
圖目錄 x
第一章 緒論 1
1-1 研究背景 1
1-2 研究目的及方法 2
第二章 相關知識與文獻回顧 3
2-1 四針狀氧化鋅 (T-ZnO) 3
2-2 氧化鋅的表面改質法 5
2-3 金屬氧化物奈米粒子的表面改質 7
2-3-1 物理方法 7
2-3-2 化學方法 8
2-1 潤濕定律與接觸角 9
2-1 Wenzel 方程式 12
2-2 Cassie-Baxter 定理:適應性和局限性 13
2-3 超疏水表面 13
2-4 機械性能 15
2-5 腐蝕原理 16
2-6 防蝕塗料的分類 17
2-6-1 電化學防蝕 18
2-6-2 表面塗層 20
第三章 實驗 24
3-1 實驗藥品與組成 24
3-2 實驗流程 26
3-2-1 四針狀氧化鋅(T-ZnO)的合成 26
3-2-2 一步合成法-ZnO@SiO2、ZnO@SiO2-FOTS塗料粉體 27
3-2-3 一步合成法總流程圖及材料命名 28
3-3 分析設備機台與廠牌 29
3-3-1 掃描式電子顯微鏡 (Scanning Electron Microscope, SEM)廠牌與機台型號:Phenom, ProX 29
3-3-2 穿透式電子顯微鏡 (Transmission Electron Microscope, TEM)廠牌與機台型號:FEI E.O Tecnai F20 G2 Field Emission 30
3-3-3 X 光繞射儀 (X-ray Diffractometer, XRD)廠牌與機台型號:PANalytical, X’Pert PRO 31
3-3-4 接觸角量測儀廠牌與機台型號:dataphysics, OCA15EC 31
3-3-5 測量方法 32
3-3-6 精密秤量天秤 (Precision Weighing Scales)廠牌與機台型號:Sartorious;XS-225A 33
3-3-7 傅立葉轉換紅外線光譜儀 (Fourier-transform infrared spectroscopy ,FTIR)廠牌與機台型號:Perkin Elmer Spectrum One FT-IR Spectrometer 34
3-3-8 X 光光電子能譜儀(X-ray photoelectron spectroscopy, XPS/ESCA)廠牌與機台型號:PHI Quantera II 34
3-3-9 自動塗布機廠牌與機台型號:全華精密;PFA-2010S 35
3-3-10 恆電位儀 (Potentiostat)廠牌與機台型號:Biologic, SP-240 36
3-3-11 原子力顯微鏡(atomic force microscope, AFM)廠牌與機台型號:CSPM-4000 38
第四章 結果數據分析 41
4-1 ZnO分析 42
4-1-1 SEM 表面特徵分析 42
4-1-2 XRD分析 43
4-1-3 TEM分析 44
4-1-4 FTIR 45
4-1-5 XPS 46
4-2 ZnO@SiO2和ZnO@SiO2-FOTS分析 48
4-2-1 ZnO@SiO2 —SEM與EDS分析 48
4-2-2 ZnO@SiO2 — TEM 50
4-2-3 FTIR 51
4-2-4 ZnO@SiO2-FOTS — SEM 52
4-2-5 ZnO@SiO2-FOTS — XPS 53
4-3 ZnO、ZS、ZSFOTS之塗料性能分析 55
4-3-1 各塗層SEM分析 55
4-3-2 AFM表面分析 56
4-3-1 表面潤濕性分析 58
4-3-2 塗層的自潔能力 59
4-3-1 塗層的腐蝕性能 60
4-3-2 循環耐刷洗測試 64
4-3-3 不同pH值下的CA/SA測試 65
4-3-4 UV光測試 68
4-3-5 耐候測試 69
4-3-6 百格刀附著力測試 70
4-3-7 剪切磨損測試 71
第五章 結論 72
第六章 參考文獻 74

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