臺灣博碩士論文加值系統

摘 要 i
ABSTRACT iii
Acknowledgements vii
Table of Contents x
List of Tables xiv
List of Figures xv
List of Schemes xix
Chapter 1 Introduction 1
1.1 Organophosphorus pesticides 1
1.1.1 Methyl Parathion 2
1.1.2 Fenitrothion 3
1.1.3 Paraoxon ethyl 3
1.2 Electrochemical sensor 4
1.3 Transition metal Phosphides 5
1.3.1 Cobalt phosphide 6
1.4 Binary transition metal Phosphides 6
1.5 Carbon 7
1.6 Hydrothermal method 7
1.7 Phosphorization technique 8
1.8 Aim and objective of the present work 8
Chapter 2 Methods of Instrumentation 10
2.1 Characterization techniques 10
2.1.1 X-ray diffraction method (XRD) 10
2.1.2 Fourier-transform infrared spectroscopy (FT-IR) 11
2.1.3 X-ray Photoelectron Spectroscopy (XPS) 11
2.1.4 Field Emission Scanning Electron Microscopy (FESEM) 12
2.1.5 High Resolution Transmission Electron Microscopy (HRTEM) 13
2.2 Electrochemical Applications 14
2.2.1 Cyclic Voltammetry 15
2.2.2 Differential pulse voltammetry 15
2.2.3 Three electrode electrochemical system 16
Chapter 3 Construction of Manganese Cobalt Phosphide/C Coreshell for Electrochemical Detection of Hazardous Pesticide Methyl Parathion 17
3.1 Introduction 17
3.2 Experimental section 19
3.2.1 Chemicals and reagents 19
3.2.2 Synthesis of manganese cobalt glycerate and cobalt glycerate 20
3.2.3 Synthesis of manganese cobalt phosphate and cobalt phosphate 20
3.2.4 Electrode Fabrication 21
3.3 Results and discussions 21
3.3.1 XRD analysis 21
3.3.2 XPS analysis 23
3.3.3 HRTEM analysis 25
3.3.4 Electrocatalytic activity of MP at MnCoP/C/GCE 27
3.3.5 Electrocatalytic determination of MP at MnCoP/C/GCE 32
3.3.6 Repeatability, reproducibility, storage stability of MP 33
3.3.7 Real sample performance of MP 35
3.4 Conclusion 37
Chapter 4 Self-Decorated Iron Cobalt Phosphide/C Coreshell-Enhanced Electrochemical Detection of Harmful Organophosphorus Pesticide Fenitrothion 39
4.1 Introduction 39
4.2 Experimental section 41
4.2.1 Chemicals and reagents 41
4.2.2 Synthesis of iron cobalt phosphide/C coreshell (FCP/C) 41
4.2.3 Electrode Fabrication 42
4.3 Results and discussions 43
4.3.1 XRD analysis 43
4.3.2 FESEM and HRTEM analysis 44
4.3.3 XPS and BET analysis. 48
4.3.4 CV analysis of FN by FCP/C/GCE 50
4.3.5 Effect of scan rate investigation 51
4.3.6 Effect of pH study 53
4.3.7 Effect of FN concentration 54
4.3.8 Electrochemical Determination of FN by DPV analysis 54
4.3.9 Repeatability and selectivity of FN 56
4.3.10 Repeatability and storage stability of FN 57
4.3.11 Real sample analysis 58
4.4 Conclusion 60
Chapter 5 Self-Decorated Nickel Cobalt Phosphide at Carbon Coreshell Electrocatalyst: A Highly Sensitive Electrochemical Detection of Organophosphorus Pesticide Paraoxon Ethyl 61
5.1 Introduction 61
5.2 Experimental section 64
5.2.1 Chemicals and reagents 64
5.2.2 Synthesis of nickel cobalt phosphide/C 64
5.2.3 Electrode Fabrication 66
5.3 Results and discussion 66
5.3.1 XRD analysis 66
5.3.2 FESEM and HRTEM analysis 68
5.3.3 XPS analysis 72
5.3.4 Electrochemical CV analysis of PE at NCP/C/GCE 73
5.3.5 Electrochemical DPV analysis of PE 77
5.3.6 Repeatability, reproducibility and storage stability of PE 79
5.3.7 Real sample performance of PE 81
5.4 Conclusion 82
Chapter 6 83
6.1 References 83
Chapter 7 90
7.1 Summary and Conclusion 90
7.2 List of Publications 92

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