臺灣博碩士論文加值系統

摘要 i
Abstract ii
目錄 iii
圖目錄 vi
第一章 緒論 1
1.1 前言 1
1.2 研究動機與目標 1
第二章 文獻回顧 2
2.1 皺褶結構(Wrinkle) 2
2.1.1 仿生皺褶結構 2
2.1.2 皺褶形成理論 4
2.1.3 皺褶理論公式 7
2.1.4 皺褶製備方式 10
2.2 波浪緞帶皺褶結構(Wavy ribbon) 16
2.2.1 皺褶的幾何侷限效應 16
2.2.2 波浪緞帶皺褶結構的製備 18
2.3 可拉伸電子(Stretchable electronics) 20
2.3.1 可拉伸電子的概況 20
2.3.2 皺褶化之可拉伸電子 22
2.3.3 波浪緞帶皺褶應用於可拉伸電子 24
2.4 導電高分子：聚苯胺(Polyaniline) 28
2.4.1 導電高分子的發展史 28
2.4.2 導電聚合物的導電原理 29
2.4.3 本質性導電聚合物：聚苯胺 30
2.4.4 聚苯胺表面皺褶結構 32
2.4.5 聚苯胺衍生物：聚苯乙烯/聚苯胺核殼粒子 34
2.4.6 導電性核殼粒子應用於軟性電子 36
2.5 蒸發誘導自組裝(Evaporation induced self-assembly) 38
2.5.1 咖啡環效應 38
2.5.2 刮刀塗佈技術 40
2.6 溶劑蒸氣退火法(Solvent vapor annealing method) 43
第三章 實驗方法 44
3.1 實驗藥品 44
3.2 實驗儀器 45
3.3 實驗流程 53
3.3.1 玻璃基板清潔與表面改質 53
3.3.2 犧牲層與軟質層溶液配製 53
3.3.3 波浪緞帶皺褶結構之製備 54
第四章 結果與討論 56
4.1 刮刀塗佈技術之探討分析 56
4.2 PS微球之波浪緞帶皺褶結構 59
4.2.1 合成單分散PS微球 59
4.2.2 製備PS微球之波浪緞帶皺褶 61
4.2.3 參數控制與表面形貌觀察 65
4.3 PS/PANI核殼粒子之波浪緞帶皺褶結構 71
4.3.1 合成PS/PANI核殼粒子 71
4.3.2 製備核殼粒子之波浪緞帶皺褶 76
4.4 導電核殼粒子波浪緞帶皺褶結構之電氣性質 81
第五章 結論 83
第六章 參考文獻 84

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