臺灣博碩士論文加值系統

目錄
中文摘要 I
Abstract III
致謝 V
目錄 VI
表目錄 IX
圖目錄 X
第一章 緒論 1
1.1前言 1
1.2研究動機與目的 5
第二章 文獻回顧 7
2.1 電化學原理 7
2.1.1電化學反應機制 7
2.2 超級電容器 9
2.2.1超級電容器的類別與原理 9
2.3四氧化三錳、二硫化鉬材料的性質、製備及應用 19
2.3.1 Mn3O4材料的結構 19
2.3.2 Mn3O4文獻回顧 20
2.3.3 MoS2材料的結構 22
2.3.4 MoS2文獻回顧 24
2.3.5碳纖維布(Carbon fiber cloth, CC) 25
2.3.6電解液 26
2.3.7 水熱法與熱處理技術製備金屬氧化物電極材料 29
2.4氧化海藻酸鈉-殼聚醣複合水凝膠的性質、製備及應用 33
2.4.1氧化海藻酸鈉 33
2.4.2殼聚醣 35
2.4.3氧化海藻酸鈉-殼聚醣複合水凝膠 36
2.4.4氧化海藻酸鈉-殼聚醣複合水凝膠文獻回顧 38
第三章 實驗方法與步驟 40
3.1實驗藥品 40
3.2實驗儀器 42
3.3實驗步驟與流程 43
3.3.1碳纖維布前處理 44
3.3.2製備Mn3O4@NPC/CC正極 45
3.3.3製備MoS2@NC/CC負極 46
3.3.4製備PECH 48
3.3.5 組裝PECH Mn3O4//MoS2超級電容器 49
3.4儀器分析 50
3.4.1分析型場發掃描式電子顯微鏡(Analytical field emission scanning electron microscope, AFE-SEM) 50
3.4.2掃描穿透式電子顯微鏡(Field emission scanning transmission electron microscope, FE-S/TEM) 51
3.4.3 X-ray繞射分析儀(X-ray diffractometer, XRD) 52
3.4.4 傅立葉紅外光譜儀（Fourier transform infrared spectroscopy, FTIR） 54
3.4.5 核磁共振儀(Nuclear Magnetic Resonance, NMR) 56
3.4.5 BET比表面積分析儀(Brunauer-Emmett-Teller specific surface area and porosity analyzer, BET) 59
3.4.6 萬能試驗機(Universal testing machine) 60
3.4.7 流變儀（rheometer） 62
3.7電化學測試 63
3.7.1循環伏安法(cyclic voltammetry, CV) 65
3.7.2恆電流充放電測試(galvanostatic charge-discharge, GCD) 66
3.7.3電化學交流阻抗分析(Electrochemistry Impedance Spectroscopy, EIS) 67
 
第四章 結果與討論 70
4.1 材料之物性分析 70
4.2 添加殼聚醣對製備MN3O4與MOS2材料的影響 71
4.2.1 添加殼聚醣/磷酸製得Mn3O4材料與添加殼聚醣製得MoS2材料之物性分析 71
4.2.2 添加殼聚醣/磷酸製得Mn3O4@NPC/CC電極與添加殼聚醣製得MoS2@NC/CC電極之電性分析 104
4.3 殼聚醣與氧化海藻酸鈉複合水凝膠材料 108
4.3.1 添加不同比例NaCl、KCl以及Na2SO4無機鹽之複合水凝膠物性分析 108
4.3.2 添加不同比例NaCl、KCl以及Na2SO4無機鹽之複合水凝膠電性分析 145
4.3.3 添加不同比例NaCl、KCl及Na2SO4無機鹽之PECH抗菌試驗 163
第五章 結論 168
第六章 參考文獻 170

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