臺灣博碩士論文加值系統

環丙沙星（CIP）是第三代氟喹諾酮類抗生素，通常用於治療抗藥性微生物引起的疾病。 由於未消化的 CIP 的生物降解不充分，在城市廢水、製藥廢水、廢水和地表水中都發現了它。 因此，必須採用有效的方法在抗生素釋放到環境中之前將其去除。 最近，基於硫酸根的高級氧化製程（SR-AOP）被認為具有強大的潛在氧化能力和對彈性有機物分解的有效性。 在先前的研究中，已知一維亞錳酸鹽（MnOOH）具有高表面活性位點、大量表面羥基位點和高電子轉移率，可以成為SR-AOP用於抗生素降解的潛在材料。 因此，本論文旨在開發MnOOH以及MnOOH與其他材料的組合，以提高水中抗生素的降解效率。 在第一項研究中，透過在 MnOOH 奈米棒上塗覆 1%、5%、10% 和 20% NiCo2O4 NPs 有效合成了催化劑 NiCo@MnOOH，以提高 CIP 降解的催化活性。 結果表明，20% NiCo@MnOOH 作為過一硫酸鹽（PMS）活化劑具有最佳的 CIP 降解性能。 在 100 mg L-1 的 20% NiCo@MnOOH 和 200 µM PMS 下反應 30 分鐘後，CIP (20 µM) 的降解率為 97.8%。 結果表明，NiCo@MnOOH + 中貢獻了硫酸根（SO4●-）、氧自由基（O2●-）、羥基自由基（●OH）等自由基氧化物種和單線態氧（1O2）等非自由基物種。用於 CIP 降解的 PMS 系統。
在第二項研究中，為了製造具有高表面積、良好導電性、高穩定性和減少金屬浸出的催化劑，透過將NiCo2O4 和MnOOH 固定在活化PMS 進行CIP 降解的氧化石墨烯(GO) 上，成功合成了NiCo@MnOOH/GO。 。 結果表明，NiCo@MnOOH/GO 在 CIP 降解中表現出最高的性能，其次是 MnOOH/GO 和 MnOOH。 在 0.2 mM PMS 和 0.15 g L-1 NiCo@MnOOH/GO 下，30 分鐘後，CIP (0.02 mM) 的去除效率為 95%。 NiCo@MnOOH/GO + PMS 系統的動力學速率常數（kobs）為 17x10-2 min-1，分別是 MnOOH + PMS 和 MnOOH/GO + PMS 系統的 7.5 倍和 4.5 倍。 結果表明，NiCo@MnOOH/GO 活化的 PMS 中產生1O2、SO4●-、O2●-、●OH，並負責 CIP 降解。
在第三項研究中，設計和合成的ZIF-67@MnOOOH@GO三元複合材料可以改善活性表面位點、金屬浸出和比表面積，從而實現有效的電子轉移和PMS活化，從而產生豐富的反應物種CIP 降解。 研究了催化劑劑量、PMS 劑量、pH 值和溫度對 CIP 降解的影響。 結果表明，在 0.2 mM PMS 和 50 mg L-1 ZIF/Mn/GO 劑量下反應 20 分鐘後，CIP (0.02 mM) 的分解率為 97.8%。 不同催化劑下CIP降解kobs大小為：ZIF/Mn/GO (43.4x10-2 min-1) > ZIF/MnOOH (18.3x10-2 min-1) > ZIF/GO (13.8x10-2 min-1) > ZIF-67 (8.8x10-2 min-1) > MnOOH@GO (6.2x10-2 min-1) > MnOOH (4.1x10-2 min-1)。 此外，結果顯示ZIF/Mn/GO/PMS體系中存在SO4●-、O2●-、●OH和1O2。 , 1O2 是一種主要的活性氧(ROS)，有助於CIP 降解。
此外，透過將石墨烯量子點（GQDs）附著在MnOOH奈米棒表面，成功合成了催化劑GQDs/Mn，以促進抗生素的催化臭氧化，例如CIP。 結果表明，GQDs/Mn/O3 系統具有最大的 CIP 去除效果，其次是 MnOOH/O3 和僅 O3。 在 9.6 mg L-1 O3 存在下，由 12.5 mg L-1 GQDs/Mn 催化，0.02 mM CIP 在 30 分鐘內降解效率為 99.9%。 動力學速率常數的順序為：GQDs/Mn/O3 (0.161 min-1) > MnOOH/O3 (0.079 min-1) > O3 (0.055 min-1)。 此外，GQDs/Mn 可增強 CIP 降解並抑制不同水源中 BrO3- 的形成。 結果表明，O2●-、●OH和1O2參與了GQDs/Mn/O3系統的CIP降解。 這些發現證明了基於 MnOOH 的催化劑在增強 PMS 活化和水中抗生素降解催化臭氧化方面的催化活性的潛在應用。

Ciprofloxacin (CIP) is a third-generation fluoroquinolone antibiotic that is commonly used to treat diseases caused by resistant microbes. Due to the insufficient breakdown of undigested CIP, it has been detected in municipal wastewater, pharmaceutical wastewater, effluent, and surface water. Hence, employing an efficient approach to eliminate antibiotics prior to their discharge into the environment is crucial. Lately, sulfate radical-based advanced oxidation process (SR-AOP) has been known to have strong potential oxidation capability and effectiveness for the breakdown of resilient organic matters. One-dimensional manganite (MnOOH) is known to have high surface-active sites, a lot of surface hydroxyl sites, and a high electron transfer rate among prior investigations, which can be potential material for SR-AOP for antibiotics degradation. Thus, this thesis aims to develop MnOOH and combination of MnOOH with other materials for enhance efficiency degradation of the antibiotics in water. In the first study, by coating MnOOH with 1%, 5%, 10%, and 20% NiCo2O4 NPs, the catalyst NiCo@MnOOH was successfully produced to improve its catalytic efficiency for the decomposition of CIP. The findings showed that the optimum CIP decomposition performance was achieved using 20% NiCo@MnOOH as the activator of PMS. The decomposition of CIP was 97.8% during a 30-minute reaction at 100 mg L-1 of 20% NiCo@MnOOH and 200 µM of PMS. The result demonstrated that radical oxidative species such as sulfate radical (SO4●-), oxygen radical (O2●-), hydroxyl radicals (●OH), and non-radical species as singlet oxygen (1O2) were influenced in NiCo@MnOOH/PMS system for CIP degradation.
In the second study, to create the catalyst with high surface area, good conductivity, high stability and reduced metal leaching, NiCo@MnOOH/GO was successfully manufactured by coating NiCo2O4 and MnOOH on the graphene oxide (GO) that activated PMS for CIP degradation. The best performance in CIP decompositon is exhibited by NiCo@MnOOH/GO, followed by MnOOH/GO and MnOOH, according to the findings. After 30 minutes at 0.15 g L-1 of NiCo@MnOOH/GO and 0.2 mM PMS, the degradation of CIP (0.02 mM) was 95%. The kobs of the NiCo@MnOOH/GO/ PMS system was 17x10-2 min-1, which was 7.5 and 4.5 times higher than that MnOOH/PMS, and MnOOH/GO/PMS system. The findings demonstrated that PMS activated by NiCo@MnOOH/GO produced 1O2, SO4●-, O2●-, ●OH, which oversaw CIP decomposition.
In the third study, the ternary composites of ZIF/MnOOOH@GO designed and synthesized that can improve active surface sites, metal leaching, and specific surface area resulting in efficient electron transfer and PMS activation, which generates an abundance of reactive species for CIP degradation. The impact of catalyst dose, PMS dose, pH, and temperature on CIP degradation was examined. The findings showed that the degradation of CIP reached 97.8% after a 20-minute reaction using a dosage of 0.2 mM PMS and 50 mg L-1 ZIF/Mn/GO. The kobs of CIP degradation under different catalysts was in the order: ZIF/Mn/GO > ZIF/MnOOH > ZIF/GO > ZIF-67 > MnOOH/GO > MnOOH. Moreover, the results exposed the presence of sulfate radical (SO4●-), O2●-, ●OH, and 1O2 were generated in ZIF/Mn/GO/PMS system, 1O2 is a predominance ROSs that contributes to CIP degradation.
Moreover, graphene quantum dots (GQDs) were effectively bonded to the surface of MnOOH nanorods to create a catalyst GQDs/Mn, which enhances the catalytic ozonation of antibiotics, such as CIP. The outcome showed that the CIP removal efficacy of the GQDs/Mn/O3 system was the highest, followed by that of MnOOH/O3 and O3 alone. CIP was destroyed with 99.9% efficiency in 30 minutes when 12.5 mg L-1 of GQDs/Mn and 9.6 mg L-1 of O3 were present. The kobs was as follows: GQDs/Mn/O3 > MnOOH/O3 > O3. Furthermore, in some water sources, the GQDs/Mn may promote CIP breakdown and prevent BrO3-formation. The findings showed that the GQDs/Mn/O3 system generated ROSs as included ●OH, 1O2, and O2●-, which involved in CIP degradation. These results show how MnOOH-based catalysts may be used to increase catalytic activity in terms of PMS activation and catalytic ozonation for the breakdown of antibiotics in water.
Keywords: MnOOH, NiCo2O4, GO, ZIF-67, GQDs, Peroxymonosulfate, ciprofloxacin, sulfate radical, catalytic ozonation.

ACKNOWLEDGEMENT i
摘要 ii
ABSTRACT v
TABLE OF CONTENTS viii
LIST OF FIGURES xii
LIST OF TABLES xxi
LIST OF ABBREVIATIONS xxii
CHAPTER 1. INTRODUCTION 1
1.1. Motivation 1
1.2. Objective 5
CHAPTER 2. LITERATURE REVIEW 6
2.1. Overview of antibiotics 6
2.1.1. General introduction to antibiotics 6
2.1.2. Methodology to remove antibiotics. 10
2.2. Overview of advanced oxidation processes 11
2.2.1. Sulfate radical-based advanced oxidation process. 13
2.2.2. Catalytic ozonation process 18
2.3. Overview of MnOOH 23
CHAPTER 3. METHODOLOGY 25
3.1. Overview of research 25
3.2. Research contents 26
3.2.1. Characterizations and analytical methods 26
3.2.2. Chemical analysis 27
3.2.3. Phase 1: NiCo@MnOOH 27
3.2.3.1. Chemicals 27
3.2.3.2. Preparation of catalysts 28
3.2.3.3. Catalytic oxidation experiments 29
3.2.4. Phase 2: NiCo@MnOOH/GO 30
3.2.4.1. Chemicals 30
3.2.4.2. Preparation of catalysts 30
3.2.4.3. Catalytic oxidation tests 31
3.2.5. Phase 3: ZIF67@MnOOH@GO 32
3.2.5.1. Chemicals 32
3.2.5.2. Preparation of catalysts 32
3.2.5.3. Catalytic oxidation tests 33
3.2.6. Phase 4: GQDs/Mn 34
3.2.6.1. Chemicals 34
3.2.6.2. Preparation of catalysts 34
3.2.6.3. Catalytic oxidation experiments 35
CHAPTER 4. RESULTS AND DISCUSSION 37
4.1. Phase 1: NiCo@MnOOH 37
4.1.1. Characterization of catalyst 37
4.1.2. Catalytic activity as PMS activator 43
4.1.3. Effect of Operational parameters on CIP degradation 45
4.1.3.1. Effect of catalyst dose 45
4.1.3.2. Effect of PMS dosage 45
4.1.3.3. Effect of initial pH 47
4.1.3.4. Effect of temperature 49
4.1.3.5. Effect of inorganic ions 49
4.1.3.6. Effect of natural organic matter 50
4.1.4. Reusability and stability of catalysts 51
4.1.5. Mechanisms of NiCo@MnOOH for PMS activation 53
4.2. Phase 2: NiCo@MnOOH/GO 59
4.2.1. Catalytic activity of catalysts 59
4.2.2. Effect of operating parameters on CIP degradation 68
4.2.2.1. Effect of NiCo@MnOOH/GO dosage on CIP degradation. 68
4.2.2.2. Effect of PMS dosage on CIP degradation. 69
4.2.2.3. Effect of initial pH on CIP degradation. 70
4.2.2.4. Effect of inorganic ions on CIP degradation. 72
4.2.2.5. Effect of natural organic acids on CIP degradation. 74
4.2.3. Reusability and stability of NiCo@MnOOH/GO 75
4.2.4. Mechanisms of PMS activation on NiCo@MnOOH/GO 78
4.2.5. Mineralization of CIP and toxicity evaluation. 83
4.3. Phase 3: ZIF/Mn/GO 85
4.3.1. Properties of catalysts 85
4.3.2. Catalytic activity of ZIF/Mn/GO as PMS activator 93
4.3.2.1. Optimization ratio of ZIF-67/MnOOH 93
4.3.2.2. Comparison CIP degradation in different catalysts 95
4.3.3. The impact of experiment conditions on CIP degradation 97
4.3.3.1. Impact of catalyst dose 97
4.3.3.2. Impact of PMS dose 98
4.3.3.3. Impact of initial pH 99
4.3.3.4. Impact of temperature 100
4.3.4. Reusability and stability of catalysts 101
4.3.5. Mechanisms of PMS activation on ZIF/Mn/GO 103
4.3.6. Mineralization of CIP and Toxicity evaluation 108
4.3.7. Pathway of CIP degradation 109
4.4. Phase 4: GQDs/Mn 114
4.4.1. Characterization of GQDs/Mn 114
4.4.2. Activity of GQDs/Mn/O3 116
4.4.3. Effect of operating factors on CIP degradation 119
4.4.3.1. Effect of catalyst/O3 dosage 119
4.4.3.2. Effect of initial pH 120
4.4.3.3. Effect of temperature 121
4.4.3.4. Effect of foreign ions 123
4.4.4. Inhibition of bromate formation 124
4.4.5. Feasibility of catalytic ozonation application 126
4.4.6. Mechanisms of CIP degradation in catalytic ozonation 128
4.4.7. Proposed pathway of Cip degradation 131
CHAPTER 5. CONCLUSIONS AND FUTURE DIRECTIONS 134
REFERENCES. 136

1.Xian, Z., et al., Application of FeIII-TAML/H2O2 system for treatment of fluoroquinolone antibiotics. Journal of Environmental Sciences, 2021. 99: p. 110-118.
2.Sodhi, K.K. and D.K. Singh, Insight into the fluoroquinolone resistance, sources, ecotoxicity, and degradation with special emphasis on ciprofloxacin. Journal of Water Process Engineering, 2021. 43: p. 102218.
3.Kovalakova, P., et al., Occurrence and toxicity of antibiotics in the aquatic environment: A review. Chemosphere, 2020. 251: p. 126351.
4.Li, S., et al., Antibiotics in water and sediments of rivers and coastal area of Zhuhai City, Pearl River estuary, south China. Science of the Total Environment, 2018. 636: p. 1009-1019.
5.Cuerda-Correa, E.M., M.F. Alexandre-Franco, and C. Fernández-González, Advanced oxidation processes for the removal of antibiotics from water. An overview. Water, 2019. 12(1): p. 102.
6.Mathur, P., et al., Treatment technologies to mitigate the harmful effects of recalcitrant fluoroquinolone antibiotics on the environ-ment and human health. Environmental Pollution, 2021. 291: p. 118233.
7.Wang, Y., et al., Removal of pharmaceuticals and personal care products from wastewater using algae-based technologies: a review. Reviews in Environmental Science and Bio/Technology, 2017. 16: p. 717-735.
8.Qi, Y., et al., Co/Fe and Co/Al layered double oxides ozone catalyst for the deep degradation of aniline: Preparation, characterization and kinetic model. Science of The Total Environment, 2020. 715: p. 136982.
9.Song, X., et al., Molybdenum disulfide as excellent Co-catalyst boosting catalytic degradation of sulfamethoxazole by nZVI/PDS process. Separation and Purification Technology, 2022. 285: p. 120398.
10.Sun, X., et al., Efficient degradation of methyl orange in water via both radical and non-radical pathways using Fe-Co bimetal-doped MCM-41 as peroxymonosulfate activator. Chemical Engineering Journal, 2020. 402: p. 125881.
11.Lin, K.Y.A., F.K. Hsu, and W.D. Lee, Magnetic cobalt-graphene nanocomposite derived from self-assembly of MOFs with graphene oxide as an activator for peroxymonosulfate. Journal of Materials Chemistry A, 2015. 3(18): p. 9480-9490.
12.Anipsitakis, G.P. and D.D. Dionysiou, Radical generation by the interaction of transition metals with common oxidants. Environmental science & technology, 2004. 38(13): p. 3705-3712.
13.Ghanbari, F. and M. Moradi, Application of peroxymonosulfate and its activation methods for degradation of environmental organic pollutants. Chemical Engineering Journal, 2017. 310: p. 41-62.
14.Du, X. and M. Zhou, Strategies to enhance catalytic performance of metal-organic frameworks in sulfate radical-based advanced oxidation processes for organic pollutants removal. Chemical Engineering Journal, 2020: p. 126346.
15.Hassani, A., et al., Acetaminophen removal from aqueous solutions through peroxymonosulfate activation by CoFe2O4/mpg-C3N4 nanocomposite: Insight into the performance and degradation kinetics. Environmental Technology & Innovation, 2020. 20: p. 14.
16.Lin, K.Y.A. and Z.Y. Zhang, Degradation of Bisphenol A using peroxymonosulfate activated by one-step prepared sulfur-doped carbon nitride as a metal-free heterogeneous catalyst. Chemical Engineering Journal, 2017. 313: p. 1320-1327.
17.Zhao, Z., et al., An ideal confined catalytic model via MOFs derived yolk-shell nanoreactors: The formation mechanism and catalytic performance for single-core and multi-core. Applied Surface Science, 2023. 623: p. 156958.
18.He, P., et al., Heterogeneous activation of peroxymonosulfate by flower-like cobalt sulfide enhanced sulfamethoxazole degradation via non-radical pathways. Applied Surface Science, 2023: p. 157676.
19.Bhat, S.S.M., et al., All-Solution-Processed BiVO4/TiO2 Photoanode with NiCo2O4 Nanofiber Cocatalyst for Enhanced Solar Water Oxidation. Acs Applied Energy Materials, 2020. 3(6): p. 5646-5656.
20.Zhao, S., et al., Regulation of electronic structures of MOF-derived carbon via ligand adjustment for enhanced Fenton-like reactions. Science Of The Total Environment, 2021. 799: p. 149497.
21.Qin, J., S. Wang, and X. Wang, Visible-light reduction CO2 with dodecahedral zeolitic imidazolate framework ZIF-67 as an efficient co-catalyst. Applied Catalysis B: Environmental, 2017. 209: p. 476-482.
22.Wang, S., J. Hu, and J. Wang, Degradation of sulfamethoxazole using PMS activated by cobalt sulfides encapsulated in nitrogen and sulfur co-doped graphene. Science of the Total Environment, 2022. 827: p. 154379.
23.Wang, Q., J. Wang, and L. Duan, Insights into the activation of peroxymonosulfate by ZIF-L@ ZIF-67 derived CoCN catalyst for highly effective removal of phenol in the presence of chloride ions. Applied Surface Science, 2023: p. 158501.
24.Liang, J., et al., Accelerated sulfate radical generation from peroxymonosulfate by ZIF-67-derived Co3O4 encapsulated in g-C3N4: A gift from in situ growth. Chemical Engineering Journal, 2023. 460: p. 141797.
25.Wang, Y., et al., Ternary ZIF-67/MXene/CNF aerogels for enhanced photocatalytic TBBPA degradation via peroxymonosulfate activation. Carbohydrate Polymers, 2022. 298: p. 120100.
26.Shaikh, N., et al., Spectroscopic investigation of interfacial interaction of manganese oxide with triclosan, aniline, and phenol. Environmental Science & Technology, 2016. 50(20): p. 10978-10987.
27.He, D., et al., New insights into MnOOH/peroxymonosulfate system for catalytic oxidation of 2, 4-dichlorophenol: Morphology dependence and mechanisms. Chemosphere, 2020. 255: p. 126961.
28.Liang, P., et al., N-doped graphene from metal–organic frameworks for catalytic oxidation of p-hydroxylbenzoic acid: N-functionality and mechanism. ACS Sustainable Chemistry & Engineering, 2017. 5(3): p. 2693-2701.
29.Zhu, J. and J. He, Facile synthesis of graphene-wrapped honeycomb MnO2 nanospheres and their application in supercapacitors. ACS applied materials & interfaces, 2012. 4(3): p. 1770-1776.
30.Choi, W., et al., Synthesis of graphene and its applications: a review. Critical Reviews in Solid State and Materials Sciences, 2010. 35(1): p. 52-71.
31.Wang, J. and H. Chen, Catalytic ozonation for water and wastewater treatment: Recent advances and perspective. Science of the Total Environment, 2020. 704: p. 135249.
32.Yang, W. and T. Wu, Investigation of matrix effects in laboratory studies of catalytic ozonation processes. Industrial & Engineering Chemistry Research, 2019. 58(8): p. 3468-3477.
33.Guo, Y., et al., The application and reaction mechanism of catalytic ozonation in water treatment. J Environ Anal Toxicol, 2012. 2(7): p. 2161-0525.1000150.
34.Kruanak, K. and C. Jarusutthirak, Degradation of 2, 4, 6-trichlorophenol in synthetic wastewater by catalytic ozonation using alumina supported nickel oxides. Journal of Environmental Chemical Engineering, 2019. 7(1): p. 102825.
35.Luo, L., et al., Heterogeneous catalytic ozonation of ciprofloxacin in aqueous solution using a manganese-modified silicate ore. RSC advances, 2018. 8(58): p. 33534-33541.
36.Wang, Y., et al., Metal-free catalytic ozonation on surface-engineered graphene: microwave reduction and heteroatom doping. Chemical Engineering Journal, 2019. 355: p. 118-129.
37.Nawaz, F., et al., Catalytic ozonation of 4-nitrophenol over an mesoporous α-MnO2 with resistance to leaching. Catalysis Today, 2015. 258: p. 595-601.
38.Wang, Y., et al., The role of Mn-doping for catalytic ozonation of phenol using Mn/γ-Al2O3 nanocatalyst: performance and mechanism. Journal of Environmental Chemical Engineering, 2016. 4(3): p. 3415-3425.
39.Zhang, Z., et al., Catalytic deep degradation of Cl-VOCs with the assistance of ozone at low temperature over MnO2 catalysts. Chemical Engineering Journal, 2021. 426: p. 130814.
40.Elizarova, G., G. Zhidomirov, and V. Parmon, Hydroxides of transition metals as artificial catalysts for oxidation of water to dioxygen. Catalysis Today, 2000. 58(2-3): p. 71-88.
41.Huang, Y., et al., Efficient catalytic activity and bromate minimization over lattice oxygen-rich MnOOH nanorods in catalytic ozonation of bromide-containing organic pollutants: Lattice oxygen-directed redox cycle and bromate reduction. Journal of Hazardous Materials, 2021. 410: p. 124545.
42.Nguyen, T.-B., et al., Construction of ternary NiCo@MnOOH/GO composite for peroxymonosulfate activation with enhanced catalytic activity toward ciprofloxacin degradation. Chemical Engineering Journal, 2022: p. 137326.
43.Anh, N.T.N., A.D. Chowdhury, and R.-a. Doong, Highly sensitive and selective detection of mercury ions using N, S-codoped graphene quantum dots and its paper strip based sensing application in wastewater. Sensors and Actuators B: Chemical, 2017. 252: p. 1169-1178.
44.Sweetman, M.J., et al., A Practical Guide to Prepare and Synthetically Modify Graphene Quantum Dots. Advanced Functional Materials, 2019. 29(14): p. 18.
45.Al-Buriahi, A.K., et al., Ciprofloxacin removal from non-clinical environment: A critical review of current methods and future trend prospects. Journal of Water Process Engineering, 2022. 47: p. 102725.
46.Gothwal, R. and T. Shashidhar, Antibiotic pollution in the environment: a review. Clean–Soil, Air, Water, 2015. 43(4): p. 479-489.
47.Babuponnusami, A. and K. Muthukumar, A review on Fenton and improvements to the Fenton process for wastewater treatment. Journal of Environmental Chemical Engineering, 2014. 2(1): p. 557-572.
48.Giannakis, S., K.-Y.A. Lin, and F. Ghanbari, A review of the recent advances on the treatment of industrial wastewaters by Sulfate Radical-based Advanced Oxidation Processes (SR-AOPs). Chemical Engineering Journal, 2021. 406: p. 127083.
49.Nidheesh, P., et al., Treatment of textile wastewater by sulfate radical based advanced oxidation processes. Separation and Purification Technology, 2022: p. 121115.
50.Wang, J. and S. Wang, Activation of persulfate (PS) and peroxymonosulfate (PMS) and application for the degradation of emerging contaminants. Chemical Engineering Journal, 2018. 334: p. 1502-1517.
51.Hassani, A., et al., Sulfate radicals-based advanced oxidation processes for the degradation of pharmaceuticals and personal care products: A review on relevant activation mechanisms, performance, and perspectives. Environmental Research, 2022: p. 114789.
52.Feng, M., et al., Synergistic effect of aqueous removal of fluoroquinolones by a combined use of peroxymonosulfate and ferrate (VI). Chemosphere, 2017. 177: p. 144-148.
53.Feng, Y., et al., Sulfate radical-mediated degradation of sulfadiazine by CuFeO2 rhombohedral crystal-catalyzed peroxymonosulfate: synergistic effects and mechanisms. Environmental Science & Technology, 2016. 50(6): p. 3119-3127.
54.Deng, J., et al., Heterogeneous activation of peroxymonosulfate using ordered mesoporous Co3O4 for the degradation of chloramphenicol at neutral pH. Chemical Engineering Journal, 2017. 308: p. 505-515.
55.Feng, Y., et al., Cu2O-promoted degradation of sulfamethoxazole by α-Fe2O3-catalyzed peroxymonosulfate under circumneutral conditions: synergistic effect, Cu/Fe ratios, and mechanisms. Environmental technology, 2018. 39(1): p. 1-11.
56.Ao, X. and W. Liu, Degradation of sulfamethoxazole by medium pressure UV and oxidants: peroxymonosulfate, persulfate, and hydrogen peroxide. Chemical Engineering Journal, 2017. 313: p. 629-637.
57.Ao, X., et al., Degradation of tetracycline by medium pressure UV-activated peroxymonosulfate process: influencing factors, degradation pathways, and toxicity evaluation. Chemical Engineering Journal, 2019. 361: p. 1053-1062.
58.Wang, S. and J. Wang, Degradation of carbamazepine by radiation-induced activation of peroxymonosulfate. Chemical Engineering Journal, 2018. 336: p. 595-601.
59.Mahdi-Ahmed, M. and S. Chiron, Ciprofloxacin oxidation by UV-C activated peroxymonosulfate in wastewater. Journal of hazardous materials, 2014. 265: p. 41-46.
60.Deng, J., et al., Iron-doped ordered mesoporous Co3O4 activation of peroxymonosulfate for ciprofloxacin degradation: Performance, mechanism and degradation pathway. Science of The Total Environment, 2019. 658: p. 343-356.
61.Deng, J., et al., Degradation of ciprofloxacin using α-MnO2 activated peroxymonosulfate process: effect of water constituents, degradation intermediates and toxicity evaluation. Chemical Engineering Journal, 2017. 330: p. 1390-1400.
62.You, Y., et al., Synthesis of magnetized nitrogen-doped biochar and its high efficiency for elimination of ciprofloxacin hydrochloride by activation of peroxymonosulfate. Separation and Purification Technology, 2021. 258: p. 117977.
63.Qin, Y., et al., Three-dimensional Co–N/SBA-15/alginate hydrogels with excellent recovery and recyclability for activating peroxymonosulfate to degrade ciprofloxacin. Microporous and Mesoporous Materials, 2021. 323: p. 111259.
64.Choong, Z.-Y., K.-Y.A. Lin, and W.-D. Oh, Copper ferrite anchored on hexagonal boron nitride as peroxymonosulfate activator for ciprofloxacin removal. Materials Letters, 2021. 285: p. 129079.
65.Huang, Y., et al., Catalytic degradation of ciprofloxacin by magnetic CuS/Fe2O3/Mn2O3 nanocomposite activated peroxymonosulfate: Influence factors, degradation pathways and reaction mechanism. Chemical Engineering Journal, 2020. 388: p. 124274.
66.Luo, H., et al., Lignocellulosic biomass derived N-doped and CoO-loaded carbocatalyst used as highly efficient peroxymonosulfate activator for ciprofloxacin degradation. Journal of Colloid and Interface Science, 2021.
67.Zhao, Z., J. Zhao, and C. Yang, Efficient removal of ciprofloxacin by peroxymonosulfate/Mn3O4-MnO2 catalytic oxidation system. Chemical Engineering Journal, 2017. 327: p. 481-489.
68.Shen, C.-H., et al., Visible-light-driven activation of peroxymonosulfate for accelerating ciprofloxacin degradation using CeO2/Co3O4 pn heterojunction photocatalysts. Chemical Engineering Journal, 2020. 391: p. 123612.
69.Zhao, J., et al., Efficient degradation of ciprofloxacin by magnetic γ-Fe2O3–MnO2 with oxygen vacancy in visible-light/peroxymonosulfate system. Chemosphere, 2021. 276: p. 130257.
70.Wang, J., et al., Degradation of organic pollutants by ultraviolet/ozone in high salinity condition: Non-radical pathway dominated by singlet oxygen. Chemosphere, 2021. 268: p. 128796.
71.Liu, H., et al., The application of UV/O3 process on ciprofloxacin wastewater containing high salinity: Performance and its degradation mechanism. Chemosphere, 2021. 276: p. 130220.
72.Wang, H., et al., pH-dependent norfloxacin degradation by E+-ozonation: Radical reactivities and intermediates identification. Journal of cleaner production, 2020. 265: p. 121722.
73.Caianelo, M., et al., Evaluation of residual antimicrobial activity and acute toxicity during the degradation of gatifloxacin by ozonation. Water Science and Technology, 2021. 84(1): p. 225-236.
74.He, Y., et al., Catalytic ozonation for metoprolol and ibuprofen removal over different MnO2 nanocrystals: Efficiency, transformation and mechanism. Science of the Total Environment, 2021. 785: p. 147328.
75.Yang, Y., et al., Ceramic nanofiber membrane anchoring nanosized Mn2O3 catalytic ozonation of sulfamethoxazole in water. Journal of Hazardous Materials, 2022. 436: p. 129168.
76.Li, P., et al., Highly porous α-MnO2 nanorods with enhanced defect accessibility for efficient catalytic ozonation of refractory pollutants. Journal of Hazardous Materials, 2022: p. 129235.
77.Zhang, Z., et al., A new insight into catalytic ozonation of ammonia by MgO/Co3O4 composite: The effects, reaction kinetics and mechanism. Chemical Engineering Journal, 2021. 418: p. 129461.
78.Yu, Y., et al., MnFe2O4 decorated graphene as a heterogeneous catalyst for efficient degradation of di-n-butyl phthalate using catalytic ozonation in water. Separation and Purification Technology, 2021. 259: p. 118097.
79.Liang, D., et al., Highly efficient catalytic ozonation for ammonium in water upon γ-Al2O3@ Fe/Mg with acidic-basic sites and oxygen vacancies. Science of The Total Environment, 2022. 834: p. 155278.
80.Su, W., et al., Catalytic ozonation of N, N-dimethylacetamide in aqueous solution by Fe3O4@ SiO2@ MgO composite: Optimization, degradation pathways and mechanism. Journal of the Taiwan Institute of Chemical Engineers, 2022. 135: p. 104380.
81.Luo, K., et al., Synthesis of petal-like δ-MnO 2 and its catalytic ozonation performance. New Journal of Chemistry, 2018. 42(9): p. 6770-6777.
82.Wu, Z., et al., Insights into mechanism of catalytic ozonation over practicable mesoporous Mn-CeO x/γ-Al2O3 catalysts. Industrial & Engineering Chemistry Research, 2018. 57(6): p. 1943-1953.
83.Bricker, O., Some stability relations in the system Mn-O2-H2O at 25 and one atmosphere total pressure. American Mineralogist: Journal of Earth and Planetary Materials, 1965. 50(9): p. 1296-1354.
84.Gabelich, C.J., et al., Sequential manganese desorption and sequestration in anthracite coal and silica sand filter media. Journal‐American Water Works Association, 2006. 98(5): p. 116-127.
85.Kessick, M.A. and J.J. Morgan, Mechanism of autoxidation of manganese in aqueous solution. Environmental Science & Technology, 1975. 9(2): p. 157-159.
86.Ramstedt, M., et al., Thermodynamic and spectroscopic studies of cadmium (II)–N-(phosphonomethyl) glycine (PMG) complexes. Inorganica chimica acta, 2004. 357(4): p. 1185-1192.
87.Sahu, R.S., K. Bindumadhavan, and R.A. Doong, Boron-doped reduced graphene oxide-based bimetallic Ni/Fe nanohybrids for the rapid dechlorination of trichloroethylene. Environmental Science-Nano, 2017. 4(3): p. 565-576.
88.Zhao, J., et al., Magnetic field enhanced denitrification in nitrate and ammonia contaminated water under 3D/2D Mn2O3/g-C3N4 photocatalysis. Chemical Engineering Journal, 2018. 349: p. 530-538.
89.Liu, C., et al., Chlorine intercalation in graphitic carbon nitride for efficient photocatalysis. Applied Catalysis B: Environmental, 2017. 203: p. 465-474.
90.Liu, P., et al., Rational synthesis of highly uniform hollow core–shell Mn3O4/CuO@ TiO2 submicroboxes for enhanced lithium storage performance. Chemical Engineering Journal, 2017. 316: p. 214-224.
91.Kutty, R.K.N., et al., Structural and magnetic properties of CoMn2O4 synthesized by auto combustion method. Journal of Materials Science: Materials in Electronics, 2019. 30(2): p. 975-981.
92.Naresh, B., et al., Reagent induced morphological changes in NiCo2O4 electrode material for flexible supercapacitor. Materials Letters, 2019. 248: p. 218-221.
93.Nguyen, T.B., et al., CoO-3D ordered mesoporous carbon nitride (CoOCN) composite as peroxymonosulfate activator for the degradation of sulfamethoxazole in water. 2021.
94.Li, C.-X., et al., Metal organic framework-derived CoMn2O4 catalyst for heterogeneous activation of peroxymonosulfate and sulfanilamide degradation. Chemical Engineering Journal, 2018. 337: p. 101-109.
95.Wang, Y., et al., Nanoscaled magnetic CuFe2O4 as an activator of peroxymonosulfate for the degradation of antibiotics norfloxacin. Separation and Purification Technology, 2019. 212: p. 536-544.
96.Qin, W., et al., Mechanistic understanding of polychlorinated biphenyls degradation by peroxymonosulfate activated with CuFe2O4 nanoparticles: Key role of superoxide radicals. Chemical Engineering Journal, 2018. 348: p. 526-534.
97.Al-Anazi, A., et al., Cobalt ferrite nanoparticles with controlled composition-peroxymonosulfate mediated degradation of 2-phenylbenzimidazole-5-sulfonic acid. Applied Catalysis B: Environmental, 2018. 221: p. 266-279.
98.Asif, A.H., et al., Heterogeneous activation of peroxymonosulfate by Co-doped Fe2O3 nanospheres for degradation of p-hydroxybenzoic acid. Journal of Colloid and Interface Science, 2021. 604: p. 390-401.
99.Hassani, A., et al., Acetaminophen removal from aqueous solutions through peroxymonosulfate activation by CoFe2O4/mpg-C3N4 nanocomposite: Insight into the performance and degradation kinetics. Environmental Technology & Innovation, 2020. 20: p. 101127.
100.Cao, J., et al., Efficient charge transfer in aluminum-cobalt layered double hydroxide derived from Co-ZIF for enhanced catalytic degradation of tetracycline through peroxymonosulfate activation. Chemical Engineering Journal, 2020. 382: p. 122802.
101.Nguyen, T.-B., et al., A Z-scheme NiCo 2 O 4/S codoped 1D gC 3 N 4 heterojunction for solar-light-sensitive photocatalytic degradation of antibiotics in aqueous solutions exemplified by tetracycline. Environmental Science: Nano, 2022. 9(1): p. 229-242.
102.Khan, A., et al., Degradation of antibiotics in aqueous media using manganese nanocatalyst-activated peroxymonosulfate. Journal of Colloid and Interface Science, 2021. 599: p. 805-818.
103.Lin, K.-Y.A., F.-K. Hsu, and W.-D. Lee, Magnetic cobalt–graphene nanocomposite derived from self-assembly of MOFs with graphene oxide as an activator for peroxymonosulfate. Journal of Materials Chemistry A, 2015. 3(18): p. 9480-9490.
104.Shah, N.S., et al., Hydroxyl and sulfate radical mediated degradation of ciprofloxacin using nano zerovalent manganese catalyzed S2O82−. Chemical Engineering Journal, 2019. 356: p. 199-209.
105.Lin, H., et al., Degradation of bisphenol A by activating peroxymonosulfate with Mn0. 6Zn0. 4Fe2O4 fabricated from spent Zn-Mn alkaline batteries. Chemical Engineering Journal, 2019. 364: p. 541-551.
106.Hu, L.M., et al., Enhanced degradation of Bisphenol A (BPA) by peroxymonosulfate with Co3O4-Bi2O3 catalyst activation: Effects of pH, inorganic anions, and water matrix. Chemical Engineering Journal, 2018. 338: p. 300-310.
107.Lin, K.-Y.A., et al., Prussian Blue analogue supported on sulfur-doped carbon nitride as an enhanced heterogeneous catalyst for activating peroxymonosulfate. Journal of colloid and interface science, 2018. 529: p. 161-170.
108.Sahu, R.S., K. Bindumadhavan, and R.-a. Doong, Boron-doped reduced graphene oxide-based bimetallic Ni/Fe nanohybrids for the rapid dechlorination of trichloroethylene. Environmental Science: Nano, 2017. 4(3): p. 565-576.
109.Lim, J., et al., Visible light-induced catalytic activation of peroxymonosulfate using heterogeneous surface complexes of amino acids on TiO2. Applied Catalysis B-Environmental, 2018. 225: p. 406-414.
110.Lin, K.-Y.A., H.-K. Lai, and S. Tong, One-step prepared cobalt-based nanosheet as an efficient heterogeneous catalyst for activating peroxymonosulfate to degrade caffeine in water. Journal of colloid and interface science, 2018. 514: p. 272-280.
111.Li, W., et al., Mechanism of persulfate activation with CuO for removing cephalexin and ofloxacin in water. Research on Chemical Intermediates, 2019. 45(11): p. 5549-5558.
112.Nguyen, T.B., et al., Construction of ternary NiCo@MnOOH/GO composite for peroxymonosulfate activation with enhanced catalytic activity toward ciprofloxacin degradation. Chemical Engineering Journal, 2022. 446: p. 14.
113.Kang, S. and J. Hwang, CoMn2O4 embedded hollow activated carbon nanofibers as a novel peroxymonosulfate activator. Chemical Engineering Journal, 2021. 406: p. 14.
114.Lin, K.Y.A. and B.J. Chen, Magnetic carbon-supported cobalt derived from a Prussian blue analogue as a heterogeneous catalyst to activate peroxymonosulfate for efficient degradation of caffeine in water. Journal of Colloid and Interface Science, 2017. 486: p. 255-264.
115.Kabel, K.I., A.H. Mady, and A.M. Rabie, Novel preparation of ferromanganese oxide based on hyperbranched polymer for peroxymonosulfate activation as a robust catalyst for the degradation of organic pollutants. Environmental Technology & Innovation, 2021. 22: p. 12.
116.Nguyen, T.B., et al., CoO-3D ordered mesoporous carbon nitride (CoO@mpgCN) composite as peroxymonosulfate activator for the degradation of sulfamethoxazole in water. Journal of Hazardous Materials, 2021. 401: p. 11.
117.Ganesan, V., C. Louis, and S.P. Damodaran, Graphene oxide-wrapped magnetite nanoclusters: A recyclable functional hybrid for fast and highly efficient removal of organic dyes from wastewater. Journal of Environmental Chemical Engineering, 2018. 6(2): p. 2176-2190.
118.Yang, R., et al., Synthesis and characterization of single-crystalline nanorods of α-MnO2 and γ-MnOOH. Materials chemistry and physics, 2005. 93(1): p. 149-153.
119.Sharma, P.K. and M.S. Whittingham, The role of tetraethyl ammonium hydroxide on the phase determination and electrical properties of gamma-MnOOH synthesized by hydrothermal. Materials Letters, 2001. 48(6): p. 319-323.
120.Yu, H., et al., High-efficient synthesis of graphene oxide based on improved hummers method. Scientific reports, 2016. 6(1): p. 1-7.
121.Chen, P., L. Guo, and Y. Wang, Graphene wrapped SnCo nanoparticles for high-capacity lithium ion storage. Journal of Power Sources, 2013. 222: p. 526-532.
122.Soltani, T. and B.-K. Lee, A benign ultrasonic route to reduced graphene oxide from pristine graphite. Journal of colloid and interface science, 2017. 486: p. 337-343.
123.Zhou, F., et al., Synthesis of γ-MnOOH nanorods and their isomorphous transformation into β-MnO 2 and α-Mn 2 O 3 nanorods. Journal of materials science, 2007. 42(24): p. 9978-9982.
124.Asgari, G., et al., Prediction and Optimization of Pentachlorophenol Degradation and Mineralization in Heterogeneous Catalytic Ozonation Using Artificial Neural Network. Journal of Water Chemistry and Technology, 2020. 42(3): p. 164-170.
125.Yang, S.S., et al., Efficient peroxymonosulfate activation and bisphenol A degradation derived from mineral-carbon materials: Key role of double mineral-templates. Applied Catalysis B-Environmental, 2020. 267: p. 11.
126.Nfodzo, P. and H. Choi, Triclosan decomposition by sulfate radicals: effects of oxidant and metal doses. Chemical Engineering Journal, 2011. 174(2-3): p. 629-634.
127.Rastogi, A., S.R. Al-Abed, and D.D. Dionysiou, Sulfate radical-based ferrous–peroxymonosulfate oxidative system for PCBs degradation in aqueous and sediment systems. Applied catalysis B: environmental, 2009. 85(3-4): p. 171-179.
128.Solis, R.R., et al., Activation of inorganic peroxides with magnetic graphene for the removal of antibiotics from wastewater. Environmental Science-Nano, 2021. 8(4): p. 960-977.
129.Asif, A.H., et al., Heterogeneous activation of peroxymonosulfate by Co-doped Fe2O3 nanospheres for degradation of p-hydroxybenzoic acid. Journal of Colloid and Interface Science, 2021. 604: p. 390-401.
130.Qu, S., et al., Enhancement of peroxymonosulfate activation and utilization efficiency via iron oxychloride nanosheets in visible light. Separation and Purification Technology, 2019. 224: p. 132-141.
131.Chan, K. and W. Chu, Degradation of atrazine by cobalt-mediated activation of peroxymonosulfate: different cobalt counteranions in homogenous process and cobalt oxide catalysts in photolytic heterogeneous process. Water Research, 2009. 43(9): p. 2513-2521.
132.Peng, X., et al., Amine-functionalized magnetic bamboo-based activated carbon adsorptive removal of ciprofloxacin and norfloxacin: A batch and fixed-bed column study. Bioresource Technology, 2018. 249: p. 924-934.
133.Fernandes, A., P. Makos, and G. Boczkaj, Treatment of bitumen post oxidative effluents by sulfate radicals based advanced oxidation processes (S-AOPs) under alkaline pH conditions. Journal of Cleaner Production, 2018. 195: p. 374-384.
134.Lin, K.Y.A., et al., Prussian Blue analogue supported on sulfur-doped carbon nitride as an enhanced heterogeneous catalyst for activating peroxymonosulfate. Journal of Colloid and Interface Science, 2018. 529: p. 161-170.
135.Lin, K.Y.A., H.K. Lai, and S.P. Tong, One-step prepared cobalt-based nanosheet as an efficient heterogeneous catalyst for activating peroxymonosulfate to degrade caffeine in water. Journal of Colloid and Interface Science, 2018. 514: p. 272-280.
136.Ghanbari, F., M. Ahmadi, and F. Gohari, Heterogeneous activation of peroxymonosulfate via nanocomposite CeO2-Fe3O4 for organic pollutants removal: The effect of UV and US irradiation and application for real wastewater. Separation and Purification Technology, 2019. 228: p. 10.
137.Li, J., et al., Enhanced peroxymonosulfate activation by supported microporous carbon for degradation of tetracycline via non-radical mechanism. Separation and Purification Technology, 2020. 240: p. 11.
138.Gao, P.P., et al., Promoted peroxymonosulfate activation into singlet oxygen over perovskite for ofloxacin degradation by controlling the oxygen defect concentration. Chemical Engineering Journal, 2019. 359: p. 828-839.
139.Li, Z.D., et al., Singlet oxygen dominated peroxymonosulfate activation by CuO-CeO2 for organic pollutants degradation: Performance and mechanism. Chemosphere, 2019. 233: p. 549-558.
140.Reyes, C., et al., Degradation and inactivation of tetracycline by TiO2 photocatalysis. Journal of Photochemistry and Photobiology a-Chemistry, 2006. 184(1-2): p. 141-146.
141.Yahiat, S., et al., Removal of antibiotics by an integrated process coupling photocatalysis and biological treatment - Case of tetracycline and tylosin. International Biodeterioration & Biodegradation, 2011. 65(7): p. 997-1003.
142.Zhang, T., et al., Synthesis of Fe3O4@ ZIF-8 magnetic core–shell microspheres and their potential application in a capillary microreactor. Chemical engineering journal, 2013. 228: p. 398-404.
143.Yang, Q., et al., Selective separation of methyl orange from water using magnetic ZIF-67 composites. Chemical Engineering Journal, 2018. 333: p. 49-57.
144.Le, V.-R., et al., Catalytic ozonation performance of graphene quantum dot doped MnOOH nanorod for effective treatment of ciprofloxacin and bromate formation control in water. Separation and Purification Technology, 2023. 315: p. 123672.
145.Lin, K.-Y.A. and H.-A. Chang, Ultra-high adsorption capacity of zeolitic imidazole framework-67 (ZIF-67) for removal of malachite green from water. Chemosphere, 2015. 139: p. 624-631.
146.Thai, V.-A., et al., Graphene quantum dots (GQDs) decorated zeolitic imidazole framework-67 (ZIF67) electrode for the in-situ oxidation of ciprofloxacin in water. Environmental Technology & Innovation, 2023. 30: p. 103039.
147.Yu, Y.-b., et al., Reaction mechanism of N-(4-hydroxyphenyl) ethanamide electrodegradation via phosphorus-graphene prepared from triphenylphosphine: Generation and destruction of the reactive species. Chemical Engineering Journal, 2021. 403: p. 126322.
148.Nguyen, T.B., et al., CoO-3D ordered mesoporous carbon nitride (CoO@ mpgCN) composite as peroxymonosulfate activator for the degradation of sulfamethoxazole in water. Journal of Hazardous Materials, 2021. 401: p. 123326.
149.Le, V.-R., et al., Peroxymonosulfate activation over NiCo@MnOOH for enhancing Ciprofloxacin degradation in water. Environmental Technology & Innovation, 2023. 30: p. 103117.
150.Ren, W., et al., The intrinsic nature of persulfate activation and N-doping in carbocatalysis. Environmental Science & Technology, 2020. 54(10): p. 6438-6447.
151.Chen, C., et al., Single-atom co sites confined in layered double hydroxide for selective generation of surface-bound radicals via peroxymonosulfate activation. Applied Catalysis B: Environmental, 2024. 340: p. 123218.
152.Ren, Y., et al., Sulfate radicals induced from peroxymonosulfate by magnetic ferrospinel MFe2O4 (M= Co, Cu, Mn, and Zn) as heterogeneous catalysts in the water. Applied Catalysis B: Environmental, 2015. 165: p. 572-578.
153.Dou, J., et al., Biochar co-doped with nitrogen and boron switching the free radical based peroxydisulfate activation into the electron-transfer dominated nonradical process. Applied Catalysis B: Environmental, 2022. 301: p. 120832.
154.Song, L., et al., In-situ growth of Mn2O3/MnCo2O4 on 3D nickel foam as a novel heterogeneous composites peroxymonosulfate activator for the degradation of levofloxacin: Performance, stability and mechanism. Chemical Engineering Journal, 2023: p. 144629.
155.Shao, P., et al., Revisiting the graphitized nanodiamond-mediated activation of peroxymonosulfate: singlet oxygenation versus electron transfer. Environmental Science & Technology, 2021. 55(23): p. 16078-16087.
156.Bu, Y., et al., Peroxydisulfate activation and singlet oxygen generation by oxygen vacancy for degradation of contaminants. Environmental Science & Technology, 2021. 55(3): p. 2110-2120.
157.Khan, A., et al., Highly efficient α-Mn 2 O 3@ α-MnO 2-500 nanocomposite for peroxymonosulfate activation: comprehensive investigation of manganese oxides. Journal of Materials Chemistry A, 2018. 6(4): p. 1590-1600.
158.He, Y., et al., Revealing the crystal phase effect of CeO2 in spinel-based nanocatalysts toward the peroxymonosulfate activation for organics degradation. Chemical Engineering Journal, 2023: p. 145737.
159.Chen, Z., et al., Enhanced degradation of triclosan by cobalt manganese spinel-type oxide activated peroxymonosulfate oxidation process via sulfate radicals and singlet oxygen: Mechanisms and intermediates identification. Science of The Total Environment, 2020. 711: p. 134715.
160.Deng, Q., et al., The MOF/LDH derived heterostructured Co3O4/MnCo2O4 composite for enhanced degradation of levofloxacin by peroxymonosulfate activation. Separation and Purification Technology, 2022. 294: p. 121182.
161.Kang, S. and J. Hwang, CoMn2O4 embedded hollow activated carbon nanofibers as a novel peroxymonosulfate activator. Chemical Engineering Journal, 2021. 406: p. 127158.
162.Nguyen, T.-B., et al., Construction of ternary NiCo@MnOOH/GO composite for peroxymonosulfate activation with enhanced catalytic activity toward ciprofloxacin degradation. Chemical Engineering Journal, 2022. 446: p. 137326.
163.Yao, Y., et al., Sulfate radicals induced from peroxymonosulfate by cobalt manganese oxides (CoxMn3− xO4) for Fenton-Like reaction in water. Journal of Hazardous Materials, 2015. 296: p. 128-137.
164.Lin, K.-Y.A. and B.-J. Chen, Magnetic carbon-supported cobalt derived from a Prussian blue analogue as a heterogeneous catalyst to activate peroxymonosulfate for efficient degradation of caffeine in water. Journal of colloid and interface science, 2017. 486: p. 255-264.
165.Kabel, K.I., A.H. Mady, and A.M. Rabie, Novel preparation of ferromanganese oxide based on hyperbranched polymer for peroxymonosulfate activation as a robust catalyst for the degradation of organic pollutants. Environmental Technology & Innovation, 2021. 22: p. 101435.
166.Gao, P., et al., Promoted peroxymonosulfate activation into singlet oxygen over perovskite for ofloxacin degradation by controlling the oxygen defect concentration. Chemical Engineering Journal, 2019. 359: p. 828-839.
167.Ahamad, T., M. Naushad, and S.M. Alshehri, Analysis of degradation pathways and intermediates products for ciprofloxacin using a highly porous photocatalyst. Chemical Engineering Journal, 2021. 417: p. 127969.
168.Liu, W.-J., et al., Enhanced degradation of ultra-violet stabilizer Bis (4-hydroxy) benzophenone using oxone catalyzed by hexagonal nanoplate-assembled CoS 3-dimensional cluster. Chemosphere, 2022. 288: p. 132427.
169.Bayoudh, A., N. Etteyeb, and R. Kossai, Hydrothermal synthesis, characterization and electrochemical properties of gamma-MnOOH nanobelts. Ceramics International, 2015. 41(9): p. 12273-12279.
170.Ghuge, S.P. and A.K. Saroha, Catalytic ozonation for the treatment of synthetic and industrial effluents-Application of mesoporous materials: A review. Journal of Environmental Management, 2018. 211: p. 83-102.
171.Gomes, J.F., et al., Study of the influence of the matrix characteristics over the photocatalytic ozonation of parabens using Ag-TiO2. Science of the Total Environment, 2019. 646: p. 1468-1477.
172.Boczkaj, G. and A. Fernandes, Wastewater treatment by means of advanced oxidation processes at basic pH conditions: a review. Chemical Engineering Journal, 2017. 320: p. 608-633.
173.Nosaka, Y. and A.Y. Nosaka, Generation and detection of reactive oxygen species in photocatalysis. Chemical reviews, 2017. 117(17): p. 11302-11336.
174.Nguyen, T.B., C.P. Huang, and R.A. Doong, Photocatalytic degradation of bisphenol A over a ZnFe2O4/TiO2 nanocomposite under visible light. Science of the Total Environment, 2019. 646: p. 745-756.
175.Aghaeinejad-Meybodi, A., et al., Comparative investigation on catalytic ozonation of Fluoxetine antidepressant drug in the presence of boehmite and gamma-alumina nanocatalysts: operational parameters, kinetics and degradation mechanism studies. Chemical Papers, 2021. 75(1): p. 421-430.
176.Shang, K.F., et al., Synergetic degradation of Acid Orange 7 (AO7) dye by DBD plasma and persulfate. Chemical Engineering Journal, 2017. 311: p. 378-384.
177.Yao, W., et al., Comparison of methylisoborneol and geosmin abatement in surface water by conventional ozonation and an electro-peroxone process. Water Research, 2017. 108: p. 373-382.
178.Gounden, A.N. and S.B. Jonnalagadda, Advances in Treatment of Brominated Hydrocarbons by Heterogeneous Catalytic Ozonation and Bromate Minimization. Molecules, 2019. 24(19): p. 18.
179.Joshi, R., et al., Bromate formation control by enhanced ozonation: A critical review. Critical Reviews in Environmental Science and Technology, 2022. 52(7): p. 1154-1198.
180.Bandara, J. and J. Kiwi, Fast kinetic spectroscopy, decoloration and production of H2O2 induced by visible light in oxygenated solutions of the azo dye Orange II. New Journal of Chemistry, 1999. 23(7): p. 717-724.
181.Criquet, J. and N.K.V. Leitner, Reaction pathway of the degradation of the p-hydroxybenzoic acid by sulfate radical generated by ionizing radiations. Radiation Physics and Chemistry, 2015. 106: p. 307-314.
182.Shang, K.F., et al., Degradation of sulfamethoxazole (SMX) by water falling film DBD Plasma/Persulfate: Reactive species identification and their role in SMX degradation. Chemical Engineering Journal, 2022. 431: p. 9.
183.Berekute, A.K., et al., Novel visible-light-induced P-doped g-C3N4/alpha-Bi2O3 nanocomposite photocatalysts for enhanced degradation of refractory endocrine disruptors-benzophenones. Applied Surface Science, 2023. 607: p. 15.
184.Pimentel, J.A.I., et al., Degradation of tetracycline antibiotics by Fe2+-catalyzed percarbonate oxidation. Science of the Total Environment, 2021. 781: p. 9.
185.Nguyen, M.D., et al., Z-scheme S, B co-doped g-C3N4 nanotube@MnO2 heterojunction with visible-light-responsive for enhanced photodegradation of diclofenac by peroxymonosulfate activation. Chemical Engineering Journal, 2023. 452: p. 14.
186.Torres-Blancas, T., et al., Ozonation enhancement by Fe-Cu biometallic particles. Journal of the Taiwan Institute of Chemical Engineers, 2017. 74: p. 225-232.
187.Lyu, Z., et al., Hierarchical nano-vesicles with bimetal-encapsulated for peroxymonosulfate activation: Singlet oxygen-dominated oxidation process. Chemical Engineering Journal, 2022. 433: p. 13.
188.Biard, P.-F., et al., Efficient catalytic ozonation by ruthenium nanoparticles supported on SiO2 or TiO2: Towards the use of a non-woven fiber paper as original support. Chemical Engineering Journal, 2016. 289: p. 374-381.
189.Chen, H. and J. Wang, MOF-derived Co3O4-C@ FeOOH as an efficient catalyst for catalytic ozonation of norfloxacin. Journal of hazardous materials, 2021. 403: p. 123697.
190.Tian, S.-Q., et al., Heterogeneous catalytic ozonation of atrazine with Mn-loaded and Fe-loaded biochar. Water Research, 2021. 193: p. 116860.
191.Nguyen, T.B., et al., Manipulating the morphology of 3D flower-like CoMn2O4 bimetallic catalyst for enhancing the activation of peroxymonosulfate toward the degradation of selected persistent pharmaceuticals in water. Chemical Engineering Journal, 2022. 436: p. 13.
192.Xu, Y., et al., Mechanism and kinetics of catalytic ozonation for elimination of organic compounds with spinel-type CuAl2O4 and its precursor. Science of the Total Environment, 2019. 651: p. 2585-2596.
193.Lee, B.-D., M. Iso, and M. Hosomi, Prediction of Fenton oxidation positions in polycyclic aromatic hydrocarbons by Frontier electron density. Chemosphere, 2001. 42(4): p. 431-435.
194.Zeng, Y., et al., Study on heterogeneous photocatalytic ozonation degradation of ciprofloxacin by TiO2/carbon dots: kinetic, mechanism and pathway investigation. Chemosphere, 2019. 227: p. 198-206.
195.Ding, D., et al., Mechanism insight of degradation of norfloxacin by magnetite nanoparticles activated persulfate: identification of radicals and degradation pathway. Chemical Engineering Journal, 2017. 308: p. 330-339.