臺灣博碩士論文加值系統

目錄
摘要 i
ABSTRACT ii
誌謝 iii
表目錄 vii
圖目錄 viii
第一章 緒論 1
1.1 前言 1
1.2 研究動機 3
第二章 文獻回顧 4
2.1 鈣鈦礦介紹 4
2.2 鈣鈦礦太陽能元件發展簡介 5
2.2.1 溶劑工程 7
2.2.2 退火工藝 8
2.2.3 缺陷鈍化 10
2.3 鈣鈦礦太陽能元件工作原理 12
2.3.1 開路電壓 (Open circuit voltage, VOC) 13
2.3.2 短路電流密度 (Short circuit current density, JSC) 13
2.3.3 填充因子 (Fill factor, FF) 14
2.3.4 光電轉換效率 (Power conversion efficiency, PCE) 14
2.4 元件組成 15
2.4.1 導電基材 15
2.4.2 電洞傳輸層 Hole Transport Layer (HTL) 15
2.4.3 鈣鈦礦層 Perovskite Layer 19
2.4.4 電子傳輸層 Electron Transport Layer (ETL) 20
2.4.5 電洞阻擋層Hole Blocking Layer (HBL) 21
2.4.6 金屬陰極 22
第三章 實驗介紹 23
3.1 實驗藥品與材料 23
3.2 實驗儀器 24
3.3 電洞傳輸材料之合成 26
3.4 反式鈣鈦礦元件材料製備 27
3.4.1 電洞傳輸材料溶液配製 27
3.4.2 鈣鈦礦前驅液配製 27
3.4.3 電子傳輸材料溶液配製 27
3.4.4 電洞阻擋層配製 27
3.4.5 金屬陰極製備 28
3.4.6 光伏元件製作流程 28
3.5 元件製作儀器與分析儀器簡介 30
3.5.1 元件製作儀器簡介 30
3.5.2 分析儀器簡介 32
第四章 結果與討論 42
4.1 DK系列性質分析 42
4.1.1 UV-vis吸收、穿透光譜分析 42
4.1.2 電化學性質分析 44
4.1.3 熱穩定性分析 45
4.1.4 空間電荷限制電流(Space Charge Limited Current, SCLC) 46
4.1.5 DK薄膜水接觸角觀測 47
4.2 DK系列與鈣鈦礦共同分析 48
4.2.1 塗佈於DK上之鈣鈦礦X光繞射光譜分析 48
4.2.2 塗佈於DK上之鈣鈦礦掃描式電子顯微鏡俯視 49
4.2.3 塗佈於DK上之鈣鈦礦原子力顯微鏡俯視 50
4.2.4 塗佈於DK上之鈣鈦礦之UV-vis吸收光譜 51
4.2.5 塗佈於DK上之鈣鈦礦螢光光譜分析 52
4.2.6 不同HTMs之鈣鈦礦缺陷密度 53
4.2.7 DK鈍化鈣鈦礦缺陷之X光電子能譜儀分析 54
4.3 DK系列元件之性能分析 56
4.3.1 不同濃度之元件光伏特性比較 56
4.3.2 優化濃度後之最高效率與平均效率 57
4.3.3 電流穩定性測試 60
4.3.4 長效測試 61
4.4 其餘系列HTMs效率更新 63
第五章 結論 70
參考文獻 71

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