臺灣博碩士論文加值系統

高級氧化程序中，Fenton 氧化程序是利用亞鐵離子和過氧化氫在酸性條件下進行反應，產生出一高氧化能力、非選擇性的氫氧自由基(‧OH），用以氧化廢水中之各種有機物，破壞有機物之鍵結，進一步將廢水中的有機物氧化成二氧化碳和水。本研究使用Electro-Fenton程序降解抗生素(Trimethoprim, TMP)廢水，配合適當參數，探討其礦化作用及去除能力。本系統分別以不銹鋼網及不銹鋼棒為陰陽兩電極之材料，陰極處藉由曝氣產生溶氧，並於通電後還原生成過氧化氫，而陽極處將鐵氧化產生亞鐵離子，進行Fenton反應。
由背景實驗結果可知，本實驗之過氧化氫生成的最佳操作參數為電流1.5 A、空氣曝氣量0.7 NL/min，在此條件下操作180分鐘，其最大過氧化氫淨生成量為57.32 mg/L，而且前30分鐘之生成速率為0.05582 mg-H2O2/min。
研究結果顯示，Fenton氧化程序在pH = 3時，添加10 mg/L 亞鐵離子和50 mg/L 過氧化氫，處理10 mg/L TMP。當反應時間為60分鐘，其TMP去除率為19.3 %；處理時間延長為360分鐘，其TMP、COD、TOC去除率分別為32.1 %、29.2 %、28.1 %。在Electro-Fenton氧化程序中，以生成實驗之最佳操作條件，反應180分鐘後，其TMP去除率為66.0 %；處理時間延長為360分鐘，其TMP、COD、TOC去除率分別為71.8 %、59.4 %、53.6 %。Electro-Fenton氧化程序的處理結果明顯優於傳統的Fenton氧化程序，而且COD去除率和礦化率也都有提升，因此Electro-Fenton氧化程序是有利於TMP之去除，並且增進其礦化效果。

Fenton oxidation process, which is one of the advanced oxidation processes, is performed by reacting ferrous ions with hydrogen peroxide to generate hydroxyl radical (‧OH) under acidic conditions. This process produces a high oxidation ability, non-selective hydroxyl radical which can oxidize a variety of organic matter in the wastewater. Further the powerful oxidizing capability to oxidize organic matter of the wastewater to carbon dioxide and water. In the present study, the application of Electro-Fenton process for the degradation of antibiotic Trimethoprim (TMP) wastewater with the appropriate parameters to explore the mineralization and removal capacity was investigated. The material of cathode and anode were, respectively, stainless steel net and stick used in the system. H2O2 can be electro-generated by reduction of oxygen in the cathode, and ferrous ions can be produced by oxidation of iron in the anode.
Based on the results of background experiment, the optimal parameters for electro-generated H2O2 was at current of 1.5 A and air flow of 0.7 NL/min. Under these conditions, the maximum remnant of H2O2 was 57.32 mg/L in 180 min of operation. The formation rate was 0.05582 mg-H2O2/min in 30 min before the reaction.
Results show that the Fenton process can degrade 10 mg/L TMP by using 10 mg/L ferrous ions and 50 mg/L hydrogen peroxide in acidic solution after 60 min. The TMP removal rate is 19.3 %. When the treatment time is extended to 360 min, the TMP, COD and TOC removal rates are 32.1, 29.2, and 28.1 % respectively. Electro-Fenton oxidation process with optimal parameters found in generation experiment, the TMP removal rate is 66.0 % after 180 min. When the treatment time is extended to 360 min, the TMP, COD and TOC removal rate are 71.8, 59.4, and 53.6 % separately. The results are significantly better than traditional Fenton oxidation process. The COD removal rate and mineralization are also enhanced. Electro-Fenton oxidation process is conducive to the removal of TMP, and enhance the mineralization.

摘要 I
Abstract III
目錄 V
表目錄 VIII
圖目錄 IX
第一章 前言 1
1-1 研究緣起 1
1-2 研究目的 1
1-3 研究內容 1
第二章 文獻回顧 3
2-1藥物與個人保健用品之簡介 3
2-1-1 抗生素的分類 4
2-1-2 抗生素在環境中之流佈 5
2-1-3 抗生素之危害 7
2-2 TMP簡介 8
2-2-1 TMP藥理特性 8
2-2-2 TMP作用機轉 8
2-2-3 TMP在環境中的流佈與相關研究 9
2-3芬頓氧化程序 11
2-3-1 芬頓氧化原理 11
2-3-2 芬頓氧化程序之影響因子 13
2-3-3 芬頓氧化程序之優缺點 15
2-3-4 芬頓氧化程序之相關研究 17
2-4電芬頓氧化程序 19
2-4-1 電解作用 19
2-4-2電芬頓氧化原理 19
2-4-3 電芬頓氧化程序之影響因子 22
2-4-4電芬頓氧化程序之優缺點 24
2-4-5電芬頓氧化程序之相關研究 25
第三章 材料與方法 27
3-1實驗設計 27
3-2 實驗操作 30
3-2-1 系統控制參數 30
3-2-1-1 檢量線製作 30
3-2-1-2背景實驗 31
3-3系統裝置 35
3-4 實驗藥品及配製 36
3-4-1 實驗藥品 36
3-4-2 實驗藥品配製 37
3-5 實驗設備 38
3-6 實驗分析方法 39
3-6-1TMP濃度分析方法 39
3-6-2亞鐵離子分析方法 39
3-6-3過氧化氫分析方法 40
3-6-4 COD分析方法 40
3-6-5 總有機碳分析方法 41
第四章 結果與討論 43
4-1 檢量線建立 43
4-2 TMP全波長分析 43
4-3 背景實驗 45
4-3-1 生成實驗 45
4-3-1-1 電流對Fe2+和H2O2淨生成量之影響 45
4-3-1-2 空氣曝氣量對Fe2+和H2O2淨生成量之影響 49
4-3-2 直接電解 51
4-4 最佳操作參數 54
4-4-1 Fenton氧化程序 54
4-4-1-1 pH值對TMP去除之影響 54
4-4-1-2 污染物濃度對TMP去除之影響 55
4-4-1-3 亞鐵劑量對TMP去除之影響 57
4-4-1-4 過氧化氫劑量對TMP去除之影響 58
4-4-2 Electro-Fenton氧化程序 60
4-4-2-1 pH值對TMP去除之影響 60
4-4-2-2 污染物濃度對TMP去除之影響 62
4-5 不同程序之比較 64
4-6 降解動力分析 68
4-6-1 反應速率定律 68
4-6-2 動力式型態 68
第五章 結論與建議 71
5-1結論 71
5-2 建議 71
第六章 參考文獻 73
中文部分 73
西文部分 74
附錄 79

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