跳到主要內容

臺灣博碩士論文加值系統

(216.73.216.182) 您好!臺灣時間:2025/10/10 04:05
字體大小: 字級放大   字級縮小   預設字形  
回查詢結果 :::

詳目顯示

: 
twitterline
研究生:車同坤
研究生(外文):Tong-Kun Che
論文名稱:利用不同水質處理劑去除水中恩氟沙星與西氟沙星之研究
論文名稱(外文):Studies on Removal of Enrofloxacin and Ciprofloxacin by Using Various Agents
指導教授:冉繁華冉繁華引用關係
指導教授(外文):Dr. Fan-Hua Nan
學位類別:碩士
校院名稱:國立臺灣海洋大學
系所名稱:水產養殖學系
學門:農業科學學門
學類:漁業學類
論文種類:學術論文
論文出版年:2012
畢業學年度:100
語文別:中文
論文頁數:141
中文關鍵詞:恩氟沙星西氟沙星
外文關鍵詞:enrofloxacinEFAciprofloxacinCIP
相關次數:
  • 被引用被引用:3
  • 點閱點閱:302
  • 評分評分:
  • 下載下載:28
  • 收藏至我的研究室書目清單書目收藏:0
本論文主要探討不同種類水質處理劑(腐植酸、沸石粉、松樹精、活性碳、牡蠣殼粉)分別對水體中1 mg/L恩氟沙星(enrofloxacin, EFA)與西氟沙星(ciprofloxacin, CIP)在14天內之去除率。發現其去除能力以沸石粉最佳,然後依次為松樹精、腐植酸、活性碳及牡蠣殼粉。此外亦發現,其去除能力會隨著水質處理劑的濃度增加而增加。
以不同濃度(5、10、20、50及100 mg/L)沸石粉分別去除水體中1 mg/L、0.5 mg/L、0.1 mg/L的EFA與CIP。實驗14天後發現其去除1 mg/L EFA的去除率分別為19%、28%、42 %、80%及97%,去除1 mg/L CIP的去除率分別為80%、85%、91%、98%及99%。而針對0.5 mg/L EFA與CIP的去除率則為96%、99%、100%、100%及100%。0.1 mg/L EFA與CIP的去除率則在第2天後各處理組均達100%。這些結果顯示沸石粉可作為去除水體中EFA與CIP的吸附劑。
多次使用沸石粉去除水體中1mg/L EFA與CIP之情形,以不同濃度 (5、20及50 mg/L)每隔3天重覆添加一次,結果顯示各處理組水體中EFA與CIP之濃度會隨著採樣時間增加有下降的情形,實驗第12天後各處理組去除率皆為90%以上。在多次實驗中結果發現沸石粉去除速度比單次添加的實驗快速。

The present study focuses on the removal of Enrofloxacin (EFA) and ciprofloxacin (CIP) from freshwater by using five agents: humic acid (HA), zeolite (ZEO), pinus extract (PE), activated carbon (AC) and oyster shell powder (OSP) for 14 days. Results showed that zeolite was the best agent to remove EFA and CIP solution. The removal efficiency of agents to remove 1 mg/L EFA and CIP was: zeolite> pinus extract> humic acid> activated carbon> oyster shell powder. Besides, results showed that the removal efficiency increased when the concentration of agent increased.
Different concentrations of zeolite (5, 10, 20, 50 and 100 mg/L) was used to remove 1.0, 0.5 and 0.1 mg/L of EFA and CIP. Results showed that the removal efficiency of zeolite to remove 1 mg/L EFA solution was 19, 28, 42, 80 and 97%; 1 mg/L CIP was 80, 85, 91, 98 and 99%. As for 0.5 mg/L EFA and CIP solution, removal efficiency of zeolite was 100% after two days of treatment. This indicated that zeolite as an agent can be used to remove EFA and CIP.
In sequential treatment, zeolite at different concentrations (5, 20 and 50 mg/L) was used to remove 1 mg/L of EFA and CIP where it added in every 3 days. Results showed that EFA and CIP concentrations decreased with the sampling points and the removal efficiency was above 90% after 12 days of treatments. The removal efficiency of zeolite in sequential treatment was better than the removal efficiency in single treatment.

目錄
頁次
謝辭 i
中文摘要 iii
英文摘要 iv
目錄 v
表目錄- vi
圖目錄 x
第一章 前言 1
第二章 文獻整理 3
第三章材料方法 18
第四章結果 28
第五章討論 56
第六章結論 67
參考文獻 68
附錄 123

王渭賢,鄧晶瑩,劉正義,1993。Quinolone 類藥物在魚類細菌性疾病
治療之應用探討。台灣畜牧獸醫學會會報,62,37-46。
王德敏,2008。以液相層析串聯式質譜儀測定水產品中三苯甲烷類化
合物及其代謝物。國立中山大學海洋生物科技暨資源研究所碩士
論文。
行政院農業委員會。停止製造及輸入口服液劑及飲水散劑劑型之
Fluoroquinolones 類動物用藥品。行政院農業委員會94年5月16
日農授防字第0941472294號公告。2005。
行政院農業委員會。外銷養殖鰻魚生產管理證明核發要點。行政院農
業委員會95年7月21日農授漁字第0951340934號令。2006。
行政院農業委員會。動物用藥品使用準則。行政院農業委員會96年8月
29日農防字第0961473107 號令。2007。
行政院公報,2011。食品中動物用藥殘留量檢驗方法—多重殘留分析
(二),衛生署授食字第1001904025號令。
行政院衛生署食品藥物管理局食品化學檢驗方法確效規範(參考方法)
1001202_1.pdf http://www.fda.gov.tw/files/list/
任剛,崔福義,2006。改性天然沸石去除水中氨氮的研究。環境汙染
治理技術與設備,第7卷,第3期,第75-79 頁
李俊鎖,邱月明,王超,2002。獸藥殘留分析「諾酮類藥物殘留分析
」。上海科學技術出版社,257-300。
范 晨,2010。二氧化氯及碳酸鈣對養殖池水及底泥中Fluoroquinolone
變化之影響。國立臺灣海洋大學水產養殖學系碩士論文。
69
林壹鴻,2006。灰化牡蠣殼粉應用於截切蔬菜對其品質影響之研究。
中國文化大學生活應用科學研究所碩士論文。
林雅雯,2007。以廢棄牡蠣殼製備懸浮性重金屬吸附劑之研究。屏東
科技大學環境工程與科學系所碩士論文。
林明弘,2008。應用電灑法串聯式液質譜定量分析含heparin之人體血
漿中的procaterol。大同大學生物工程研究所碩士論文。
張菊香,2009。建立禽畜水產品中之喹諾酮類藥物分析方法及恩氟喹
諾酮羧酸在吳郭魚中藥物動力學之研究。國立中山大學海洋生物
科技暨資源學系博士論文。
許欣潔,2007。沸石吸附材料製備及其運用於水中有機污染物之去除
。嘉南藥理科技大學環境工程與科學系碩士論文。
陳立夫,楊秋忠,1993。土壤精華-腐植質。科學月刊,24,53-58。
陳姝樺,2001。以二氧化氯為前氧化劑對淨水混沉之影響探討。逢甲
大學環境工程與科學研究所碩士論文。
陳惠芬, 2003 。Na2O·Al2O3·nSiO2,CaO·Al2O3·nSiO2,xCaO·(1-x)
Na2O·Al2O3·nSiO2 及xNa2O·(1-x)K2O·Al2O3·nSiO2系統中合成沸石
之研究。國立台灣大學地質科學研究所博士論文。
陳文樟,2006。簡介活性碳製造、分類及應用。中鼎月刊,321,17-21
頁。
曾素貞,2005。台灣五葉松萃取物抑菌試驗與致突變性之評估。國立
屏東科技大學食品科學系碩士論文。
黃淑華,2000。應用高液相層析法檢測豬糞中四環素類抗生素及磺胺
劑。中興大學獸醫系碩士論文。
葉俐君,2004。Amoxicillin免疫素連結反應檢驗試劑開發及應用。國立
70
中興大學獸醫學系碩士論文。
蔡佳均,2006。不同濃度羥四環黴素對吳郭魚殘留量及非特異性免疫
之影響。國立台灣海洋大學水產養殖學系碩士論文。
劉孟欣,2002。利用酵素免疫分析及氣相層析質譜儀確認分析尿液中
氟硝西泮之主要代謝物。私立慈濟大學藥理暨毒理學系碩士論文。
劉錡樺,2010。水處理污泥轉換活性碳-沸石複合吸附材料之研究。
國立中央大學環境工程學系碩士論文。
Adams, C., Asce, M., Wang, Y., Loftin, K., Meyer, M., 2002. Removal of
antibiotics from surface and distilled water in conventional water
treatment processes. J. Environ. Eng. 128, 253-260.
Aiken, G.R., 1985. Humic Substances in Soil, Sediment and Water. John
Wiley and Sons, New York.
Ambrose, P.G., Owens, R.C., Quintiliani, R., Nightingale, C.H., 1997. New
generations of quinolones: with particular attention tolevofloxacin. J.
Conn. Med. 61, 269-272.
Andersson, M.I., MacGowan, A.P., 2003. Development of the quinolones.
J. Antimicrob. Chemother. 51, 1-11.
Andreu, V., Blasco, C., Picó, Y., 2007. Analytical strategies to determine
quinolones residues in food and the environment.Trends Anal.
Chem. 26, 534-555.
Aral F., Karacal F, Baba F., 2008. The effect of enrofloxacin on sperm
quality in male mice. Res. Vet. Sci. 84, 95-99.
Ashworth, R.B., 1985. Liquid chromatographic assay of tetracyclines in
tissues of food-producing animals. J. Assoc. Off. Anal. Chem. 68,
1013-1019.
Ball, P., 2000. Quinolone generatios: natural history or natural selection. J.
Antimicrob. Chemother. 46, 17-24.
71
Barré, J., 2001. Caractéristiques pharmacocinétiques des nouvelles
fluoroquinolones. Médicales Mal Infect. 31, 637-641.
Batt, A.L., Snow, D.D., Aga, D.S., 2006. Occurrence of sulfonamide
antimicrobials in private water wells in Washington County, Idaho,
USA. Chemosphere 64, 1963-1971.
Blondeau, J.M., Phd, M., 1999. Expanded activity and utility of new
fluoroquinolones: A Review. Cli. Ther. 21, 3-40.
Bobu, M., Yediler, A., Siminiceanu, I., Schulte-Hostede, S., 2008.
Degradation studies of ciprofloxacin on a pillared iron catalyst. Appl.
Catal. B. 83, 15-23.
Bowser, P.R., Babish, J.G., 1991. Clinical pharmacology and efficacy of
fluoroquinolones in fish. Annual. Rev. Fish Dis. 13, 63-66.
Boyd, C.E., Massaut, L., 1999. Risks associated with the use of chemicals
in pond aquaculture. Aquacult. Eng. 20, 113-132. J.
Bras, I., Ciasantos, L., Alves, A., 1999. Organochlorine pesticides removal
by pinus bark sorption. Environ. Sci. Technol. 33, 631-663.
Brown, K.D., Kulis, J., Thomson, B., Chapman, T.H., Mawhinney, D.B.,
2006. Occurrence of antibiotics in hospital, residential, and dairy
effluent, municipal wastewater, and the Rio Grande in New Mexico,
Sci. Total Environ. 366, 772-783.
Burkhardt, J., Hill , M., Carlton, W., 1990. Histologic and histochemical
changes in cartilages of immature beagle dogs dosed with difloxacin,
a fluoroquinolone. Vet. Pathol. 27, 162-170.
Capleton, A.C., Courage, C., Rumsby, P., Holmes, P., Stutt, E., Boxall,
A.B.A., Levy, L.S., 2006. Prioritising veterinary medicines
according to their potential indirect human exposure and toxicity
profile. Toxicol. 163, 213-223.
Cardoza, L.A., Knapp, C.W., Larive, C.K., Belden, J.B., Lydy, M.A.,
72
Graham, D.W., 2005. Factors affecting the fate of ciprofloxacin in
aquatic field systems. Water, Air and Soil Pollut. 161, 383-398.
Carrasquillo, A.J., Bruland, G.L., Mackay, A.A., Vasudevan, D., 2008.
Sorption of ciprofloxacin and oxytetracycline zwitterions to soils and
soil materials: influence of compound structure. Environ. Sci.
Technol. 42, 7634-7642.
Chang, P.H., Li, Z.H., Jiang, W.T., Jean, J.S., 2009a. Adsorption and
intercalation of tetracycline by swelling clay minerals. Appl. Clay
Sci. 46, 27-36.
Choi, K.J., Kim, S.G., Kim, S.H., 2008. Removal of antibiotics by
coagulation and granular activated carbon filtration. J. Hazard. Mater.
151, 38-43.
Cinquina, A.L., Roberti, P., Giannetti, L., Longo, F., Draisci, R., Fagiolo,
A., Brizioli, N.R., 2003. Determination of enrofloxacin and its
metabolite ciprofloxacin in goat milk by high-performance liquid
chromatography with diode-array detection Optimization and
validation. J. Chromatogr. 987, 221-226.
Debska, J., Kot-Wasik, A., Namiesnik, J., 2004. Fate and analysis of
pharmaceutical residues in the aquatic environment. Crit. Rev. Anal.
Chem. 34, 51-67.
De Witte, B., Dewulf, J., Demeestere, K., Van Langenhove, H., 2009.
Ozonation and advanced oxidation by the peroxone process of
ciprofloxacin in water. J. Hazard. Mater. 161, 701-708.
Fradinho, D.M., Pascoal Neto, C., Evtuguin, D., Jorge, F.C., Irle, M.A.,
Gil, M.H., P., de Jesus, J., 2002. Chemical characterization of bark
and of alkaline bark extracts from maritime pine grown in Portugal.
Ind. Crops Prod. 16, 23-32.
Fink, L., Dror, I., Berkowitz, B., 2012. Enrofloxacin oxidative degradation
73
facilitated by metal oxide nanoparticles. Chemosphere. 86, 144-149.
Garcia de Mateos-Verchere, J., Vaugeois, J.M., Naudin, B., Costentin, J.,
1998. Behavioural and neurochemical evidence that the
antimicrobial agent oxolinic acid is a dopamine uptake inhibitor.
Euro. Neuro. Chopharmacol. 8, 255-259.
Gellert, M., Sukoneck, S.C., Bello, A., Ge, Z., Grasela, D.M., 1997.
Nalidixic acid resistance a second genetic character involved in DNA
gyrase activity. P. Natl. Acad. Sci. USA. 74, 4772-4778.
Glynn, A.W., 1995. Fulvic and humic acids decrease the absorption of
cadmium in the rat intestine. Arch. Toxicol. 70, 28-33.
Göbel, A., McArdell, C.S., Joss, A., Siegrist, H., Giger, W., 2007. Fate of
sulfonamides, macrolides, and trimethoprim in different wastewater
treatment technologies. Sci. Total Environ. 372, 361-371.
Gonzalez, C., Moreno, L., Small, J., Jones, DG., Bruni Sergio, F.S., 2006.
A liquid chromatographic method, with fluorometric detection, for
the determination of enrofloxacin and ciprofloxacin in plasma and
endometrial tissue of mares. Anal. Chem. Acta. 560, 227-234.
Golet, E.M., Alder, A.C., Hartmann, A., Ternes, T.A., Giger, W., 2001.
Trace determination of fluoroquinolone antibacterial agents in
solid-phase extraction urban wastewater by and liquid
chromatography with fluorescence detection. Anal. Chem. 73,
3632-3638.
Golet, E.M., Alder, A.C., Giger, W., 2002. Environmental exposure and
risk assessment of fluoroquinolone antibacterial agents in wastewater
and river water of the Glatt Valley Watershed Switzerland. Environ.
Sci. Technol. 36, 3645-3651.
Gore, S.R., Harms, C.A., Kuanich, B., Forsythe, J., Papich., M.G., 2005.
Enrofloxacin pharmacokinetics in the European cuttlefish, Sepia
74
officinalis, after a single i.v. injection and bath administration. J. Vet.
Pharmacol. Ther. 28, 433-439.
Gorla, N., Chiostri, E., Ugnia, L., Weyers, A., Giacomelli, N., Davicino, R.,
Garcia, OH., 1997. HPLC residues of enrofloxacin and ciprofloxacin
in eggs of laying hens. Int. J. Antimicrob. Agents 8, 253-256.
Gu, B., Schmitt, J., Chen, Z., Liang, L., McCarthy, J.F., 1994. Adsoprtion
and desorption of natural organic matter on iron oxide: mechanisms
and models. Environ. Sci. Technol. 28, 38-46.
Guinea, E., Garrido, J.A., Rodríguez, R.M., Cabot, P.-L., Arias, C.,
Centellas, F., Brillas, E., 2010. Degradation of the fluoroquinolone
enrofloxacin by electrochemical advanced oxidation processes based
on hydrogen peroxide electrogeneration. Electrochim. 55,
2101-2115.
Guo, L., Xie, Z., Lin., X., Y., Z., 2005. Pharmacokinetics of ciprofloxacin
in eels by high-performance liquid chromatography with
fluorescence detection. Anal. Biochem. 341, 275-279.
Halling-Sørenson, B., Nielsen, N., Lansky, P.F., Ingerslev, F., Lutzhoft,
J.H.C., Jorgensen, S.E., 1998. Occurrence, fate and effects of
pharmaceutical substances in the environment- A review.
Chemosphere. 36, 357-393.
Hartmann, A., Golet, E.M., Gartiser, S., Alder, A.C., Koller, T., Widmer,
R.M., 1999. Primary DNA damage but not mutagenicity correlates
with ciprofloxacin concentrations in German hospital wastewaters.
Arch. Environ. Contam. Toxicol. 36, 115-119.
Hektoen, H., Berge, J.A., Hormazabal, V., Yndestad, M., 1995. Persistence
of antibacterial agents in marine sediments. Aquaculture 133,
175-184.
Homem, V., Santos, L., 2011. Degradation and removal methods of
75
antibiotics from aqueous matrices -A review. J. Environ. Manage. 92,
2304-2347.
Hooper, D.C., Wolfson, J.S., 1993b. Adverse Effect. In: D. C. Hooper and
J. S. Wolfson ( Editors ) . Quinolone Antimicrobial Agents.
American Society for Microbiology, Washington, DC, USA
489-512.
Hooper, D.C., Wolfson, J.S., 1996. Quinolone Antimicrobial Agents.
Adverse effects. American Society for Microbiology, Washington,
DC, USA, 549.
Hooper, D.C., 1999b. Mechanisms of fluoroquinolone resistance. Drug
Resist Updat. 2, 38-55.
Hori, S.C., Shimada, J., 1993. Effects of quinolone on the central nervous
system. In: D. C. Hooper and J. S. Wolfson ( Editors ), Quinolone
Antimicrobial Agents. American Society for Microbiology,
Washington, DC, USA, 513-518.
Hsu, T.C., 2009. Experimental assessment of adsorption of Cu2+ and Ni2+
from aqueous solution by oyster shell powder. J. Hazard. Mater. 171,
995-1000.
Huang, T.S., Lu, F.J., 1991. Iodide binding by humic acid. Environ.
Toxicol. Chem. 10, 179-184.
Intorre, L., Cecchini, S., Bertini, S., 2000. Pharmacokinetics of
enrofloxacin in the seabass (Dicentrarchus labrax). Aquaculture
182, 49-59.
Ito, A., Hiral, K., Inoue, M., Hiroshi, K., Suzue, S., Irikura, T., Mitsuhashi,
S.S., 1980. In Vitro Antibacterial Activity of AM-715, a New
Nalidixic acid analong. J. Antimicrob. Agents Chemother.
17,103-108.
76
Jaroslaw, W., Didier, R., Joanna, S., Korneliusz, M., Sixto, M., Jean, V.,
Didier, G., Surmacz, J., 2004. Solar phtocatalytic degradation of
humic acids as a model of organic compounds of landfill leachate in
pilot-plant experiments : influence of inorganic salts. Environ.
53,127-137.
Kümmerer, K., 2003. Significance of antibiotics in the environment. J.
Antimicrob. Chemother. 52, 5-7.
Kato, M., Onodera, T., 1988. Morphological investigation of cavity
formation in articular cartilage induced by ofloxacin in rats. Fund
Appl. Toxicol. 11, 110-119.
Kemper, N., 2008. Veterinary antibiotics in the aquatic and terrestrial
environment. Ecol. Indic. 8, 1-13.
Kim, S.R., Nonaka, L., Suzuki, S., 2004. Occurrence of tetracycline
resistance genes tet(M) and tet(S) in bacteria from marine
aquaculture sites. FEMS. Microbiol. Letter. 237, 147-156.
Kim. M.S., Lim, J.H., Park, B.K., Hwang, Y.H., Yun, H.J., 2006.
Pharmacokinetic of enrofloxacin in Korean catfish (Silurus asotus
). J. Vet. Pharmacol. Ther. 29, 397-402.
Kim, S.H., Shon, H.K., Ngo, H.H., 2010. Adsorption characteristics of
antibiotics trimethoprim on powered and granular activated carbon. J.
Ind. Eng. Chem. 16, 344-349.
Kolpin, D.W., Furlong, E.T., Meyer, M.T., Thurman, E.M., Zaugg, S.D.,
Barber, L.B., Buxton, H.T., 2002. Pharmaceuticals, hormones, and
other organic wastewater contaminants in US streams, 1999-2000. A
national reconnaissance. Environ. Sci. Technol. 36, 1202-1211.
Korsrud, G.O., Papich, M.G., Fesser, A.C.E., Salisbury, C.D.C., Macneil,
J.D., 1995. Laboratry testing of the Cham Π Test receptor assays and
77
Cham Farm Test with tissues and fluids from hogs fed sulfamethazine,
chlortetracycline, and penicillin G. J. Food Protection. 59, 161-166.
Korsrud, G.O., Boison, J.O., 1998. Bacterial inhibition tests used to screen
for antimicrobial veterinary drug residues in slaughtered animals. J.
Assoc. Off. Anal. Chem. 81, 21-24.
Krol, G.J., Beck, G.W., Benham, T., 1995. HPLC analysis of ciprofloxacin
and ciprofloxacin metabolites in body fluids. J. Pharm. Biomed.
Anal.14, 181-190.
Kulshrestha, P., Giese, R.F., Aga, D.S., 2004. Investigating the molecular
interactions of oxytetracycline in clay and organic matter: insights on
factors affecting its mobility in soil. Environ. Sci. Technol. 38,
4097-4105.
Lützhøft, H.-C.H., Halling-Sørensen, B., JørgensenDOI, S.E., 1999. Algal
toxicity of antibacterial agents applied in danish fish farming. Arch.
Environ. Con. Toxicol. 36, 1-6.
Lesher, G.Y., Forelich, E.D., Gruet, M.D., Bailey, J.H., Brumdage, R.P.,
1962. A new class of chemotherapeutic agents. J. Med. Pharml
Chem. 5, 1063-1068.
Lewbart, G., Vaden, S., Deen, J., Flammer, K., 1997. Pharmacokinetics of
enrofloxacin in the red pacu (Colossoma brachypomum) after
intramuscular, oral and bath adminstration. J. Vet. Pharmacol. Ther.
20, 124-128.
Li, Z., Chang, P.H., Jean, J.S., Jiang, W.T., Wang, C.J., 2010. Interaction
between tetracycline and smectite in aqueous solution. J. Colloid
Interface. Sci. 341, 311-319.
Livens, R.F., 1991. Chemical reactions of metals with humic material.
Environ. Pollut. 70, 183-208.
Lucchett, D., Fabrizi, L., Guandalini, E., Podesta, E., Marvasi, L., Zaghini,
78
A., Coni, E., 2007. Long depletion time of enrofloxacin in Rainbow
Trout (Oncorhynchus mykis). Antimicrob. Agents Chemother. 48,
3912-3917.
Martínez-Carballo, E., Gans, O., Gonza´lez-Barreiro, C., Scharf, S., 2007.
Environmental monitoring study of selected veterinary antibiotics in
animal manure and soils in Austria. Environ. Pollut. 148, 570-579.
Martinsen, B., Horsberg, T.E., 1995. Comparative single-dose
pharmacokinetics of four quinolones, oxolinic acid,
flumequine,sarafloxacin, and enrofloxacin, in Atlantic Salmon (
Salmo salar ) held in seawater at 10 ℃ . Antimicrob. Agents
Chemother. 39, 1059-1064.
Motsi, T., Rowson, N.A., Simmons, M.J.H., 2009. Adsorption of heavy
metals from acid mine drainage by natural zeolite. Int. J. Miner.
Process. 92, 42-48.
Norris, S., Mandell, G.L., 1988. In the Quinolones: history and overview.
in Andriole V.T. ed. The Quinolones Academic Press Inc. Sa Diego
USA, 1-22.
Nowara, A., Burhenne, J.a., Spiteller, M., 1997. Binding of
fluoroquinolone carboxylic acid derivatives to clay minerals. J.
Agric. Food Chem. 45, 1459-1463.
Oliphant, C.M., Green, GM., 2002. Quinolones: A Comprehensive Review
Ame. Fam. Physician. 65,455-465.
Ö tker, H.M., Akmehmet-Balcio glu, I., 2005. Adsorption and degradation
of enrofloxacin, a veterinary antibiotic on natural zeolite. J. Hazard.
Mater. 122, 251-258.
Pan, S.C., Lin, C.C., Tseng, D.H., 2003. Reusing sewage sludge ash as
adsorbent for copper removal from wastewater, Resour. Conserv.
79
Recy. 39, 79–90.
Parshikov, I.A., Freeman, J.P., Jackson, O.L.J., Beger, R.D., Williams,
A.J., Sutherland, J.B., 1999. Regioselective transformation of
ciprofloxacin to N-acetylciprofloxacin by the fungus Mucor
ramannianus. FEMS. Microbol. Lett. 177, 131-135.
Pascual-Reguera, M.I., Parras, G.P., Diaz, A.M., 2004. Solid-phase UV
spectrophotometric method for determination of ciprofloxacin. J.
Microchem .77, 79-84.
Pico, Y., Andreu, V., 2007. Fluoroquinolones in soil--risks and challenges.
Anal. Bioanal. Chem. 387, 1287-1299.
Raji, C., Anirudhan, T.S., 1996. Removal of Hg (II) from aqueous
solution by sorption on polymerized saw dust. Indian. J. Chem.
Technol. 3, 49-54.
Rao, M.M., Reddy, D.H.K.K., Venkateswarlu, P., Seshaiah, K., 2009a.
Removal of mercury from aqueous solutions using activated carbon
prepared from agricultural by-product/waste. J. Environ. Manage.
90, 634-643.
Rao, R. A. K., Kashifuddin, M., 2012. Adsorption studies of Cd (II) on
ball clay: Comparison with other natural clays. Ara. J. Chem.
Original Article. Doi:10.1016/j.arabjc. 2012. 01. 010.
Ratola, N., Botelho, C., Alves, A., 2003. The use of pine bark as a natural
adsorbent for persistent organic pollutants-study of lindane and
heptachlor adsorption. J. Chem. Technol. Biotechnol. 78, 347-351.
Renew, J.E., Huang, C.H., 2004a. Simultaneous determination of
fluoroquinolone, sulfonamide, and trimethoprim antibiotics in
wastewater using tandem solid phase extraction and liquid
chromatography-electrospray mass spectrometry. J. Chromatogr.
80
1042, 113-121.
Riely, C.M., 1996. High-performance liquid chromatography: modes of
chromatography. Lough, WJ, Wainer IW. 1st ed. Chapman & Hall
New York, USA.
Rigos, G., Nengas, I., and, A.M., Troisi G.M., 2004. Potential drug (
oxytetracycline and oxolinic acid)pollution from Mediterranean
sparid fish farms. Aquatic. Toxicol. 69 , 281-288.
Robinson, I., Junqua, G., Coillie, R.V., Thomas, O., 2007. Trends in the
detection of pharmaceutical products, and their impact and
mitigation in water and wastewater in North America. Anal. Bio
Chem. 387, 1143-1151.
Rocca, G.D., Salvo, A.D., Malvisi, J., 2004. The disposition of
enrofloxacin in seabream ( Sparus aurata L. ) after single
itravenous injection or from medicated feed administration.
Aquaclture 232, 53-62.
Rooklidge, S.J., 2004. Environmental antimicrobial contamination from
terraccumulation and diffuse pollution pathways. Sci. Environ. 325,
1-13.
Putra, E.K., Pranowo, R., Sunarso, J., Indraswati, N., Ismadji, S., 2009.
Performance of activated carbon and bentonite for adsorption of
amoxicillin from wastewater: mechanism, isotherms and kinetics.
Water Res. 43, 2419-2430.
Saad, B., Mohamad, R., Mohamed, N., Jab, M.S., Saleh, M.I., Lawrence,
G.D., 2002. Determination of oxolinic acid in feeds and cultured fish
using capillary electrophoresis. J. Food Chem. 78, 383-388.
Samuelsen, O.B., 2006. Pharmacokinetics of quinolones in fish: A review.
Aquaculture 255, 55-75.
81
Sarmah, A.K., Meyer, M.T., Boxall, A.B.A., 2006. A global perspective on
the use, sales, exposure pathways, occurrence, fate and effects of
veterinary antibiotics (VAs) in the environment. Chemosphere. 65,
725-759.
Sawai, J., Shiga, H., Kojima, H., 2001. Kintic analysis of the bactericidal
action of heated scallop-shell powder. J. Food Microbio.71, 211-218.
Savarino, P., Montoneri, E., Musso, G., Boffa,V., 2010. Biosurfactants from
urban wastes for detergent formulation : surface activity and washing
performance. J. Surfact. Deterg. 13.
Seabra, I.J., Dias, A.M.A., Braga, M.E.M., de Sousa, H.C., 2012. High
pressure solvent extraction of maritime pine bark: Study of
fractionation, solvent flow rate and solvent composition. J. Supercrit.
Fluid. 62, 135-148.
Steelink, C., 1963. What is humic acid? . J. Chem. Educat. 40, 379-384.
Stehly, G.U., Gingerich, W.H., 1999. A bridging study for tetracycline in
edible fillet of rainbow trout: analysis by a liquid chromatographic
method and the official microbial inhibition assay. J. Assoc. Off. Anal.
Chem. 82, 886-870.
Stevenson, F. J., 1985. Humus chemistry. John Wiley & Sons, New York.
Tang, J., Yang, X.L., Zheng, Z.L., Yu, W.J., Hu, K., Yu, H.J., 2006.
Pharmacokinetics and the active metabolite of enrofloxacin in Chinese
mitten-handed crab (Eriocheir sinensis). Aquaculture 260, 69-76.
Tangkawanit, S., Rangsriwatananon, K., Dyer, A., 2005. Ion exchange of
Cu2+,Ni2+,Pb2+ and Zn2+ in analcime(ANA) synthesized from Thai
perlite. Micropor. Mesopor. Mat. 79, 171-175.
Taylor and Francis Group, 2005. Activated carbon adsorption. Roop Chand
Bansal Meenakshi Goyal. www.chemical.mem.ir.
82
Thabaj, K.A., Kulkarni, S.D., Chimatadar, S.A., Nandibewoor, S.T. 2007
Oxidative transformation of ciprofloxacin by alkaline permanganate –
A kinetic and mechanistic study. Polyhedron. 26, 17, 4877-4885.
Thanabalasingam, P., Pickering, W.F., 1986. Arsenic sorption by humic
acids. Environ. Pollut. 12, 233-246.
Toil, J., 2001. Sorption of Veterinary Pharmaceuticals in Soils-review.
Environ.Toxicol. Chem. 35, 3397.
Turiel, E., Martin-Esteban, A., Bordin, G., Rodriguez, A.R., 2004. Stability
of fluoroquinolone antibiotics in river water samples and in octadecyl
silica solid-phase extraction cartridges. Anal. Bio. Chem. 380,
123-128.
Uslu, M.Ö., Yediler, A., Balcıoğlu, I.A., Schulte-Hostede, S., 2007.
Analysis and Sorption Behavior of Fluoroquinolones in Solid
Matrices. Water. Air. Soil. Poll. 190, 55-63.
Vasconcelos, T.G., Henriques, D.M., Konig, A., Martins, A.F., Kummerer,
K., 2009. Photo-degradation of the antimicrobial ciprofloxacin at high
pH: identification and biodegradability assessment of the primary
by-products. Chemosphere. 76, 487-493.
Vazquez, G., Antorrena, G., Gonzfilez, J., Doval, M.D., 1994. Adsorption
of heavy metal ion by chemically modified pinus pinaster bark. Biore.
Technol. 48, 251-255.
Vieno, N.M., Hrkki, H., Tuhkanen, T., Kronberg, L., 2007. Occurrence of
pharmaceuticals in river water and their elimination in a pilot-scale
drinking water treatment plant. Environ. Sci. Technol. 41, 5077-5084.
Wang, W.S., Shih, C.W., Hung, S.W., Ling, Y.F., Tu, C.Y., Chen, B.R.,
Tsou, L.T., Ho, S.P., 2006. Development and application of the
enzyme-linked immunosorbent assay residual detection kits for
fluoroquinolones. Taiwan Vet. J. 32. 391-403.
83
Wang, C.J., Li, Z., Jiang, W.T., Jean, J.S., Liu, C.C., 2010. Cation exchange
interaction between antibiotic ciprofloxacin and montmorillonite. J.
Hazard Mater. 183, 309-314.
Wu, G., Meng, Y., Zhu, X., Huang, C., 2006. Pharmacokinetics and tissue
distribution of enrofloxacin and its metabolite ciprofloxacin in the
Chinese mitten-handed crab ( Eriocheir sinensis ) . Anal. Biochem.
358, 25-30.
Wu, Q., Li, Z., Hong, H., Yin, K., Tie, L., 2010. Adsorption and
intercalation of ciprofloxacin on montmorillonite. Appl. Clay. Sci. 50,
204-211.
Xu, W., Zhu, X., Wang, X., Deng, L., Zhang, G., 2006. Residues of
enrofloxacin, furazolidone and their metabolites in Nile tilapia (
Oreochromis niloticus).Aquaculture 254, 1-8.
Yoon, G. L., Kim, B. T., Kim, B. O. and Han, S. H., 2003. Chemical –
mechanical characteristics of crushed oyster-shell. Waste Manage.
23, 825-834.
Zechiedrich, E.L., Cozzarelli, N.R., 1995. Roles of topoisermase Ⅳ and
DNA gyrase in DNA unlinking during replication in Escheri coli.
Genes. Dev. 9, 2859-2828.
Zhang, F.S., Nriagu, J.O., Itoh, H., 2005. Mercury removal from water
using activated carbons derived from organic sewage sludge. Water
Res. 39, 389–395.
連結至畢業學校之論文網頁點我開啟連結
註: 此連結為研究生畢業學校所提供,不一定有電子全文可供下載,若連結有誤,請點選上方之〝勘誤回報〞功能,我們會盡快修正,謝謝!
QRCODE
 
 
 
 
 
                                                                                                                                                                                                                                                                                                                                                                                                               
第一頁 上一頁 下一頁 最後一頁 top