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研究生:賴建豪
研究生(外文):Chan-Hao Li
論文名稱:翼莖粉藤莖部之成分研究
論文名稱(外文):The Constituents of the Stem of Cissus pteroclada Hayata.
指導教授:詹于誼
指導教授(外文):Yu-Yi Chan
學位類別:碩士
校院名稱:南台科技大學
系所名稱:生物科技系
學門:生命科學學門
學類:生物科技學類
論文種類:學術論文
論文出版年:2009
畢業學年度:97
語文別:中文
論文頁數:91
中文關鍵詞:翼莖粉藤葡萄科化學成分
外文關鍵詞:Cissus pteroclada HayataVitaceae
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由新鮮之翼莖粉藤莖部分離共得到51個化合物,其中41個化合物,經由光譜分析與文獻比對,證實其結構分別為:β-sitostenone及stigmasta-4,22-dien-3-one之混合物、β-sitosterol及stigmasterol之混合物、6α-hydroxy-β-sitostenone、6β-hydroxy-β-sitostenone、palmitoyl glucosyl sitosterol及palmitoyl glucosyl stigmasterol之混合物、oleanolic acid及ursolic acid之混合物、23-hydroxyursolic acid及hederagenin之混合物、taraxerone、taraxerol、11α,12α-epoxy-14-taraxeren-3-one、betulinic acid、lupenone、phytal及dihydrophytal之混合物、methyl vanillate、p-hydroxybenzoic acid、p-hydroxybenzaldehyde、methyl-4-hydroxybenzoate、4-hydroxy-3-methoxyacetophenone、vanillin、ω-hydroxypropioguaiacone、methyl gallate、syringaresinol、4-ketopinoresinol、methyl pheophorbide-a、methyl pheophorbide-b、methyl-21-hydroxy-(21S)-pheophorbide-a及methyl-21-hydroxy-(21R)-pheophorbide-a之混合物、methyl-21-hydroxy-(21S)-pheophorbide-b及methyl-21-hydroxy-(21R)-pheophorbide-b之混合物、3,3’-di-O-methylellagic acid、3,3’,4-tri-O-methylellagic acid、3,3’,4,4’-tetra-O-methylellagic acid、ellagic acid、bergenin、methyl ester fatty acid。
Fifty-one compounds were isolated from the fresh stem of Cissus pteroclada Hayata. Among these isolates, forty-one compounds were elucidated as β-sitostenone and stigmasta-4,22-dien-3-one mixtures, β-sitosterol and stigmasterol mixtures, 6α-hydroxy-β-sitostenone, 6β-hydroxy-β-sitostenone, palmitoyl glucosyl sitosterol and palmitoyl glucosyl stigmasterol mixtures, oleanolic acid and ursolic acid mixtures, 23-hydroxyursolic acid and hederagenin mixtures, taraxerone, taraxerol, 11α,12α-epoxy-14-taraxeren-3-one, betulinic acid, lupenone, phytal and dihydrophytal mixtures, methyl vanillate, p-hydroxybenzoic acid, p-hydroxybenzaldehyde, methyl-4-hydroxybenzoate, 4-hydroxy-3-methoxyacetophenone, vanillin, ω-hydroxypropioguaiacone, methyl gallate, syringaresinol, 4-ketopinoresinol, methyl pheophorbide-a, methyl pheophorbide-b, methyl-21-hydroxy-(21S)-pheophorbide-a and methyl-21-hydroxy-(21R)-pheophorbide-a mixtures, methyl-21-hydroxy-(21S)-pheophorbide-b and methyl-21-hydroxy-(21R)-pheophorbide-b mixtures, 3,3’-di-O-methylellagic acid, 3,3’,4-tri-O-methylellagic acid, 3,3’,4,4’-tetra-O-methylellagic acid, ellagic acid, bergenin and methyl ester fatty acid.
目 錄

Abstract-----------------------------------------------------------------------------------------------------------------------------iv
中文摘要----------------------------------------------------------------------------------------------------------------------------v
謝誌---------------------------------------------------------------------------------------------------------------------------------vi
目錄--------------------------------------------------------------------------------------------------------------------------------vii
第一章 緒論----------------------------------------------------------------------------------------------------------------- 1
第一節 緒言----------------------------------------------------------------------------------------------------------- 1
第二節 翼莖粉藤之型態-------------------------------------------------------------------------------------------- 2
第二章 粉藤屬植物之研究概況----------------------------------------------------------------------------------------- 4
第一節 粉藤屬植物之成分研究回顧----------------------------------------------------------------------------- 4
第二節 粉藤屬植物生物活性之研究概況----------------------------------------------------------------------15
第三章 抽取與分離-------------------------------------------------------------------------------------------------------21
第四章 構造研究----------------------------------------------------------------------------------------------------------30
第一節 bergenin(2)構造研究--------------------------------------------------------------------------------------30
第二節 ursolic acid (41)構造研究--------------------------------------------------------------------------------34
第三節 6β-hydroxy-β-sitostenone (68)構造研究------------------------------------------------------------37
第四節 taraxerone (72)構造研究----------------------------------------------------------------------------------40
第五節 betulinic acid (75)構造研究------------------------------------------------------------------------------43
第六節 ω-hydroxypropioguaiacone (85)構造研究------------------------------------------------------------46
第七節 syringaresinol (87)構造研究-----------------------------------------------------------------------------49
第八節 methyl pheophorhide-a (89)構造研究------------------------------------------------------------------52
第九節 3,3’,4-tri-O-methylellagic acid (96)構造研究---------------------------------------------------------55
第十節 ellagic acid (98)構造研究---------------------------------------------------------------------------------58
第十一節 其它已知化合物之構造研究-------------------------------------------------------------------------61
第五章 結論----------------------------------------------------------------------------------------------------------------62
第六章 實驗部份----------------------------------------------------------------------------------------------------------63
第一節 本實驗所用之儀器與藥品----------------------------------------------------------------------------63
第二節 植物之採集與鑑定 ---------------------------------------------------------------------------------------64
第三節 翼莖粉藤莖部成分之萃取與分離 ---------------------------------------------------------------------64
第四節 光譜數據整理-------------------------------------------------------------------------------------------67
參考文獻-----------------------------------------------------------------------------------------------------------------80
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