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本論文提出下列四種新的非晶質光偵測器元件的構造、製作與特性: (1)非晶矽穿透累崩光二極體。 (2)非晶矽/碳化矽穿透累崩光二極體。 (3)非晶矽/碳化矽異質接面光電晶體。 (4)辨別色光的非晶矽光電晶體。 在5 微瓦氦氖雷射入射光功率及14.5伏特的反向偏壓下,電子入射式非晶矽穿透累崩 光二極體光增益可達380 。在倍乘值為33.46 時,其過雜訊因子為6.47。在1.8 仟歐 姆的負載電阻下,其動態交換上升時間為1 微秒。電洞與電子撞擊游離率(β與α) ,在電場E由5*105 至3.5*106 伏特/厘米的範圍內,可闊別表示成β (E)=9.87*10(四次方)EXP(-1.36*10(六次方)/E)每厘米及α(E)=6.34*10(五次方) exp(-3.16 * 10(五次方)/E) 每厘米。由本研究的結果,可知非晶矽穿透累崩光 二極體可以作為光感測器。 典型的電子入射式非晶矽/碳化矽超晶格穿透累崩光二極體,由於累崩區中有超晶格 可改良特性,當電場為3.33*10(六次方) 伏特/厘米時,其電子與電洞撞擊游離率的 比值(α/β)可達10.2,此比值是利用光電沆倍乘測量法獲得,而且也利用過雜訊 因子測量法檢查是否正確。在5 微瓦氦氖雷射入射光功率及18伏特的反向偏壓下,其 光增益高達506 。在負載電阻為1 仟歐姆時,其上升時間為1 微秒。在倍乘值為48時 ,過雜訊因子為6.53。這些結果均比從前提出的非晶質光偵測器的性能更好。 為改良同質接面非晶矽光電晶體的特性,本論文提出另一種非晶矽/碳化矽異質接面 光電晶體。其結構為玻璃/ ITO/非晶矽(n+-i-δp)+/非晶碳化矽(i-n+)/ 鋁,其中薄 的δp+非晶矽層能隙較窄,當作基極用,而與非晶碳化矽射極形成異質接面。此異質 接面元件的最佳光增益為40,反應速度為10微秒,比以前提出的同質接面元件的性質 改善很多。此種特性改善的原因也加以說明。 最後提出一種能辨別色光的非晶矽光電晶體,其結構為鋁/ n+-i-p+-i-n-i-p-i-n+/ITD玻璃。其頻譜響應的最小的。在可見光範圍內,其頻譜響 應峰值波長在4000埃至5400埃的範圍可利用所加的偏壓調整。元件的電流─電壓特性 與理論上的考慮大致符合。其最高光增益值是10。 //////// In this thesis, the structures, fabrications and characteristics of four novel amorphous photodetectors, i.e. a-Si; H reach-through avalanche photodiode (RAPD), a-Si:H/Sic::H superlattice RAPD (SRAPD), a-Si:H/SiC:H heterojunction phototransistor (HPT), and color-sensitive a-Si:H phototransistor (PT) are presented. For the electron-injection A-Si:H RAPD, an optical gain of 380 can be obtained under 5 μW He-Ne laser input light power and at a reverse-bias voltage of 14.5V. The excess noise factor is 6.47 at a multiplication of 33.46. The dynamic rise time of 1μs 0has been observed under a 1.8 kΩ load resistance. The hole and electron impact ionization rates (β and α) can be expressed empirically by β (E)=9.87*104EXP(-1.36*106/E)cm-1 and α (E)=6.34*105*exp(-3.16*105/E)cm-1 for electric field E ranging from 5-105 to 3.5*106V/cm respectively. Based on the results of this study, the a-Si:H rapd would be a promising a-Si:H device for the photosensing application. As for a typical electron-injection a-Si:H/SiCH SRAPD, due to the performance enhancement by superlattice in avalanche region, the ratio of room-temperature electron and hole impact ionization rates (α/β) is 10.2 at an electric field of 3.33*106V/cm as determined by the photocurrent multiplication measurement and checked by the excess noise factor method, the optical gain is 506 at an applied reverse-bias VR = 18 V and an incident power Pin= 5μW emitted from a He-Ne laser, the rise time is 1μ s at a load resistance RL=1kΩ, and the excess noise factor is 6.53 at a ultiplication M=48. These results are better than those of the other amorphous photodetectors ever reported. In order to improve the performance of the a-Si:H homojunction phototransistor, an alternative a-Si:H/SiC:H heterojunction phototransistor is proposed. The structure is glass/ITC/a-Si:H (n+-iδ p+)/a-SiC:H(i-n+)/Al, in which the thin δp+ a-Si:H layer of smaller band-gap is embedded as the base which forms the heterojunction with the a-Si:H emitter. This heterojuction device reveals a significant improvement over the previously reported homojunction ones, with an optimal optical gain of 40 and a response time of 10μs. The physical phenomenon which causes this performance improvement is described qualitatively also. Finally, a color-sensitive a-Si:H phototransistor with the structure of Al/n+-i-p+-i-n-i-o-i-n+/ITO/glass has been fabricated successfully. Its spectral response reveals a minimum FWHM (Full Width Half Maximum) of 600 A° which is the smallest width ever reported for amorphous phototransistors. The peak spectral response in visible range can be shifted from 4000 A°to 5400 A°by applied bias. The experimental I-V characteristics is fitted by the theoretical consideration qualitatively. A maximum optical gain of 10 is obtainable.
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