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研究生:朱志光
研究生(外文):JU, CHIH-guang
論文名稱:海水對混凝土影響之研究
論文名稱(外文):Concrete Under The Effects Of Seawater
指導教授:王櫻茂
指導教授(外文):Wang Ying Mou
學位類別:碩士
校院名稱:國立成功大學
系所名稱:土木工程研究所
學門:工程學門
學類:土木工程學類
論文種類:學術論文
論文出版年:1997
畢業學年度:85
語文別:中文
論文頁數:1
中文關鍵詞:強度酸鹼值擴散係數
外文關鍵詞:strengthpHdiffusion
相關次數:
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海水對混凝土的影響,其海水中之水會沖蝕混凝土使之氫氧化鈣流失及產
生碳酸鈣等使pH值降低,孔隙比增加,而氯離子滲透對混凝土結構而言,
除了侵蝕混凝土外,亦會導致鋼筋腐蝕速率增加,而這些因素促使混凝土
結構強度降低、混凝土之耐久性降低,並縮減壽命,增加維修費用,也間
接浪費地球資源及增加環境污染。因此本研究的目的,即在對高雄港八十
一號碼頭水域內以不同水泥及配比下,在其潮汐帶,海水面下,海岸上實
地放置混凝土試體用以觀察此等條件下海水對混凝土可能的影響,並嘗試
用直接測得之平均氯含量以利用Fick公式原理以程式來反推求氯的擴散係
數,以此方法嘗試推估港內之海水環境下混凝土或鋼筋混凝土可能受到海
水中氯之滲入量並討論其與時間、水灰比、孔隙比等與之關係,期望建立
一些參考數據,可作為港灣工程設計施工維護及研究參考資料,這些試驗
結果顯示,混凝土強度在高水灰比時其早期強度有提高傾向,但無助於後
期強度增加,而低水灰比部份在第180天抗壓強度試驗值顯示出在海水面
下放置之試體其抗壓強度約為試驗室養護池中試體強度0.9倍。氯離子之
擴散係數值隨材齡等有所變動在初期幾天稍高而後隨材齡增加而降,但低
水灰比試體之擴散係數在180天有增大的傾向,顯示出擴散係數並非固定
值,與時間、結構位置、材料、環境等有關係。氯含量隨水灰比之遞減而
減也隨孔隙比增加而增,亦隨pH值之降而增,在海面下浸泡之試體所測值
顯示第二型水泥之試體含氯量多一些而潮位帶則以第一型水泥之試體氯含
量較多。經由pH值之量測得知海水會使得混凝土pH值隨時間增加而降低,
這些均顯示出海水會侵入混凝土而產生許多的交互性物理、化學反應,並
直接或間接獲影響混凝土耐久性,然而對這些現象若需以更精確的定量方
式加以描述說明,則再需更多的實驗數據以及配合長期觀察方能使這些數
據資料更趨合理完善。
Concrete Under The Effects Of SeawaterConcrete under the effects
of seawater has many items , one of them is sodium hydroxide
dissolved by water in the seawater , it would reduce the value
of pH , increasing void ratio and permeation ,result in
increasing reinforce bar corrosion velocity , those factors
cause to reduce the strength, durability , lifecycle of concrete
structure, and increase additional maintenance cost ,finally due
to waste earth resources and more pollution. For the purpose to
understand the concrete in the marine conditions under the
seawater what will be affected ,and try to observe concrete what
will occur under those conditions of circumstances ,so using
cylinders which made from different types of cement and w/c
ratio to put it on seashore , seabed , between high and low
tide, and in the laboratory, those are in the Port of Kaohsiung
(Nos.81). Applying Fick''s Second Low of Diffusion converted to
programs to find the diffusion factors with the known content of
chlorine, then use the found diffusion factors to estimate the
among of chlorine by different values of time, depth from
concrete surface, and discuss the relations between the time, w/
c ,pores and so on ,expect to construct some referent data which
could be used in marine engineering for designing ,construction,
maintain, and research.It is showed cylinders of concrete at
high w/c in the early date could get more higher strength but
doesn''t increase the final compress strength after 180th day ,
cylinders of concrete at lower w/c was put on seabed is weaken
about 0.1 times compress strength of cylinders of concrete at
same w/c put in laboratory at the 180th day. The value of
chlorine of diffuse factors are not constant , it is changed
with the age of cylinders ,location, materials , environments
and so on .The among of content of chlorine in concrete is
decreased with w/c, increased with pores , increased when pH of
concrete is decreased. Cylinders of concrete were immersed in
seawater is made from type II cement had contained more chlorine
than type I cement but it was opposite to the cylinders of
concrete put on between high and low tide . After measuring pH
values of cylinders of concrete that we could know seawater
making pH values decreased with age of concrete.To conclude The
sum of all tests shown seawater would penetrate into concrete
and produce interactive reactions between physics and chemistry
, those interactive reactions would direct or indirect
influence the durability of concrete. If we want to use more
exact and accurate data with more reasonable and perfected to
describe and explain in fixed analysis of quantity that we
should need to make more tests and more the work of surveying .
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