臺灣博碩士論文加值系統

隨著再生能源的發展，大規模的能量儲存系統也逐漸備受需求，由於釩氧化還原電池可適用於100kW至10MW範圍內的電力儲能系統，它被認為是最有潛力的大型儲能裝置，因此影響釩氧化還原液流電池表現的離子交換膜，便是大多數相關研究的重點。在本研究中為了改善Nafion質子交換膜的離子選擇性，首先，藉由以高分子插層的方式對多孔層狀矽酸鹽材料(AMH-3)進行膨潤剝層，並以獲得的奈米級薄層多孔矽酸鹽材料作為修飾材料塗佈於Nafion有機高分子膜表面，形成有機-無機複合膜，促使優化後之Nafion膜在離子選擇表現上有97%的提升。

Large scale energy storage system has become an essential component for the development of renewable energy. The vanadium redox flow battery (VRFB) is one of the potential contenders for such large scale energy storage systems owing to its applicability in the energy range of 10kW to 10MW. The performance of VRFB essentially depends on the ion-exchange membrane and hence the studies on membrane is of primary importance. The main focus of this study is to improve the ion selectivity of Nafion membrane through the coating of modified AMH-3. The microporous layered silicate material, AMH-3, is treated by intercalated polymerization to obtain the exfoliated AMH-3. The as-modified AMH-3 is then coated on the Nafion during the membrane preparation process to get an organic- inorganic composite membrane. Compared to the pristine Nafion, the modified Nafion membrane displayed an excellent enhancement in the ion selectivity by 97 percent.

目次
致謝辭.................................................................. i
摘要................................................................... ii
Abstract................................................................ iii
目次................................................................... iv
表目次................................................................. vi
圖目次................................................................ vii
第一章　緒論........................................................... 1
第一節　研究動機..................................................... 1
第二節　全釩氧化還原液流電池......................................... 4
第三節　VRFB 半透膜必備之特性....................................... 6
第四節 半透膜的設計方向............................................. 9
第五節 奈米孔洞材料................................................ 12
第六節 研究目的.................................................... 18
第二章　藥品與儀器.................................................... 19
第一節　實驗藥品.................................................... 19
第二節　使用儀器.................................................... 20
第三章　實驗步驟...................................................... 24
第一節　AMH-3 之合成............................................... 24
第二節　AMH-3 膨潤與剝層反應....................................... 26
第三節　複合膜之製備................................................ 27
第四節 離子選擇率測試.............................................. 28
第四章　結果與討論.................................................... 30
第一節　AMH-3 結構鑑定............................................. 30
第二節　AMH-3 膨潤與剝層反應....................................... 32
第三節　複合膜之製備................................................ 42
第四節 離子選擇率測試............................................... 45
結論.................................................................. 48
參考文獻.............................................................. 49

表目次
表1 實驗藥品.......................................................... 19
表2 [H+]-Nafion及[H^+]-Nafion_AMH-3之離子選擇表現..................... 46

圖目次
圖1 全釩液流電池示意圖................................................. 5
圖2 質子傳遞的機制..................................................... 8
圖3 離子交換膜及相關研究發展史........................................ 11
圖4 頁矽酸鹽.......................................................... 13
圖5 AMH-3結構圖...................................................... 15
圖6 孔洞結構.......................................................... 16
圖7 聚合物對層狀結構物之影響.......................................... 17
圖8 水熱高壓釜示意圖.................................................. 25
圖9 半透膜離子選擇性之測試裝置........................................ 29
圖10 合成AMH-3樣品之粉末X-ray繞射圖................................. 30
圖11合成AMH-3樣品之SEM影像及EDX光譜圖............................ 31
圖12 DL-histidine質子化................................................ 33
圖13 AMH-3 + L-histidine之樣品粉末X-ray繞射圖.......................... 34
圖14 (a)MPS結構(b)MPS對無機物上氫氧根官能基行脫水聚合............... 36
圖15 AMH-3 + MPS之樣品粉末X-ray繞射圖................................ 37
圖16 PMMA對AMH-3之插層聚合反應之樣品粉末X-ray繞射圖............... 39
圖17 AMH-3分散於NMP之粒徑分析結果.................................. 40
圖18 s-AMH-3 之TGA分析圖............................................ 41
圖19 [H^+]-Nafion_e-AMH-3膜........................................... 43
圖20 [H^+]-Nafion_s-AMH-3膜........................................... 44
圖21 以AMH-3修飾前後Nafion膜之質子傳遞速率.......................... 47
圖22 以AMH-3修飾前後Nafion膜之VO^(2+)傳遞速率.......................... 48

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