臺灣博碩士論文加值系統

摘要
本研究是將bis (triazylamine) stilbene disulfonic acid 誘導體的纖維素(cellulose)用螢光增白劑(圖一)，溶解於不同的溶劑中，試作高濃度液體品來測其水溶液之稀釋安定性。
從實驗中我們可以發現 like dissolves like 是可以通用的，另外添加液化助劑對於長期保存時結晶析出的現象可以有效的防止，並可增加此系列之液體螢光增白劑在cellulose染著上的白度。

Abstract
This research of bis (triazylamine) stilbene disulfonic acid and cellulose that induce of the fluorescent whitening agents In list test we try to make the high concentration and dense liquid the stability of dilution of its aqueous solution in different dissolvent.
From this experiment, we could prove the property of “like of like dissol -ves” , and added solvents for long-term preserve in this result, the fluorescent were satisfactory to whiten Cellulose.

目錄
摘要 I
ABSTRACT II
目錄 IV
一 緒論 1
1.1 前言 1
1.2 研究目的 2
二 增白理論 3
2.1何謂螢光增白劑 5
2.2 螢光增白劑作用模式 6
2.3 螢光增白劑的化學 10
2.4螢光增白劑之類型 14
第三章、實驗方法 19
3.1 實驗藥品 19
3.2 實驗儀器: 20
3.3 實驗流程: 21
3.4 染料結構式 22
3.5.螢光增白劑之配製(C.I. 169) 23
3.5.1步驟(一):染料(C.I. 169)進行去除鈉離子及產率值分析 23
3.5.2步驟(二)配置高濃螢光增白劑(C.I. 169): 24
3.6 螢光增白劑之配製(C.I. 87): 25
3.6.1螢光增白劑(C.I. 87)分別在不同濃度之液化 25
3.7 紫外光吸收光譜測試 26
3.7.1 紫外光-可見光區光譜測試24: 26
3.7.2 配製15ppm之螢光增白劑樣本，再進行UV測試: 27
3.8 螢光增白劑之紫外吸收光譜 28
3.9 螢光增白劑之白度測量及堅牢度評估 30
3.9.1 染色性 30
3.10 染色實驗 31
3.11 染色堅牢度測試 32
3.11.1 耐炭弧光染色牢度 27(Color Fastness of Carbon-Arc Lamp) 32
3.11.2 水洗堅牢度 33
第四章 結果與討論 34
4.1 螢光增白劑液化之探討 34
4.1.1 C.I. 169液化之探討 34
4.1.2 C.I. 87液化之探討 36
4.2 染色濃度對螢光性的影響 40
4.2.1 中性鹽、染色溫度及染色PH值對增白的影響 47
4.3 UV-紫外線光譜儀之測定 48
4.4 耐日光堅牢度 49
4.4.1 水洗堅牢度評估 50
第五章 結論 51
第六章 參考文獻 53

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